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51.
应用串联氮杂Wittig反应设计合成了一系列新的2-烷氨(芳氧)基-3,8-二苯基-5-芳基-6-甲基-5,8-二氢-4H-吡唑并[4',3':5,6]吡喃并[2,3-d]嘧啶-4(3H)-酮衍生物。通过氢核磁共振谱仪(1H NMR)、傅里叶变换红外光谱仪(FTIR)和元素分析等方法对所合成的化合物进行了结构表征,用X射线单晶衍射确证了化合物2-二正丙基氨基-3,8-二苯基-5-(4-甲基苯基)-6-甲基-5,8-二氢-4H-吡唑并[4',3':5,6]吡喃并[2,3-d]嘧啶-4(3H)-酮(Ⅲi)晶体结构。室内的杀菌和杀虫活性测试结果表明:目标化合物具有一定的杀菌活性,其中部分化合物对黄瓜灰霉菌(Botrytis cinereapers)在50 mg/L剂量下抑制率达到90%以上,显示了优异的杀菌活性;对水稻褐飞虱无明显的杀虫活性,但发现对粘虫具有较高的杀灭效果,大多数抑制率达到90%以上。 相似文献
52.
Jianchao Yuan Xuehu Wang Tongjian Mei Yufeng Liu Chengping Miao Xiaoli Xie 《Transition Metal Chemistry》2011,36(4):433-439
A Br-substituted α-diimine ligand, bis[N,N′-(4-bromo-2,6-dimethylphenyl)imino]-2,3-butadiene L1, and its corresponding Ni(II) complex, {bis[N,N′-(4-bromo-2,6-dimethylphenyl)imino]-2,3-butadiene} dibromonicke [NiBr
2
(L1)], have been synthesized and characterized. The crystal structure of the free ligand (L1) was determined by X-ray crystallography. Two α-diimine-Ni(II) catalysts, {bis[N,N′-(2,4,6-dimethylphenyl)imino]-2,3-butanedione}
dibromonickel [NiBr
2
(L2)] and {bis[N,N′-(2,6-dimethylphenyl)imino]-2,3-butanedione} dibromonickel [NiBr
2
(L3)], were also synthesized and characterized for comparison. The complex [NiBr
2
(L1)], when activated by diethylaluminum chloride, produces the most active catalytic system for the polymerization of ethylene
among the three complexes. NMR analysis shows that the degree of branching of polyethylene increases in the presence of electron-withdrawing
groups under the same reaction conditions. 相似文献
53.
湿地水质与水系浮游细菌多样性关联研究 总被引:1,自引:0,他引:1
城市湿地水质受人类活动影响,其水系浮游细菌群落多样性也因水质状况不同而变化.以杭州西溪湿地国家公园为研究区,分析人类活动特征差异对河道水质及浮游细菌群落多样性的影响,测定溶解氧、氨氮、硝氮、总氮、总磷等主要理化指标,运用聚合酶链式反应与变性梯度凝胶电泳(PCR-DGGE)技术,分析各水样中浮游细菌群落多样性,通过主成分分析与典型对应分析等统计手段,比较各项理化指标与细菌群落结构的相关性.研究结果表明:湿地河道水质受人类活动影响显著,呈中度~重度富营养化;河道水域内细菌群落总体多样性较高,且多样性指数与硝态氮、总氮、TSI指数、电导率呈极显著负相关(r<-0.7,p<0 .01),与水温呈极显著正相关(r>0.8,p<0.01),相较于硝态氮、总氮等单项指标,综合营养状态指数与细菌多样性指数间具有最高负相关性(r=-0.90,p<0.01).浮游细菌群落结构变化受多种理化指标共同影响,其中限制性营养元素氨氮为主要调控因子. 相似文献
54.
本文通过考察一种新影响图的保形法曲率,给出一种新二阶局部影响分析方法,并通过实例验证了该方法的有效性. 相似文献
55.
Internal gear mechanism is widely used in micro-nano satellites due to its compact structure and high precision transmission. However, the vibration coupling caused by the small clearance coupling is more obvious and cannot be ignored under low speed, light load and zero gravity conditions. Based on the geometric relationship between radial clearance and backlash, a coupled model between dynamic backlash and radial clearance of internal meshing gear is established. Based on the conformal contact theory, the radial collision force model of the gear shaft and shaft sleeve considering the small clearances is established. Additionally, a multi-clearance gear rotor system test device is built to measure the vibration acceleration of the internal gear rotor system by an acceleration sensor and transmitted to the industrial computer through a signal collector for data processing. Through the comparison of simulation and experiment, the accuracy of the gear dynamics model is verified. The analysis results show that, compared with the traditional model, the calculation results of the gear mechanism model considering the small clearance coupling is closer to the experimental data. 相似文献
56.
New nickel(II) diimine complexes bearing phenyl and sec‐phenethyl groups: synthesis,characterization and ethylene polymerization behaviour 下载免费PDF全文
Fuzhou Wang Jianchao Yuan Qingshan Li Ryo Tanaka Yuushou Nakayama Takeshi Shiono 《应用有机金属化学》2014,28(7):477-483
A series of nickel(II) catalysts containing phenyl and chiral sec‐phenethyl groups, {[(4‐R1‐2‐R2C6H2N?C)2Nap]NiBr2} (Nap: 1,8‐naphthdiyl, R1 = Me, R2 = Ph ( 3a ); R1 = Me, R2 = sec‐phenethyl ( 3b ); R1 = Cl, R2 = sec‐phenethyl ( 3c ); R1 = Me, R2 = Me ( 3d ) were synthesized and characterized. All organic compounds were fully characterized by FT‐IR and NMR spectroscopy and elemental analysis. The single crystal for X‐ray crystallography was isolated from 3a in CH2Cl2/n‐hexane under air; the crystal structure showed a binuclear complex 3a ′, in which each nickel atom was six‐coordinate. The two nickel atoms together with two bromine atoms form a planar four‐membered ring, with a bromine and H2O axial ligands. These complexes, activated by diethylaluminum chloride and chiral nickel pre‐catalysts rac‐ 3c , exhibited good activities (up to 2.85 × 106 g PE (mol Ni h bar)?1) for ethylene polymerization, and produced polyethylene products with a high degree of branching (up to 117 branched per 1000 carbons) at high temperature. The type and amount of branches of the polyethylenes obtained were determined by 1H and 13C NMR spectroscopy. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
57.
Preparation and evaluation of novel chiral stationary phases based on quinine derivatives comprising crown ether moieties 下载免费PDF全文
Dongqiang Wang Jianchao Zhao Haixia Wu Haibo Wu Jianfeng Cai Yanxiong Ke Xinmiao Liang 《Journal of separation science》2015,38(2):205-210
The C9‐position of quinine was modified by meta‐ or para‐substituted benzo‐18‐crown‐6, and immobilized on 3‐mercaptopropyl‐modified silica gel through the radical thiol‐ene addition reaction. These two chiral stationary phases were evaluated by chiral acids, amino acids, and chiral primary amines. The crown ether moiety on the quinine anion exchanger provided a ligand‐exchange site for primary amino groups, which played an important role in the retention and enantioselectivity for chiral compounds containing primary amine groups. These two stationary phases showed good selectivity for some amino acids. The complex interaction between crown ether and protonated primary amino group was investigated by the addition of inorganic salts such as LiCl, NH4Cl, NaCl, and KCl to the mobile phase. The resolution results showed that the simultaneous interactions between two function moieties (quinine and crown ether) and amino acids were important for the chiral separation. 相似文献
58.
59.
为了同时改善固相共沉积法合成的α-Ni0.8Co0.05Al0.15(OH)2.15-2y(CO3)y·xH2O的常、高温充放电性能,样品经混合掺杂不同比率的La2O3,Sm2O3,Y2O3,Lu2O3以及La2O3+Y2O3后,作为模拟MH/Ni电池的正极材料,在不同温度下由恒流充放电和循环伏安测定其电化学性能.结果表明:复合掺加0.5%La2O3+1.0%Y2O3(质量分数),在0.5C和5C充放电下,30℃时可分别提高样品的放电比容量3.3%和4.7%,60℃时可分别提高17.4%和19.9%.同时也改善了高温放电电位. 相似文献
60.
Evaluation and application of a mixed‐mode chromatographic stationary phase in two‐dimensional liquid chromatography for the separation of traditional Chinese medicine 下载免费PDF全文
Zhishen Wei Qing Fu Jianfeng Cai Liyun Huan Jianchao Zhao Hui Shi Yu Jin Xinmiao Liang 《Journal of separation science》2016,39(12):2221-2228
In this study, two mixed‐mode chromatography stationary phases (C8SAX and C8SCX) were evaluated and used to establish a two‐dimensional liquid chromatography system for the separation of traditional Chinese medicine. The chromatographic properties of the mixed‐mode columns were systematically evaluated by comparing with other three columns of C8, strong anion exchanger, and strong cation exchanger. The result showed that C8SAX and C8SCX had a mixed‐mode retention mechanism including electrostatic interaction and hydrophobic interaction. Especially, they were suitable for separating acidic and/or basic compounds and their separation selectivities could be easily adjusted by changing pH value. Then, several off‐line 2D‐LC systems based on the C8SAX in the first dimension and C8SAX, C8SCX, or C8 columns in the second dimension were developed to analyze a traditional Chinese medicine—Uncaria rhynchophylla. The two‐dimensional liquid chromatography system of C8SAX (pH 3.0) × C8SAX (pH 6.0) exhibited the most effective peak distribution. Finally, fractions of U. rhynchophylla prepared from the first dimension were successfully separated on the C8SAX column with a gradient pH. Thus, the mixed‐mode stationary phase could provide a platform to separate the traditional Chinese medicine in practical applications. 相似文献