电声子相互作用对量子点分子中单电子隧穿的影响

研究了双量子点系统中的电子隧穿动力学过程，在考虑电子与声子相互作用的情况下用基于 正则变换的微扰方法解析地得到了电子动态隧穿电流的表达式. 并且详细分析电子与声子耦 合引起的退相干问题，在此基础上指出了可能的退耦机理. 关键词： 电声子相互作用 双量子点 隧穿     

二维复式格子声子晶体带隙结构特性

借助于平面波展开法分析了二维复式格子声子晶体能带结构，计算了铝合金柱体按周期性结构排列在空气中形成的二维固/气复合体系的声子晶体，给出了复式蜂窝格子和复式Kagome格子的能带结构，进而对比分析了复式格子和简单格子的能带结构特性.结果表明，与简单格子相比，复式格子的带隙出现在频率相对较低的位置；在f=0.091—0.6046范围内，将声子晶体排列为复式格子要优于简单格子，可以得到更宽带隙.此外，引入了带隙分布图，讨论了填充系数f对带隙数目、带隙宽度以及带隙上下边界频率的影响. 关键词： 声子晶体 复式格子 带隙 平面波算法     

QEPAS系统中石英音叉模态仿真计算与研究

对石英音叉增强型光声光谱(QEPAS)系统中常用的石英音叉进行了有限元模态计算，获得石英音叉前6阶振型与模态频率，认知了第4阶对称摆动振型为有效振动，利用单因素法分析了石英音叉的音臂长度l₁、音臂宽度w₁、音臂厚度t、音臂切角θ、音臂圆孔直径d及音臂圆孔高度h对低阶有效共振频率(Fre)的影响，敏感度依次为： l₁> w₁>d>θ>t>h，考虑实际设计情形，筛选出了l₁，w₁，d与h四个石英音叉设计变量，采用Box-Behnken实验设计方案与RSM(response surface methodology)方法，以Fre为函数目标，建立l₁，w₁，d与h的二次回归响应面模型，得到了参数之间的交互作用，利用Design-Expert软件对响应面模型进行设计参数反求，结果表明，在15 000 Hz≤Fre≤25 000 Hz计算区域内误差较小，基本满足QEPAS系统的计算需求，所提出的研究与设计方法具有一定通用性，可为QEPAS系统中石英音叉结构参数设计提供参考。     

Ordered space-time structures: Quantum carpets from Gaussian sum theory

The term "quantum carpet" can be observed in many closed quantum systems, where the evolution of a wave function exhibits a carpet-like pattern. Quantum carpet mechanisms are also akin to the classical interference patterns of light. Although the origins of quantum carpets have previously been studied by various researchers, many interesting details are still worth exploring. In this study, we present a unified framework for simultaneously analyzing three different features of quantum carpets: full revival,fractional revival, and diagonal canal. For the fractional revival feature, a complete formula is presented to explain its formation through Gaussian sum theory, in which all essential features, including phases and amplitudes, are captured analytically. We also reveal important relationships between the interference terms of diagonal canals and their geometric interpretations such that a better understanding of the development of diagonal canals can be supported.     

Amphiphilic Core–Shell Nanocomposite Particles for Enhanced Magnetic Resonance Imaging

A scalable synthesis of magnetic core–shell nanocomposite particles, acting as a novel class of magnetic resonance (MR) contrast agents, has been developed. Each nanocomposite particle consists of a biocompatible chitosan shell and a poly(methyl methacrylate) (PMMA) core where multiple aggregated γ‐Fe₂O₃ nanoparticles are confined within the hydrophobic core. Properties of the nanocomposite particles including their chemical structure, particle size, size distribution, and morphology, as well as crystallinity of the magnetic nanoparticles and magnetic properties were systematically characterized. Their potential application as an MR contrast agent has been evaluated. Results show that the nanocomposite particles have good stability in biological media and very low cytotoxicity in both L929 mouse fibroblasts (normal cells) and HeLa cells (cervical cancer cells). They also exhibited excellent MR imaging performance with a T₂ relaxivity of up to 364 mM_Fe^?1 s^?1. An in vivo MR test performed on a naked mouse bearing breast tumor indicates that the nanocomposite particles can localize in both normal liver and tumor tissues. These results suggest that the magnetic core–shell nanocomposite particles are an efficient, inexpensive and safe T₂‐weighted MR contrast agent for both liver and tumor MR imaging in cancer therapy.     

基于涡旋光束的超快速角向集束匀滑方案

针对惯性约束聚变装置对激光集束辐照均匀性的需求,提出了一种基于涡旋光束的超快速角向匀滑方案,即利用螺旋相位板使2×2集束中的两子束由超高斯光束变换为涡旋光束,而其余两子束不变,进而通过对子束偏振态和中心波长的调控,使集束中的涡旋光束和超高斯光束在靶面两两相干叠加.相干叠加后的焦斑以皮秒量级为周期超快速旋转,从而在极短时间内快速抹平焦斑强度调制,改善靶面辐照均匀性.通过建立基于螺旋相位板的激光超快速角向集束匀滑方案的物理模型,分析了其角向匀滑特性,并与光谱角色散技术和径向匀滑技术进行了比较分析.结果表明,这一新型激光集束匀滑方案能实现对焦斑的超快速角向匀滑,且能在数皮秒时间内达到最佳辐照均匀性.     

超高碰撞能23.84 kJ/mol下反应F+D2→DF+D的交叉分子束研究

本文搭建了一套新的实验设备,首次将氢原子里德堡态标记的飞行时间谱技术与激光爆破束源技术相结合,进行超高碰撞能下化学反应的动力学研究. 初步进行了F+D₂→DF+D在超高碰撞能23.84 kJ/mol下的实验研究. 在研究中应用了两种类型束源：一类是通过激光爆破过程产生的高能F原子束源,另一类是通过液氮冷却脉冲阀而产生的D₂束源. 实验中探测了反应产物振动态分辨的微分散射截面. 结果显示,大部分反应产物DF主要呈现侧向和后向散射分布,而产物DF(v''=4)则主要分布在前向. 对前向散射产物DF(v''=4)的动力学来源进行了讨论.     

一种强电磁脉冲辐射场均匀性校准测试装置

目前,辐射场均匀性主要采用单点多次测试的方式来实现,该方式将不可避免地引入因辐照信号自身时变特性带来的测量误差;此外,单点多次测试极大地增加了测试时间、测试效率低下。为解决这些问题,本文设计了一种可实现一次多点测试、测试区域可自动调节的装置,仿真表明：该装置可满足500 mm×500 mm~1500 mm×1500 mm区域辐射场9点均匀性测试;在此基础上,在1000 mm×1000 mm测试区域,针对1.35 GHz和2.88 GHz两个频点开展了实验验证,实验表明：设计的测试装置可满足辐射场均匀性9点自动测试要求,大幅提高了测试效率和自动化程度。     

钴络合物催化甲醇羰基化制甲酸甲酯反应的理论研究

本文运用密度泛函理论B3LYP方法,对C、O、H采用6-311+G(2d,p)基组,计算研究了钴络合物催化甲醇羰基化制甲酸甲酯反应的微观机理,优化了各反应物、中间体和过渡态的构型特征,用频率分析方法和内禀反应坐标方法对过渡态进行了验证,同时对各中间体进行电荷分析.对比了催化过程与非催化过程的能垒.结果表明,有催化剂参与后反应活化能明显降低.     

Image encryption using exclusive-OR with DNA complementary rules and double random phase encoding

We propose an optical image encryption scheme based on the Deoxyribonucleic Acid (DNA) theory and the double random phase encoding (DRPE) technique. The piecewise linear chaotic map (PWLCM) is used to generate key images and random phase masks, and to determine DNA encoding rules. In order to achieve ultra-fast DNA encryption, we propose using an optical exclusive-OR (XOR) gate to achieve XOR operation in DNA encryption. Different plaintexts use different initial values of PWLCM, which are generated by Message Digest Algorithm 5 (MD5). The plaintext is encrypted by two rounds of DNA and then by DRPE to form a ciphertext. Numerical simulation and the analysis of attacks on encrypted image are implemented to demonstrate the security and validity of the proposed approach.