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231.
Formation of large 2D nanosheets via PVP-assisted assembly of anatase TiO2 nanomosaics 总被引:1,自引:0,他引:1
Chen JS Liu J Qiao SZ Xu R Lou XW 《Chemical communications (Cambridge, England)》2011,47(37):10443-10445
We demonstrate an unusual formation of large 2D nanosheets from nanomosaic building blocks of anatase TiO(2) nanosheets with exposed (001) facets. It is proposed that large PVP molecules adsorbed on the (001) facets serve as the linker that brings building blocks together, at the same time prevents them from stacking along the c-axis. 相似文献
232.
Ding S Luan D Boey FY Chen JS Lou XW 《Chemical communications (Cambridge, England)》2011,47(25):7155-7157
We demonstrate a new hydrothermal method to directly grow SnO(2) nanosheets on a graphene oxide support that is subsequently reduced to graphene. This unique SnO(2)/graphene hybrid structure exhibits enhanced lithium storage properties with high reversible capacities and good cycling performance. 相似文献
233.
Wang Z Luan D Madhavi S Li CM Lou XW 《Chemical communications (Cambridge, England)》2011,47(28):8061-8063
Polycrystalline α-Fe(2)O(3) nanotubes with thin walls have been synthesized by one-step template-engaged precipitation of Fe(OH)(x) followed by thermal annealing. In virtue of the unique structural features, these α-Fe(2)O(3) nanotubes exhibit superior lithium storage capabilities with exceptional high-rate capacity retention as a potential anode material for lithium-ion batteries. 相似文献
234.
Lou P 《Physical chemistry chemical physics : PCCP》2011,13(38):17194-17204
The edge reconstruction effect of the zigzag silicon carbide nanoribbons (zz SiC NRs) to a stable line of alternatively fused seven and five membered rings without and with H passivation have been studied using first principles density functional theory (DFT). The both side's edges of the pristine SiC are respectively terminated by Si and C atoms and are called the Si-edge and the C-edge, respectively. In the un-passivated systems, the C-edge reconstructed (Crc) could effectively lower the edge energy of the system, while the Si-edge reconstructed (Sirc) could raise the edge energy of the system. Thus, the Crc edge is the best edge for the edge reconstruction of the system, while the both edge reconstructed (brc) system is the metastability. Moreover, the brc system has a nonmagnetic metallic state, whereas the Crc system, as well as Sirc system, has a ferromagnetic metallic state. The edge reconstructed destroys the magnetic moment of the corresponding edge atoms. The magnetic moment arises from the unreconstructed zigzag edges. The pristine zz edge system has a ferrimagnetic metallic state. However, in the H-passivated systems, the unreconstructed zigzag edge (zz-H) is the best edge. The Crc-H system is the metastability. The Sirc-H system has only slightly higher energy than the Crc-H system, whereas the brc-H system of the pristine SiC NR has the highest edge energy. Thus, the H passivation would prevent the occurrence of edge reconstruction. Moreover, H passivation induces a metal-semiconductor transition in the zz and brc SiC NRs. Additionally, except for brc-H system which has non-magnetic semiconducting state, the zz-H, Crc-H, and Sirc-H systems have the magnetic state. 相似文献
235.
Two undescribed dimeric ArC2 derivatives, cis- and trans-1,2-bis(3,4-dimethoxyphenyl)cyclobutane (1 and 2), one new monoterpenes esters, 2alpha,5beta-dihydroxybornane-2-cis-cinnamate (3), along with eight known compounds, 2alpha,5beta-dihydroxybornane-2-trans-cinnamate (4), perrottetin E (5), isoriccardin C (6), marchantin A (7), marchantin E (8), marchantin C (9), and isomarchantin C (10) were isolated from the liverwort Conocephalum japonicum. All the structures were established by extensive spectroscopic analysis. The isolated compounds 3-10 were evaluated for their cytotoxicity against the human KB cell line with IC50 values ranging from 16.5 to 50.2 microM. 相似文献
236.
数字全息研究领域目前存在两种不同的数字全息图取样模型.按照这两种模型进行研究时, 不但涉及较复杂的数学运算, 在许多情况下还会导致不同的研究结果, 不便于理论分析及实际应用.基于对数字全息图记录的物理过程分析及电荷藕合器件(charge coupled device, CCD)几何结构的研究, 本文将这两种取样模型简化为相同的数学表达式. 利用数字全息图的余弦级数展开及取样定理对简化模型的研究表明, 简化模型不但具有清晰的物理意义, 而且可以方便地为应用研究服务. 基于简化模型对物光波通过光学系统到达CCD的数字全息记录系统进行了研究, 导出得到实验证实的波前重建表达式.
关键词:
数字全息
波前重建
相干光成像 相似文献
237.
Based on theab initio calculation results, the hydrogen atom transfer has been investigated. In order to explain the experimental results, a new
mechanism is proposed, that is, hydrogen transfer occurs before but not after CI atom eliminates from aromatic ring. The calculation
result strongly supports this mechanism. 相似文献
238.
It is proved that a cyclically (k ? 1)(2n ? 1)-edge-connected edge transitive k-regular graph with even order is n-extendable, where k ≥ 3 and k ? 1 ≥ n ≥ ?(k + 1)/2?. The bound of cyclic edge connectivity is sharp when k = 3. © 1993 John Wiley & Sons, Inc. 相似文献
239.
The semilinear parabolic system that describes the evolution of the gene frequencies in the diffusion approximation for migration and selection at a multiallelic locus without dominance is investigated. The population occupies a finite habitat of arbitrary dimensionality and shape (i.e., a bounded, open domain in Rd). The selection coefficients depend on position; the drift and diffusion coefficients may depend on position. The primary focus of this paper is the dependence of the evolution of the gene frequencies on λ, the strength of selection relative to that of migration. It is proved that if migration is sufficiently strong (i.e., λ is sufficiently small) and the migration operator is in divergence form, then the allele with the greatest spatially averaged selection coefficient is ultimately fixed. The stability of each vertex (i.e., an equilibrium with exactly one allele present) is completely specified. The stability of each edge equilibrium (i.e., one with exactly two alleles present) is fully described when either (i) migration is sufficiently weak (i.e., λ is sufficiently large) or (ii) the equilibrium has just appeared as λ increases. The existence of unexpected, complex phenomena is established: even if there are only three alleles and migration is homogeneous and isotropic (corresponding to the Laplacian), (i) as λ increases, arbitrarily many changes of stability of the edge equilibria and corresponding appearance of an internal equilibrium can occur and (ii) the conditions for protection or loss of an allele can both depend nonmonotonically on λ. Neither of these phenomena can occur in the diallelic case. 相似文献
240.
Yuan Lou 《Journal of Differential Equations》2006,223(2):400-426
We first investigate in a logistic model the effects of migration and spatial heterogeneity of the environment on the total population size at equilibrium of a single species. Our study shows that (i) the total population size is maximized at some intermediate migration rate, and hence is a non-monotone function of the migration rate; (ii) heterogeneity of the environment increases the population size. In the second part of this paper, these findings are applied to ecological invasions. For a two-species Lotka-Volterra competition model with migration, we show that (i) without migration, the invading species eliminates the resident species at every point of the habitat, whereas when migration is present, for certain ranges of migration rates the invader may be eliminated when it is rare; and (ii) without migration, the two species can coexist at every point of the habitat, whereas when migration is present, for some ranges of migration rates one of the species is extinguished for all initial conditions. 相似文献