A fused ladder indacenodithiophene (IDT)‐based donor–acceptor (D–A)‐type alternating conjugated polymer, PIDTHT‐BT, presenting n‐hexylthiophene conjugated side chains is prepared. By extending the degree of intramolecular repulsion through the conjugated side chain moieties, an energy level for the highest occupied molecular orbital (HOMO) of –5.46 eV – a value approximately 0.27 eV lower than that of its counterpart PIDTDT‐BT – is obtained, subsequently providing a fabricated solar cell with a high open‐circuit voltage of approximately 0.947 V. The hole mobility (determined using the space charge‐limited current model) in a blend film containing 20 wt% PIDTHT‐BT) and 80 wt% [6,6]‐phenyl‐C71 butyric acid methyl ester (PC71BM) is 2.2 × 10–9 m2 V–1 s–1, which is within the range of reasonable values for applications in organic photovoltaics. The power conversion efficiency is 4.5% under simulated solar illumination (AM 1.5G, 100 mW cm–2).
A novel sensing material, MnFe2O4/polyaniline (PANI), was fabricated by doping PANI to MnFe2O4 on a modified glassy carbon electrode (GCE). This sensing material was characterized using X‐ray diffraction (XRD), scanning electron microscopy (SEM), and high‐resolution transmission electron microscopy (HR‐TEM). Using a cyclic voltammetry electrochemical‐sensing method, we tested MnFe2O4/PANI, and an acetaminophen concentration of 0.0625–5 mM was recorded. Furthermore, the sensor responses were 2.05–22.44. The detection limit was 2.23 × 10?7 M. Strong selectivity was observed for MnFe2O4/PANI, which is a possible sensing mechanism. 相似文献
Journal of Solid State Electrochemistry - Lithium ionic intercalation and conduction performance of tantalum oxides films improved by adding with iron oxides using an atmospheric pressure plasma... 相似文献
The one‐electron oxidations of a Fe2 complex lead to the formation of a persistent metal‐stabilized thiyl radical Fe2 species, mixed‐valent Fe4, and Fe8 complexes. The unpaired spin in the Fe2 radical species delocalizes over the Fe2 and the aromatic dithiolate, mostly on the terminal sulfur. The subsequent dimerization of the singly oxidized Fe2 to the Fe4 retains the partial thiyl radical character. For an analogue with less steric hindrance, the π–π stacking interaction between the dithiolato aromatic rings induces generation of the Fe8, in which process electronic structures of the species are modulated through reducing the thiyl radical to the thiolate. Electronic reorganization repeats when the Fe8 is converted to Fe4. Electronic interplay in the complexes decreases the energy gap of frontier MOs and buffers electronic impacts upon redox events. Easier accessible redox potentials and increased stability of the species are facilitated. The results demonstrate that electronic versatility of the benzenedithiolate exerts pronounced influences on electronic and coordination structure of the metal complexes. 相似文献
An investigation is conducted on enhancing lithium-ion intercalation and conduction performance of transparent organo tantalum oxide (TaOyCz) films, by addition of lithium via a fast co-synthesis onto 40 Ω/□ flexible polyethylene terephthalate/indium tin oxide substrates at the short exposed durations of 33–34 s, using an atmospheric pressure plasma jet (APPJ) at various mixed concentrations of tantalum ethoxide [Ta(OC2H5)5] and lithium tert-butoxide [(CH3)3COLi] precursors. Transparent organo-lithiated tantalum oxide (LixTaOyCz) films expose noteworthy Li+ ion intercalation and conduction performance for 200 cycles of reversible Li+ ion intercalation and deintercalation in a 1 M LiClO4-propylene carbonate electrolyte, by switching measurements with a potential sweep from ?1.25 to 1.25 V at a scan rate of 50 mV/s and a potential step at ?1.25 and 1.25 V, even after being bent 360° around a 2.5-cm diameter rod for 1000 cycles. The Li+ ionic diffusion coefficient and conductivity of 6.2?×?10?10 cm2/s and 6.0?×?10?11 S/cm for TaOyCz films are greatly progressed of up to 9.6?×?10?10 cm2/s and 7.8?×?10?9 S/cm for LixTaOyCz films by co-synthesis with an APPJ. 相似文献
Density contrasts in the universe are governed by scalar cosmological perturbations which, when expressed in terms of gauge-invariant variables, contain a classical component from scalar metric perturbations and a quantum component from inflaton field fluctuations. It has long been known that the effect of cosmological expansion on a quantum field amounts to squeezing. Thus, the entropy of cosmological perturbations can be studied by treating them in the framework of squeezed quantum systems. Entropy of a free quantum field is a seemingly simple yet subtle issue. In this paper, different from previous treatments, we tackle this issue with a fully developed nonequilibrium quantum field theory formalism for such systems. We compute the covariance matrix elements of the parametric quantum field and solve for the evolution of the density matrix elements and the Wigner functions, and, from them, derive the von Neumann entropy. We then show explicitly why the entropy for the squeezed yet closed system is zero, but is proportional to the particle number produced upon coarse-graining out the correlation between the particle pairs. We also construct the bridge between our quantum field-theoretic results and those using the probability distribution of classical stochastic fields by earlier authors, preserving some important quantum properties, such as entanglement and coherence, of the quantum field. 相似文献
A new solution route for preparing gram-scale, hydrogen terminated silicon nanoparticles is presented. Dimethoxyethane and diocytl ether have been used to prepare silicon nanoparticles via a solution reaction between sodium silicide and ammonium bromide. The reaction products are isolated as a clear yellow-orange solution and a dark black powder. Both the solution and the powder have been characterized. 相似文献
ABSTRACT An analytical computer simulation procedure for dynamic modeling of low-contact-ratio spur gear systems is presented. The procedure computes the gear static transmission error and uses a Fast Fourier Transform (FFT) to generate its frequency spectrum at various tooth profile modifications. The dynamic loading response of an unmodified (perfect involut) gear pair is compared with that of gears with profile modifications. Correlations are found between several profile modifications and the resulting dynamic loads. An effective error, obtained from frequency domain anal 相似文献