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121.
烷基苯的热力学性质与分子拓扑指数的关系研究   总被引:6,自引:0,他引:6  
此文分析了烷基苯的结构特点,以分子的拓扑指数为结构参数,研究了苯、烷基系列的燃烧热,生成自由能等八种热力学性质与结构参数的关系,提出计算热力学性质的一个通用关系式Y=a·N+b·R+c·NR+d,用计算机处理,得到一系列经验公式,计算结果表明:烷基苯系列的热力学性质与拓扑指数相关性能很好。  相似文献   
122.
颗粒滚动摩擦系数对堆积特性的影响   总被引:7,自引:0,他引:7       下载免费PDF全文
韩燕龙  贾富国  唐玉荣  刘扬  张强 《物理学报》2014,63(17):174501-174501
为探讨颗粒摩擦系数对堆积特性的影响,利用离散单元法,模拟静摩擦系数固定时,变化滚动摩擦系数对椭球形颗粒堆积角及堆积体的影响.利用自制斜面仪测定了颗粒静摩擦系数,并对滚动摩擦系数与堆积角建立线性方程.结果表明,滚动摩擦系数对颗粒堆积特性有显著影响,颗粒堆积角随滚动摩擦系数增大而增大,边界圆与连续圆间的间隙随滚动摩擦系数增大而减小.依据颗粒堆积过程中旋转动能的变化可以阐述上述结果,建立的滚动摩擦系数与堆积角的线性方程可为具体颗粒物料滚动摩擦系数的获取提供数值测量思路.模拟堆积的过程可为散体物料一些不易测量的参数进行虚拟实验标定.  相似文献   
123.
We systematically investigate the polarization gradient cooling (PGC) process in an optical molasses of ultracold cesium atoms. The SR mode for changing the cooling laser, which means that the cooling laser frequency is stepped to the setting value while its intensity is ramped, is found to be the best for the PGC, compared with other modes studied. We verify that the heating effect of the cold atoms, which appears when the cooling laser intensity is lower than the saturation intensity, arises from insufficient polarization gradient cooling. Finally, an exponential decay function with a statistical explanation is introduced to explain the dependence of the cold atom temperature on the PGC interaction time.  相似文献   
124.
The surface and interfacial properties of polymers are important for their applications. In one of our previous articles, we discussed the relationship between the dispersive surface tension component and the density and molecular weight of solvents and polymers to seek a simple and easy method to estimate the rationality of surface tension results of polymers. We found that for 30 organic solvents and 12 polymers, there was a good relationship between the dispersive surface tension and the experiential parameter 1/ρ2 M 0.2 w . In this article, the existence of the squared density term is simply deduced from the general molecular interaction energy equation and is proved with four pairs of polymer/monomer; these are polystyrene/styrene, polyisoprene/isoprene, polymethyl methacrylate/methyl methacrylate, and polyvinyl acetate/vinyl acetate.  相似文献   
125.
An axisymmetric-fold-combination (ASFC) cavity composed of two planar mirrors and spherical mirrors was designed. It is a stable-unstable resonator cavity. The light field of radial direction is Gaussian distribution. And in angular orientation, the distribution keeps invariant. It could generate annular CO2 laser beam with excellent spatial coherence. And the spatial coherence is commendably realized with its stable-unstable cavity structure. The output light intensity distribution of this special model was discussed and simulated. With exterior lenses group, the output beams can be adjusted and controlled better to meet the manufactural requirements. Some references were provided for further research of the cavity with cylindrical discharge region.  相似文献   
126.
The wettability of calcite cubes was tuned by varying the sizes of the polystyrene nanoparticles attached to their surfaces via a dispersion polymerization. The products were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersion spectrum (EDS) and Fourier transformation infrared spectrum (FTIR). The results showed that the hydrophobicity of the calcite cubes was enhanced with the increase of the size of the polystyrene nanoparticles attached. Using polystyrene nanoparticle-attached calcite cubes (PNACC) as emulsifiers, stable water-in-tricaprylin Pickering emulsions were produced. By gelling the water droplets of the Pickering emulsions, the hierarchical structures of polystyrene nanoparticle-attached calcite cube-armored microspheres were obtained. The polystyrene nanoparticle-attached calcite cubes were expected to have novel surface properties similar neither to traditional Pickering particles, nor to macroscopically asymmetrical Janus particles.  相似文献   
127.
We have theoretically investigated the transmission performance of the optical mm-wave generation by using an external modulator based on single sideband (SSB) intensity modulation. Though the SSB millimeter (mm)-wave can immune the fading effect, the baseband signals with a high bit rate are degraded greatly after transmission along fiber. The main reason is that the fiber dispersion causes the time shift of the code edges; therefore the maximum transmission distance of the baseband signals is limited. The experimental and simulation results agree well with our theoretical analysis. We also propose a novel scheme to extend the transmission distance. In this novel scheme, the data signals are modulated only onto one of the two optical carriers; hence the shift of the code edges in the down-converted signals after transmission is eliminated.  相似文献   
128.
An analytical formula for the average intensity of cosh-Gaussian (ChG) beams diffracted by an aperture in turbulent atmosphere is derived and some limiting cases are discussed. By using the average intensity formula, some numerical simulation comparisons are made and some special cases are studied, especially the influences of the ChG beam parameter (Ω0), the propagation distance, the aperture and its size on the average normalized intensity distribution. It is determined that the evolution properties of the average normalized intensity profile in turbulent atmosphere with aperture are different not only from those of free space with aperture but also from those in turbulent atmosphere without aperture. PACS 42.68.Bz; 42.79.Ag; 42.25.Fx  相似文献   
129.
基于微观sdIBM-2方案和实验单粒子能量值, 在最普遍的哈密顿量下, 用两组不同的核子-核子等效相互作用参数, 分别很好地再现了102Ru核的振动带能谱和转动带能谱及其演化过程. 微观和唯象的研究指认: 1) 这两种激发模式的共存区是能态8+1—12+1(即Ex=2.500—4.000 MeV); 态 8+1关键词: 微观sdIBM-2方案 形状演化 玻色子 102Ru核')" href="#">102Ru核  相似文献   
130.
李思众  鱼云岐  陈静  郭佳 《应用光学》2013,34(4):644-647
介绍一种用于检测多光路光电设备光轴平行性的测试系统,该系统采用准直平行光管提供无穷远目标,并融合了CCD图像采集处理和计算机技术,通过计算目标靶十字中心和激光光斑中心之间在CCD上的像素跨距,计算出红外、可见光以及激光三轴相互间的平行性误差,系统的计算误差小于5。  相似文献   
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