全文获取类型
收费全文 | 3027篇 |
免费 | 138篇 |
国内免费 | 9篇 |
专业分类
化学 | 2164篇 |
晶体学 | 3篇 |
力学 | 49篇 |
数学 | 438篇 |
物理学 | 520篇 |
出版年
2023年 | 26篇 |
2022年 | 21篇 |
2021年 | 51篇 |
2020年 | 60篇 |
2019年 | 68篇 |
2018年 | 37篇 |
2017年 | 32篇 |
2016年 | 89篇 |
2015年 | 112篇 |
2014年 | 107篇 |
2013年 | 169篇 |
2012年 | 249篇 |
2011年 | 237篇 |
2010年 | 139篇 |
2009年 | 135篇 |
2008年 | 152篇 |
2007年 | 166篇 |
2006年 | 179篇 |
2005年 | 155篇 |
2004年 | 171篇 |
2003年 | 121篇 |
2002年 | 97篇 |
2001年 | 59篇 |
2000年 | 35篇 |
1999年 | 40篇 |
1998年 | 41篇 |
1997年 | 39篇 |
1996年 | 25篇 |
1995年 | 39篇 |
1994年 | 38篇 |
1993年 | 19篇 |
1992年 | 25篇 |
1991年 | 24篇 |
1990年 | 14篇 |
1989年 | 20篇 |
1988年 | 12篇 |
1987年 | 8篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 11篇 |
1981年 | 7篇 |
1980年 | 6篇 |
1979年 | 24篇 |
1978年 | 14篇 |
1977年 | 12篇 |
1976年 | 10篇 |
1974年 | 7篇 |
1973年 | 11篇 |
1970年 | 4篇 |
排序方式: 共有3174条查询结果,搜索用时 15 毫秒
951.
Eisert J 《Physical review letters》2004,92(21):210401
In this Letter it is shown that exact decoherence to minimal uncertainty Gaussian pointer states is generic for free quantum particles coupled to a heat bath. More specifically, the Letter is concerned with damped free particles linearly coupled under product initial conditions to a heat bath at arbitrary temperature, with arbitrary coupling strength and spectral densities covering the Ohmic, sub-Ohmic, and supra-Ohmic regime. Then it is true that there exists a time t(c) such that for times t>t(c) the state can always be exactly represented as a mixture (convex combination) of particular minimal uncertainty Gaussian states, regardless of and independent from the initial state. This exact "localization" is hence not a feature specific to high temperature and weak damping limit, but is a generic property of damped free particles. 相似文献
952.
Steffen Hamann Jens Folke Kiilgaard Thomas Litman Francisco J. Alvarez-Leefmans Benny R. Winther Thomas Zeuthen 《Journal of fluorescence》2002,12(2):139-145
At high concentrations, certain fluorophores undergo self-quenching, i.e., fluorescence intensity decreases with increasing fluorophore concentration. Accordingly, the self-quenching properties can be used for measuring water volume changes in lipid vesicles. In cells, quantitative determination of water transport using fluorescence self-quenching has been complicated by the requirement of relatively high (mM) and often toxic loading concentrations. Here we report a simple method that uses low (M) loading concentrations of calcein-acetoxymethyl ester (calcein-AM) to obtain intracellular concentrations of the fluorophore calcein suitable for measurement of changes in cell water volume by self-quenching. The relationship between calcein fluorescence intensity, when excited at 490 nm (its excitation maximum), and calcein concentration was investigated in vitro and in various cultured cell types. The relationship was bell-shaped, with the negative slope in the concentration range where the fluorophore undergoes fluorescence self-quenching. In cultured retinal pigment epithelial cells, calcein fluorescence and extracellular osmolarity were linearly related. A 25-mOsm hypertonic challenge corresponded to a decrease in calcein fluorescence with high signal-to-noise ratio (>15). Similar results were obtained with the fluorophore BCECF when excited at its isosbestic wavelength (436 nm). The present results demonstrate the usefulness of fluorescence self-quenching to measure rapid changes in cell water volume. 相似文献
953.
We present a general necessary and sufficient criterion for the possibility of a state transformation from one mixed Gaussian state to another of a bipartite continuous-variable system with two modes. The class of operations that will be considered is the set of local Gaussian completely positive trace-preserving maps. 相似文献
954.
Fourth-order magnetic anisotropy and tunnel splittings in Mn(12) from spin-orbit-vibron interactions
From density-functional-theory based methods, we calculate the vibrational spectrum of the Mn(12)O(12)(COOH)(16)(H(2)O)(4) molecular magnet. Calculated infrared intensities are in accord with experimental studies. There have been no ab initio attempts at determining which interactions account for the fourth-order anisotropy. We show that vibrationally induced distortions of the molecule contribute to the fourth-order anisotropy Hamiltonian and that the magnitude and sign of the effect (-6.2 K) is in good agreement with all experiments. Vibrationally induced tunnel splittings in isotopically pure and natural samples are predicted. 相似文献
955.
Baragaña B Blackburn AG Breccia P Davis AP de Mendoza J Padrón-Carrillo JM Prados P Riedner J de Vries JG 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(13):2931-2936
The cationic steroidal receptors 9 and 11 have been synthesized from cholic acid 3. Receptor 9 extracts N-acetyl-alpha-amino acids from aqueous media into chloroform with enantioselectivities (L:D) of 7-10:1. The lipophilic variant 11 has been employed for the enantioselective transport of N-acetylphenylalanine, a) through dichloromethane (DCM) and dichloroethane (DCE) bulk liquid membranes (U-tube apparatus), and b) through 2.5% (v/v) octanol/hexane via hollow fibre membrane contactors. Significant enantioselectivities and multiple turnovers were observed for both types of apparatus. 相似文献
956.
957.
The automated structure elucidation of organic molecules from experimentally obtained properties is extended by an entirely new approach. A genetic algorithm is implemented that uses molecular constitution structures as individuals. With this approach, the structure of organic molecules can be optimized to meet experimental criteria, if in addition a fast and accurate method for the prediction of the used physical or chemical features is available. This is demonstrated using 13C NMR spectrum as readily obtainable information. By means of artificial neural networks a fast and accurate method for calculating the 13C NMR spectrum of the generated structures exists. The method is implemented and tested successfully for organic molecules with up to 18 non-hydrogen atoms. 相似文献
958.
A general NMR method is presented that allows a precise determination of the second-order rate constant, k(ese), for the electron self-exchange in blue copper proteins, from the longitudinal relaxation rates of the nuclei in the protein. The method relies on the use of partly oxidized (paramagnetic) samples of the protein. In contrast to previous NMR approaches for the determination of electron self-exchange rates, the applicability of the method extends beyond the slow-exchange limit, k(ese)c < R(ip), i = 1, 2, where c is the protein concentration, and R(ip) is the paramagnetic relaxation enhancement of the observed nuclei. 相似文献
959.
960.
Many active organic compounds and organic effect materials are poorly soluble in water, or even insoluble. Aqueous forms of application thus require special formulation techniques to utilize or optimize the physiological (pharmaceuticals, cosmetics, plant protection, nutrition) or technical (varnishes, printing inks, toners) action. The most interesting properties of nanodispersions of active organic compounds and effect materials include the impressive increase in solubility, the improvement in biological resorption, and the modification of optical, electrooptical, and other physical properties which are achievable only with particle sizes in the middle or lower nanometer range (50-500 nm). Hence in addition to economic and ecological constraints there are also technical demands which appear to urgently require the development of new processes for the production of organic nanoparticles as alternatives to the established mechanical milling processes. In this context attention is drawn to the recent increase in research activities which have as their objective the continuous, automatic preparation of nanodispersed systems by precipitation from molecular solution. In this review the current state of knowledge of the fundamentals of particle formation from homogeneous solution and the effect of solvent and polymer additives on the morphology and supramolecular structure of the nanoparticle will be discussed. The practical implementation of this new formulation technology will be explored in detail for the carotenoids, a class of compounds of both physiological and technical interest. 相似文献