全文获取类型
收费全文 | 50194篇 |
免费 | 2665篇 |
国内免费 | 2571篇 |
专业分类
化学 | 28363篇 |
晶体学 | 959篇 |
力学 | 2506篇 |
综合类 | 218篇 |
数学 | 5244篇 |
物理学 | 18140篇 |
出版年
2022年 | 591篇 |
2021年 | 728篇 |
2020年 | 749篇 |
2019年 | 834篇 |
2018年 | 970篇 |
2017年 | 945篇 |
2016年 | 1352篇 |
2015年 | 1097篇 |
2014年 | 1496篇 |
2013年 | 2613篇 |
2012年 | 2703篇 |
2011年 | 3096篇 |
2010年 | 2271篇 |
2009年 | 2331篇 |
2008年 | 2598篇 |
2007年 | 2499篇 |
2006年 | 2346篇 |
2005年 | 1945篇 |
2004年 | 1823篇 |
2003年 | 1564篇 |
2002年 | 1623篇 |
2001年 | 1948篇 |
2000年 | 1373篇 |
1999年 | 1121篇 |
1998年 | 817篇 |
1997年 | 714篇 |
1996年 | 632篇 |
1995年 | 575篇 |
1994年 | 525篇 |
1993年 | 475篇 |
1992年 | 511篇 |
1991年 | 511篇 |
1990年 | 498篇 |
1989年 | 460篇 |
1988年 | 468篇 |
1987年 | 451篇 |
1986年 | 393篇 |
1985年 | 457篇 |
1984年 | 476篇 |
1983年 | 347篇 |
1982年 | 388篇 |
1981年 | 378篇 |
1980年 | 320篇 |
1979年 | 402篇 |
1978年 | 375篇 |
1977年 | 392篇 |
1976年 | 390篇 |
1975年 | 340篇 |
1974年 | 317篇 |
1973年 | 333篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
A new method for the synthesis of exfoliated graphite and polyaniline (PANI)/graphite nanocomposites was developed. Exfoliated graphite nanosheets were prepared through the microwave irradiation and sonication of synthesized expandable graphite. The nanocomposites were fabricated via the in situ polymerization of the monomer at the presence of graphite nanosheets. The as-synthesized graphite nanosheets and PANI/graphite nanocomposite materials were characterized with Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, and thermogravimetric analysis (TGA). The conductivity of the PANI/graphite nanocomposites was dramatically increased over that of pure PANI. TGA indicated that the incorporation of graphite greatly improved the thermal stability of PANI. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1972–1978, 2004 相似文献
102.
George Z. Papageorgiou George P. Karayannidis Dimitris N. Bikiaris Anagnostis Stergiou George Litsardakis Sofoklis S. Makridis 《Journal of Polymer Science.Polymer Physics》2004,42(5):843-860
The crystallization behavior of a series of poly(ethylene‐co‐butylene naphthalate) (PEBN) random copolymers was studied. Wide‐angle X‐ray diffraction (WAXD) patterns showed that the crystallization of these copolymers could occur over the entire range of compositions. This resulted in the formation of poly(ethylene naphthalate) or poly(butylene naphthalate) crystals, depending on the composition of the copolymers. Sharp diffraction peaks were observed, except for 50/50 PEBN. Eutectic behavior was also observed. This showed isodimorphic cocrystallization of the PEBN copolymers. The variation of the enthalpy of fusion of the copolymers with the composition was estimated. The isothermal and nonisothermal crystallization kinetics were studied. The crystallization rates were found to decrease as the comonomer unit content increased. The tensile properties were also measured and were found to decrease as the butylene naphthalate content of the copolymers increased. For initially amorphous specimens, orientation was proved by WAXD patterns after drawing, but no crystalline reflections were observed. However, the fast crystallization of drawn specimens occurred when they were heated above the glass‐transition temperature. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 843–860, 2004 相似文献
103.
Ionel Rosenthal Joe Z. Sostaric Peter Riesz 《Research on Chemical Intermediates》2004,30(7-8):685-701
Sonochemistry and photochemistry are initiated by high-energy transient species, which may be prone to mutual interaction. Electronic excitation of solutes by energy transfer from high energy species generated in collapsing bubbles is already supported by experimental evidence. The rates of photochemical reactions can be affected by ultrasound-induced mixing of liquids caused by microstreaming near pulsating cavitation bubbles and shockwaves due to bubble collapse. This may not only improve light absorption but also modify the pathway of reaction by increasing the contact between reagents. Finally, one may speculate about a potentially new chemistry of photoexcited solutes under the extreme conditions inside cavitation microreactors. This work reviews research on the excitation of solutes by sonoluminescence, the combined effects of ultrasound and light on liquid systems and the effect of ultrasound on photocatalytic reactions. 相似文献
104.
105.
半自由声场环境下的声源重建和声场预测研究对声全息技术走向实际应用具有非常重要的意义.在提出基于分布源边界点法的半自由声场全息重建和预测方法的基础上,对此展开了实验研究.并将重建和预测的结果与常规方法重建和预测的结果进行了比较和讨论,说明了重建预测过程中反射声压的影响和考虑反射声压的必要性,证明了所提出方法在解决半自由声场环境下存在地面反射时的声源重建和声场预测时的有效性和准确性.还提出了采用奇异值截断滤波和Tikhonov正则化方法来削弱测量误差的影响,从而进一步优化了重建结果,提高了全息成像的可信度.
关键词:
声全息
半自由场
边界点
声辐射
反射声 相似文献
106.
稀土固体是重要的激光和光电子材料。目前 ,由于以宽带信号和太赫兹比特数据传输率为特征的信息技术的发展 ,稀土固体材料的相干瞬态动力学过程成为宽带与高速信息光子学的基本物理问题之一。研究了室温下稀土粉末样品Eu3+ ∶Y2 O3自由感应衰减的相干瞬态光谱 ,这有助于理解有效的光吸收动力学、激发态弛豫、相干能量传递和超短光脉冲在稀土固体中的传播。用一对紫外飞秒相干光脉冲作用于稀土粉末样品Eu3+ ∶Y2 O3,然后监测物质激发态的布居数随两个激发脉冲之间的延时的变化 ,测量到其自由感应衰减量子拍 (FID) ,从拍频周期分析确定了其能级精细结构 ,能级的退相时间长达皮秒量级。理论分析和实验结果符合得很好。对稀土离子的量子干涉的研究 ,表明其在受激受控光放大方面具有潜在的应用前景 相似文献
107.
The adsorption of polar organic substances (methanol, pyridine, and acetonitrile) and water was studied from the vapor phase on microporous adsorbent prepared by the substitution of polyhydroxyaluminum ions for the sodium ions of natural montmorillonite clay. The differential isosteric heats of adsorption of these substances were calculated and analyzed in a wide range of fillings. 相似文献
108.
JianXinCAO YiFengWANG GuoFangLAI ShiDeLUO 《中国化学快报》2004,15(7):797-800
From the dried aerial part ofParepigynumfuningesis Tsiang et P. T. Li (Apocynaceae),a new cardiac glucoside, named parefuningoside (1) had been isolated. Its structure was determined by means of hydrolysis and spectral analysis. 相似文献
109.
WeiMinSHI JianWU YiFengWU KaiXianQIAN 《中国化学快报》2004,15(12):1427-1429
A mono-funtionalised tetraphenylporphyrin (TPP) bearing valine moiety at the phenyl ring was synthesized for photocytotoxicity examination in four steps, starting from regiospecific mono-nitration of TPP at the phenyl ring. The in vitro photocytotoxicitic effect against SPC-Al adenocarcinona cell line was tested. 相似文献
110.
Ming Zhao WANG Guan Liang CAI Ling XIA Jun Jian YAO Hong Yan CHEN Zhao Xing MENG Bo Li LIUDepartment of Chemistry Beijing Normal University Beijing Chemical Defense Institute PLA Beijing 《中国化学快报》2004,15(4):495-497
The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents. 相似文献