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141.
Yanlin Huang Kiwan Jang Wanxue Zhao Eunjin Cho Ho Sueb Lee Xigang Wang Dake Qin Ying Zhang Chanfang Jiang Hyo Jin Seo 《Journal of solid state chemistry》2007,180(12):3325-3332
Usually, Sm2+ ions could be reduced by heating the materials in reducing atmospheres. Exposure to ionizing radiations is also known to cause Sm3+→Sm2+ conversion. In this work, BaBPO5 doped with the samarium ion was prepared by high temperature solid-state reaction. Sm2+ ions were obtained by two different reduction methods, i.e., heating in H2 reduced atmosphere and X-ray irradiation. The measurements of X-ray diffraction (XRD), and scanning electron microscope (SEM) were investigated. It is found that the conversion of Sm3+→Sm2+ is very efficient in BaBPO5 hosts after X-ray irradiation. Sm2+ ions under these two reduction methods exhibit different characteristics that were studied by measurements of luminescence and decay. The results showed that the luminescence properties of Sm2+ ions in BaBPO5 were highly dependent on the sample preparation conditions. 相似文献
142.
Gui-Chang Wang Ling Jiang Yoshitada Morikawa Junji Nakamura Zun-Sheng Cai Yin-Ming Pan Xue-Zhuang Zhao 《Surface science》2004,570(3):205-217
The adsorption behavior and thermal activation of carbon dioxide on the Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0) surfaces have been investigated by means of density functional theory calculations and cluster models and periodic slabs. According to the cluster models, the optimized results indicate that the basis set of C and O atoms has a distinct effect on the adsorption energy, but an indistinct one on the equilibrium geometry. For the CO2/Cu(hkl) adsorption systems studied here, the final structure of adsorbed CO2 is near linear and the preferred modes for the adsorption of CO2 onto the Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0) surfaces are the side-on adsorption at the cross bridge site with an adsorption energy of 13.06 kJ/mol, the side-on adsorption at the short bridge site (13.54 kJ/mol), and the end-on adsorption on the on-top site with C–O bonds located along the short bridge site (26.01 kJ/mol), respectively. However, the calculated adsorption energies from periodic slabs are lower as compared to the experimental data as well as the cluster model data, indicating that the periodic slab approach of generalized gradient approximation in the density function theory may be not suitable to obtain quantitative information on the interaction of CO2 with Cu(hkl) surfaces. 相似文献
143.
光纤加速度传感器研究进展 总被引:5,自引:0,他引:5
光纤加速度传感器与传统加速度传感器相比,不但能抗电磁干扰,而且体小、质轻、动态范围宽、精度高、能在恶劣环境下工作,因此受到各先进国家军事与商业领域的极大重视,各种实用的光纤加速度传感器不断涌现。主要有光强调制型和相位调制型两大类。光强调制式有反射式、透射式和偏振式等等。相位调制式有Mach-Zender干涉仪、Michelson干涉仪和Fabry-Perot干涉仪。有一维的,也有二维的;有与水听器组合在一起的,也有与光纤陀螺仪组合的光纤加速度传感器。最小的已经做到2.5cm长,直径仅0.25mm;测量精度已能达到1μg;共振频率可达到10kHz。为了克服温度不稳定性对测量精度的影响,人们采用了3×3耦合器解调法,双光路法,由单臂式改成推挽式等。一旦关键技术得以克服,光纤加速度传感器将会在惯性导航和其它领域发挥更重要的作用。本文将分别介绍目前各种类型光纤加速度传感器的结构、特点、走向实用化存在的问题。 相似文献
144.
在研究小波变换及布朗分形模型的基础上,定义了水平分维数,垂直分维数,对角分维数,并将它们作为纹理特征量来实现纹理的分割.实验结果表明,这些特征量能够很好地反映纹理特征,从而分割时不需有关图象中纹理类别的先验信息,较以往方法在准确度和计算复杂程度上都有很大提高. 相似文献
145.
146.
147.
Yan Zhao Xingbin Yang Ru Jiang Xiaoli Sun Wenmin Liu Shengyong Zhang 《Analytical sciences》2006,22(5):747-751
The investigation on capillary electrophoretic enantioseparation of six synthetic compounds containing vicinal diol groups has been undertaken to acquire the optimum conditions using native beta-cyclodextrin (beta-CD) as chiral selector and borate as a background electrolyte. The separation was carried out in an uncoated capillary (58.5 cm x 75 microm i.d., effective length 48.5 cm) and the effects of several important factors were investigated in detail. The results showed that beta-CD as a chiral selector exhibited good enantioselectivity and that the enantioseparation was greatly influenced by the structure of the diols, the borate concentration and the buffer pH. The optimum performance was obtained for the chiral vicinal diols under the conditions of 200 mM borate buffer of pH 9.8 containing 1.7% beta-CD at an applied voltage of 15 kV and a capillary temperature of 20 degrees C. Under the conditions, four diols were baseline separated with fast analysis time and the good theoretical plate numbers (above 10 x 10(4)) and favorable migration-time reproducibilities (RSDs below 3.0%) were obtained. The separation results were satisfactory. 相似文献
148.
V. N. Manuilov T. Idehara M. Kamada T. Hayashi La Agusu T. Kanemaki K. Yatsui Wiehua Jiang 《International Journal of Infrared and Millimeter Waves》2006,27(9):1183-1193
High power Large Orbit Gyrotron (LOG) [1] is now under development at FIR FU. First version of this device was recently manufactured
and then assembled with power supply ETIGO-IV [2]. Results of preliminary tests of electron-optic system are presented. The
conditions when stableflat form of current pulse realized are discussed. Analytical estimations of cathode-anode distance
to achieve small influence of cathode plasma during high voltage (HV) pulse are performed.
Two new electron gun versions with decreased influence of the cathode plasma on its impedance and pulse form are suggested
and optimized. New optimal magnetic field distributions are found. First gun has quiasi-flat cathode configuration near the
anode diaphragm and provides operating current about 60 A. Second one uses blade cathode with operating current about 30 A.
Beam quality for both guns is suitable for LOG operation. 相似文献
149.
用飞秒激光(200 fs,1 kHz,800 nm)脉冲在掺杂稀土离子Ce3 的聚甲基丙烯酸甲酯(PMMA)膜中进行了光存储实验研究,包括对样品的吸收光谱、激光照射前后的电子旋转共振(Electron spin resonance,ESR)光谱的测量和讨论。结果表明掺杂稀土离子Ce3 的聚甲基丙烯酸甲酯膜具有较低的写入阈值,有利于高速、并行的三维光存储。实验结果采用传统光学显微镜并行读出。给出了四层存储结果(点间距和层间距分别是4μm和16μm),并讨论了脉冲能量的大小对空腔尺寸的影响,进行高密度存储时,在保证读出信号灰度值足够大的情况下,应选择尽量小的激光脉冲写入能量。实验结果表明这种材料可以应用于三维光信息存储。 相似文献
150.
采用溶胶-凝胶方法在Si(111)上制备了LSMO(x=0.17)薄膜.研究了块体材料和不同厚度薄膜R -T曲线、红外光谱和X射线衍射.结果表明,LSMO薄膜属于正交晶体结构,薄膜取向与膜厚度 有关,当膜厚度为450nm或680nm时,主要取向〈200〉,而膜厚度为900nm时取向为〈020〉 :根据离子对相互作用能和谐振子模型,得到了红外吸收与Mn—O—Mn键长和键角关系式,6 00cm-1附近红外吸收与晶格常数b的变化有关;块体与薄膜的金属—绝缘体转变 温度(TMI)存在较大差别,薄膜转变温度显著低于块体,并与厚度有一定关系. 认为是LSMO薄膜中的应力诱导了晶格常数变化,引起键角改变及JT效应是转变温度变化的主 要原因.
关键词:
单晶硅
晶格常数
金属—绝缘体转变温度
应力诱导 相似文献