Synthesis and characterization of wholly aromatic poly(azomethine)s containing donor–acceptor triphenylamine moieties

N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl₃), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (T_gs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (Φ_F) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007     

用地面阵列寻找TeV能区γ点源的方法探讨

文中探讨搜寻TeV能区γ点源的方法.讨论利用student变量t判断来自源区及背景区宇宙线事例的统计差别,并由Bayes定理与MonteCarlo模拟相结合计算源区各能段的信号数,推算蟹状星云在TeV能区的γ射线微分能谱     

实数轴上Grünwald插值算子的收敛性

考虑了拓展插值结点取值范围后的Gruenwald插值算子在实数轴上的收敛性，证明了将结点范围扩大到全实轴后，即取为Hermite多项式的零点，对任意点x∈(-∞,∞)，有Gn(f，x)→f(x)，n→∞，其中，f(x)为实数轴上任一满足|f(x)|=O(e^x^2/2)的连续函数．     

非保守力和非完整约束对Hamilton系统Lie对称性的影响

研究非保守力和非完整约束对Hamilton系统的Lie对称性和守恒量的影响.分别研究了Hamilt on系统受到非保守力和非完整约束作用时，系统的Lie对称性保持不变的条件，同时给出了 系统的结构方程和守恒量保持不变的条件.以著名的Emden方程和Appell-Hamel模型为例进行 了分析讨论. 关键词： 分析力学 Hamilton系统 非保守力 非完整约束 对称性 守恒量     

保险公司离散型崩溃模型研究

本文提出并讨论了含投资因素、红利分配因素的崩溃模型，得出了关于崩溃概率、保险公司的期望寿命的结论，这些结论推广了没有考虑投资因素的崩溃模型的相关结论．     

A problem in extremal quasiconformal extensions

A constantK ₀ ^(m) (h) is introduced for every quasisymmetric mappingh of the unit circle and every integerm≥4 which contains the constantK ₀(h) (indicated by the change in module of the quadrilaterals with vertices on the circle) as a special case. A necessary and sufficient condition is established forK ₀ ^(m) (h) =K ₁(h). It is shown that there are infinitely many quasisymmetric mappings of the unit circle having the property thatK ₀ ^(m) (h)<K ₁(h), wherek ₁(h) is the maximal dilatation ofh.     

钾离子选择电极及其在生物医学中的应用进展

钾离子选择电极的研究一直是一个非常活跃的题目,具有令人瞩目的发展。本文就其研制、测试法与应用方面的新进展进行评述。     

关于E-凸函数及E-凸规划几个错误结论的修正

本文研究Youness在1999年建立的有关E凸函数和E规划的结论.利用E凸函数和E凸规划的基本性质和优化分析技术,获得了有关E凸函数E凸规划的几个错误结论的修正..     

灰色模型的最优化及其参数的直接求法

基于灰色模型的内涵表达式和白化方程响应式均为等比级数的观点,提出了一种不用求ago值、均值,不涉及灰色微分方程,白化微分方程概念,直接求灰色模型参数a,c的方法,通过此方法建立的新模型不仅从理论上可保证是在满足给定评价标准为模拟绝对误差平方和最小(或模拟相对误差平方和最小)、给定精度条件下的最优化模型,从而结束了灰色模型只有更优,没有最优的历史.并从理论上证明了新模型具有白化指数律重合性、白化系数律重合性,伸缩变换一致性.最后通过实例编程验证该方法具有可操作性,且预测精度高,效果好.