20单元双压电片变形反射镜的影响函数有限元分析和实验测量

影响函数是分析双压电片变形反射镜像差校正能力的重要参量,通过建立有限元模型预测实际器件的影响函数,以有限元模型的不断优化替代实际器件的尝试性改进,可以减小构造的盲目性,从而节约研发成本,缩短双压电片变形镜的实用化进程.采用Veeco干涉仪测量了20单元双压电片变形反射镜的影响函数,同时建立有限元模型进行了相应计算,并将计算结果与实际器件的测量数据进行了对比分析.结果表明,相对于实测数据而言,有限元模型计算得出的影响函数在量值上略有偏小,但其形状和峰值位置与测量数据一致性好,两者对前35项泽尼克像差的拟合曲线也基本吻合,各项拟合误差系数之差皆小于0.1.这说明通过不断改进有限元模型实现对实际器件的优化设计是切实可行的.     

基于柯西分布的视频图像序列背景建模和运动目标检测

提出了一种用于视觉监视系统的基于柯西分布的发光模型的光照不变变化检测方法.假定视频图像序列中每个背景图像像素点灰度观测值的时序变化由白噪声引起,利用建立的初始化背景高斯统计模型对每帧图像进行归一化,得到了背景像灰度比值的分布符合标准柯西分布的结论,解决了柯西分布的模型参量估计问题.在变化检测的基础上,YCbCr颜色空间的亮度、色调和饱和度被用来识别和消除由阴影和反光等引起的变化区域.结果表明,提出的背景建模方法对场景中各种光线变化、小的背景扰动等噪声具有稳健性,可以较为可靠地检测前景目标,识别和去除阴影和反光.     

带-NH2的嘧啶环对钌配合物与DNA相互作用的瞬态发光特性的影响

采用时间分辨的发光光谱技术,分别测量了两种新合成的钌配合物[Ru(bpy)2 (dpbpd(NH2)2)]2 和[Ru(phen)2(dpbpd(NH2)2)]2 与小牛胸腺脱氧核糖核酸(ctDNA)相互作用时的瞬态发光动力学过程,并与以往对[Ru(phen)2dppz]2 等的研究结果进行对比,从而研究带-NH2的嘧啶环对配合物与DNA作用动力学过程的影响.结果表明:这两种含有带-NH2的嘧啶环的钌配合物与DNA相互作用时的发光按双指数规律衰减,发光寿命为几十纳秒,比dppz类钌配合物与DNA作用时的发光衰变寿命(几百纳秒)小一个数量级.归因于嘧啶环上的N和-NH2可能与水分子、DNA的碱基对或磷酸骨架形成氢键,从而加快激发态的无辐射弛豫,削弱发射光强,缩短发光寿命.该结论为进一步研究配合物分子与DNA的相互作用的机理提供了一定的依据.     

余弦二值编码纯相位全息图的数字微镜器件显示

分析了采用错误减算法的迭代过程,在已知物波函数傅里叶谱的振幅和物波函数振幅的情况下恢复出纯相位的物波函数,最大限度地保留物波的振幅及相位信息.提出采用余弦二值编码生成二值全息图,即全息图的透射率函数取0或1.二值全息图通过数字微镜器件全息显示系统进行了重构显示,重构效果很好.理论分析了数字微镜器件的衍射效率,表明其最大衍射效率仅和微镜之间的间隔尺寸与微镜边长之比有关.余弦二值编码方法从理论上消除了零级衍射,可以制作像素较多的全息图.     

转移基板材质对Si衬底GaN基LED芯片性能的影响

在Si衬底上生长了GaN基LED外延材料,分别转移到新的硅基板和铜基板上,制备了垂直结构蓝光LED芯片。研究了这两种基板GaN基LED芯片的光电性能。在切割成单个芯片之前,对大量尺寸为(300μm×300μm)的这两种芯片分别通高达1 A的大电流在测试台上加速老化1 h。结果显示,铜基板Si衬底GaN基LED芯片有更大的饱和电流,光输出效率更高,工作电压随驱动电流的变化不大,光输出在老化过程中衰减更小。铜基板芯片比硅基板芯片可靠性更高,在大功率半导体照明器件中前景诱人。     

一种高性能太阳敏感器复合光学系统设计

以夫朗禾费衍射理论为基础,结合微透镜,设计了一种高性能的数字式太阳敏感器复合光学系统。分析了光学系统的组成,建立了光学系统的数学模型,设计了光学系统的焦距、孔径和微透镜参量,并进行了成像的数值仿真。仿真结果表明,与基于掩模的光学系统相比,这种新型的复合光学系统成像光斑能量分布集中,保证计算光斑中心位置的高精度,使敏感器具有大视场和高精度的特点。     

Ionic/electronic conductivity regulation of n-type polyoxadiazole lithium sulfonate conductive polymer binders for high-performance silicon microparticle anodes

Low-cost silicon microparticles(SiMP),as a substitute for nanostructured silicon,easily suffer from cracks and fractured during the electrochemical cycle.A novel n-type conductive polymer binder with excellent electronic and ionic conductivities as well as good adhesion,has been successfully designed and applied for high-performance SiMP anodes in lithium-ion batteries to address this problem.Its unique features are attributed to the stro ng electron-withdrawing oxadiazole ring structure with sulfonate polar groups.The combination of rigid and flexible components in the polymer ensures its good mechanical strength and ductility,which is beneficial to suppress the expansion and contraction of SiMP s during the charge/discharge process.By fine-tuning the monomer ratio,the conjugation and sulfonation degrees of the polymer can be precisely controlled to regulate its ionic and electronic conductivities,which has been systematically analyzed with the help of an electrochemical test method,filling in the gap on the conductivity measurement of the polymer in the doping state.The experimental results indicate that the cell with the developed n-type polymer binder and SiMP(~0.5 μm) anodes achieves much better cycling performance than traditional non-conductive binders.It has been considered that the initial capacity of the SiMP anode is controlled by the synergetic effect of ionic and electronic conductivity of the binder,and the capacity retention mainly depends on its electronic conductivity when the ionic conductivity is sufficient.It is worth noting that the fundamental research of this wo rk is also applicable to other battery systems using conductive polymers in order to achieve high energy density,broadening their practical applications.     

Weaving 3D highly conductive hierarchically interconnected nanoporous web by threading MOF crystals onto multi walled carbon nanotubes for high performance Li-Se battery

Lithium-selenium (Li-Se) battery has attracted growing attention.Nevertheless,its practical application is still impeded by the shuttle effect of the formed pol...     

Acid-induced tunable white light emission based on triphenylamine derivatives

A series of triphenylamine (TPA) derivatives with various substituent groups were prepared and showed different absorption and fluorescence characteristics due to the substituent effect. On account of the existence of pyridine units, these TPA derivatives exhibited acid-induced tunable multicolor fluorescence emission including white light emission. In addition, acid-induced fluorescence regulation of these compounds has been also realized in the solid state, which enable them to be successfully constructed the stimuli-responsive fluorescent films and fluorescent inks for inkjet printing.     

An unexpected generation of magnetically separable Se/Fe3O4 for catalytic degradation of polyene contaminants with molecular oxygen

Selenization of Fe₂O₃ with NaHSe led to Se/Fe₃O₄. The unexpected generation of Fe₃O₄ attributed to the reduction conditions of the reaction, and the resulted magnetic features of the material facilitated its separation in practical applications. Owning to the synergistic effect of Se with Fe, the material was especially active to catalyze the oxidative C=C scission using O₂ as mild oxidant. The technique has been successfully applied in polyene degradation project, which is of profound practical values for the treatment of the polyene pigment pollution and may be applied in the food and pharmaceutical industry.