全文获取类型
收费全文 | 112篇 |
免费 | 92篇 |
国内免费 | 101篇 |
专业分类
化学 | 141篇 |
数学 | 4篇 |
物理学 | 160篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 4篇 |
2019年 | 1篇 |
2018年 | 9篇 |
2017年 | 5篇 |
2016年 | 7篇 |
2015年 | 7篇 |
2014年 | 7篇 |
2013年 | 7篇 |
2012年 | 19篇 |
2011年 | 25篇 |
2010年 | 24篇 |
2009年 | 28篇 |
2008年 | 25篇 |
2007年 | 15篇 |
2006年 | 25篇 |
2005年 | 19篇 |
2004年 | 14篇 |
2003年 | 18篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
排序方式: 共有305条查询结果,搜索用时 15 毫秒
91.
近年来 ,以钌 ( )多吡啶配合物为探针研究 DNA的结构已成为生物无机化学领域中的一个热点[1,2 ] .这些配合物由于热力学稳定性好 ,光化学和光物理信息丰富 ,在研究 DNA内部的电子转移和Fig.1 Structures of the ligandsDNA的结构识别等方面均有重要的作用[3~ 7] .在配合物与 DNA的相互作用中 ,配合物的形状、大小以及中心离子电荷等都有一定的影响[8] ,其中 ,配合物的形状起着至关重要的作用 ,与 DNA的形状匹配的配合物与DNA的结合较强 .这些配合物中通常含有平面性较大的芳香环配体 ,可插入到 DNA的碱基对之间 ,并与 DNA具有… 相似文献
92.
We study the kinetic behavior of a two-species aggregation-migration model in which an irreversible aggregation
occurs between any two clusters of the same species and a reversible migration occurs simultaneously between two different species. For a simple model with constant aggregation rates and
with the migration rates
KA(i;j)=K'A(i;j) ∝ijv1 and
KB(i;j)=K'B(i;j) ∝ijv2, we find that the evolution behavior of the system depends crucially on the
values of the indexes v1 and v2. The aggregate size
distribution of either species obeys a conventional scaling law for most cases. Moreover, we also generalize the two-species system to the multi-species case and analyze its kinetic behavior
under the symmetrical conditions. 相似文献
93.
GUO Jian-Hong 《理论物理通讯》2004,41(1):37-40
The interaction of $N$ two-level atoms with both a two-mode cavity
field and an external classical pumping field, and with the fields being
degenerate in frequency, is studied in the regime where the atoms
and fields are highly detuned. This dispersive interaction
can be used to generate a large number of important entangled coherent states
conditional on the initial atomic states and state-selective measurements.
A dynamical relation is established between the results for the case with continuous
pumping and the case without external driving where the coherent field is
put in as the initial condition. 相似文献
94.
Yi-Wen Chung Ing-Chi Leu Jian-Hong Lee Min-Hsiung Hon 《Colloids and surfaces. A, Physicochemical and engineering aspects》2006,290(1-3):256-262
High-quality polystyrene (PS) colloidal photonic crystals in large area were fabricated in 24 h via a capillary-enhanced process. Then, the photonic crystals with core-shell structure were obtained by incorporating silica nanoparticles into the interstitial space of opal template via a dipping process. The filling ratio (Vsilica) of interstitial space could be manipulated by dipping colloidal crystals into suspensions with different concentrations of silica nanoparticles, which in turn renders the obtained core-shell photonic crystals. The absorptive peak of opal without dipping process is at 445 nm as measured by UV–vis spectrometry. The filling ratios of 0.130, 0.167 and 0.253 can be calculated according to the modified Bragg's Law, which corresponds to the absorptive peaks for core-shell opals at 453, 463 and 469 nm obtained from suspensions with silica nanoparticles of 0.017, 0.122, and 0.244 wt%, respectively. Therefore, by using this dipping process, the characteristic absorption wavelength for photonic crystal will be varied easily, efficiently and cost effectively than that by traditional methods for constructing opal from monodispersed colloids of different diameters. 相似文献
95.
激光蒸发产生钽钌酸铅团簇负离子的研究巨新,杨建红,施朝淑,张南,高振,孔繁敖,朱起鹤(中国科学技术大学,合肥,230026)(中国科学院化学研究所,北京)关键词团簇离子,激光蒸发,奇偶性厚膜电阻以RuO2、Pb2Ru2O7或Bi2Ru2O7作导电相,... 相似文献
96.
97.
Hao-Wei Chang Ruei-Yi Shiu Ching-Shiang Fang Jian-Hong Liao Pilli V. V. N. Kishore Samia Kahlal Jean-Yves Saillard C. W. Liu 《Journal of Cluster Science》2017,28(2):679-694
Two luminescent, monoanionic chalcogenide-centered nonanuclear silver clusters stabilized by dichalcogenophosphates were synthesized and fully characterized by various spectroscopies including multinuclear NMR and ESI-mass. Single crystal X-ray diffraction studies on both cluster anions, [Ag9(S){S2P(OEt)2}8]?, 1, and [Ag9(Se){Se2P(OEt)2}8]?, 2, reveal that the nine silver atoms form an extremely distorted tricapped trigonal prism, which has an encapsulating chalcogenide. The coordination geometry of the central chalcogenide appears to be monocapped trigonal prismatic, which was analyzed by DFT calculations. The origin of the yellow emission is assigned by TDDFT calculations to originate from a chalcogen (ligand + encapsulated) → silver charge transfer. 相似文献
98.
以乙醇为溶剂, 钛酸四丁酯为前驱体, 用溶剂热法制备了Ag表面修饰的负载型纳米二氧化钛光催化剂. 利用X射线衍射(XRD)、N2吸附-脱附(BET)、透射电子显微镜(TEM)、X射线光电子能谱(XPS)、紫外-可见(UV-Vis)光谱等技术对其进行了系统的表征, 以亚甲基蓝(MB)溶液的脱色降解为模型反应, 考察了不同Ag含量样品的光催化性能. 结果表明: 用溶剂热法制备的样品中TiO2皆为锐钛矿相, 金属Ag颗粒沉积在TiO2表面, 粒径为2 nm左右, 比表面积较溶胶凝胶法制备的样品大大增加, 最高可达151.44 m2·g-1; UV-Vis光谱和光催化实验表明: Ag修饰使TiO2对光的吸收能力大大增强, 吸收带边红移至可见光区, 亚甲基蓝在该复合材料上的光催化降解反应遵循一级反应动力学模型; 溶剂热法制备样品的光催化性能明显好于溶胶凝胶法制备的样品, 在紫外光和可见光下, Ag摩尔分数为5%的样品表现出最佳的光催化活性. 相似文献
99.
Li YJ Latouche C Kahlal S Liao JH Dhayal RS Saillard JY Liu CW 《Inorganic chemistry》2012,51(14):7439-7441
Two luminescent, undecanuclear silver complexes [Ag(11)(μ(9)-I)(μ(3)-I)(3){E(2)P(O(i)Pr)(2)}(6)](PF(6)) [E = S (yellow), 1; Se (orange), 2], containing the first μ(9)-iodine inscribed at the center of a pentacapped trigonal-prismatic silver skeleton, were reported. 相似文献
100.
在一维海森堡模型的基础上,采用界面参数化方法,将双层异质磁薄膜中自旋波本征值问题归结为联立求解能量约束方程和界面参数化方程.重点讨论体系中体模和完全禁闭模的波形演化过程,发现体系中体模波形随自旋波矢呈余弦变化,会出现局域共振现象.激发能对两子层中体模有较大的影响,不仅影响体模的振幅,而且还影响体模的波长.另外,激发能对体系中的完全禁闭模也有较大影响,随着激发能增大,铁磁层中完全禁闭模波长变短,波速变小,但振幅不变. 相似文献