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排序方式: 共有791条查询结果,搜索用时 15 毫秒
91.
在目前常规图象分辨率基础上,对数字图象相关测量方法的灵敏度进行分析,给出了位移和应变测量的灵敏度,并讨论了影响灵敏度的有关因素,进而指出,数字图象测量系统特别适合于各种位移场的大变形场的定量测量,在配制了相应的光学观察仪器后。也基本适合一般变形场的测量。 相似文献
92.
在已有的基于膨胀体模型、动理论模型和连续介质理论得到的关系式基础上,分析了水沙流中颗粒流动的应力关系应由摩擦应力、滑动应力和碰撞应力3部分组成,并将颗粒弹性恢复系数引入,对颗粒碰撞项进行了修正。根据颗粒碰撞时间间隔T_c和颗粒弛豫时间T_e的对比,提出了颗粒流动进入碰撞惯性区的临界值,即当T_c/T_e<0.02时,水沙流中颗粒流动碰撞作用占优,可忽略摩擦应力和滑动应力,并将提出的临界值与实验资料进行了比较。利用修正后的水沙流中颗粒流动应力关系,对缓槽水沙流动进行了模拟计算,获得了与实测资料一致的结果。 相似文献
93.
主要介绍自由电子激光相干强太赫兹源(FEL-THz)装置上的砷化镓光阴极直流高压注入器的研究进展,并讨论其驱动未来高重复频率短波长自由电子激光器的差距。通过综合砷化镓阴极寿命的三大影响因素,提出了其工作寿命的定性物理模型;通过该模型对阴极和注入器进行优化,在直流高压电子枪上得到了5mA,32min的连续稳定输出;测量了电子束在4.8mA下归一化发射度约为4.0πmm·mrad,阴极热发射度约为0.6πmm·mrad,电子束本征横向能量约为92meV,250keV电子束在距离阴极90.6cm处纵向均方根长度约为11.5ps。这一束流状态已经基本满足FEL-THz需求。 相似文献
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96.
Synthesis, Crystal Structure, and Herbicidal Activities of 2-Cyanoacrylates Containing 1,3,4-Thiadiazole Moieties 总被引:1,自引:0,他引:1
Tingting Wang Wenke Miao Shanshan Wu Guifang Bing Xin Zhang Zhenfang Qin Haibo Yu Xue Qin Jianxin Fang 《中国化学》2011,29(5):959-967
Three series of novel 2‐cyanoacrylates 7a – 7f , 9a – 9f , 10a – 10f containing 1,3,4‐thiadiazole ring moieties were synthesized as herbicidal inhibitors of photosystem II (PS II) electron transportation. Their structures were clearly verified by 1H NMR, 13C NMR, elemental analysis (or HRMS analysis) and single‐crystal X‐ray diffraction analysis. Bioassay showed that a suitable group at the 3‐position of acrylates was essential for high herbicidal activity. In particular, compound 7e showed the best herbicidal activities and gave 100% inhibitory activity against rape and amaranth pigweed at a dose of 1.5 kg/ha. Introduction of substituent with higher polarity such as sulfinyl or sulfonyl to the 5‐position of 1,3,4‐thiadiazole decreased herbicidal activities. 相似文献
97.
Identifying essential proteins is very important for understanding the minimal requirements of cellular survival and development. Fast growth in the amount of available protein-protein interactions has produced unprecedented opportunities for detecting protein essentiality from the network level. Essential proteins have been found to be more abundant among those highly connected proteins. However, there exist a number of highly connected proteins which are not essential. By analyzing these proteins, we find that few of their neighbors interact with each other. Thus, we propose a new local method, named LAC, to determine a protein's essentiality by evaluating the relationship between a protein and its neighbors. The performance of LAC is validated based on the yeast protein interaction networks obtained from two different databases: DIP and BioGRID. The experimental results of the two networks show that the number of essential proteins predicted by LAC clearly exceeds that explored by Degree Centrality (DC). More over, LAC is also compared with other seven measures of protein centrality (Neighborhood Component (DMNC), Betweenness Centrality (BC), Closeness Centrality (CC), Bottle Neck (BN), Information Centrality (IC), Eigenvector Centrality (EC), and Subgraph Centrality (SC)) in identifying essential proteins. The comparison results based on the validations of sensitivity, specificity, F-measure, positive predictive value, negative predictive value, and accuracy consistently show that LAC outweighs these seven previous methods. 相似文献
98.
The selective oxidation of thiols to disulfides and sulfides to sulfoxides using graphite oxide (GO), a heterogeneous carbocatalyst obtained from low cost, commercial starting materials is described. The aforementioned oxidation reactions were found to proceed rapidly (as short as 10 min in some cases) and in good yield (51-100%) (19 examples). No over-oxidation of the substrates was observed, and GO's heterogeneous nature facilitated isolation and purification of the target products. 相似文献
99.
Zou J Pan L Li Q Zhao J Pu J Yao P Gong N Lu Y Kondratyuk TP Pezzuto JM Fong HH Zhang H Sun H 《Organic letters》2011,13(6):1406-1409
From the medicinal plant Isodon rubescens, we isolated two novel diterpenes, rubesanolides A (1) and B (2). The compounds contain a unique β-lactone subgroup. This is the first discovery for a natural diterpene having rings A, B, and C in chair, boat, and twist-chair conformations, respectively. The structures were elucidated by analysis of spectroscopic data, and the absolute configuration of 1 was determined by X-ray diffraction. 相似文献
100.
Bromine reacts with the 1,2-bisadduct C(60)(OOtBu)(2) efficiently to form the cyclopentadienyl-type compound 4 (C(60)(OOtBu)(2)Br(4)). In the presence of AgClO(4), the four bromine atoms can be replaced regioselectively by methoxyl groups in a stepwise fashion to form C(60)(OOtBu)(2)Br(4-x)(OMe)(x). A second alcohol may be introduced by treating partially methoxylated compound 6 (C(60)(OOtBu)(2)Br(2)(OMe)(2)) with ROH/AgClO(4). Other related reactions have been investigated to explore the reactivity patterns. The structure of compound 6 was confirmed by single crystal X-ray analysis. 相似文献