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排序方式: 共有443条查询结果,搜索用时 15 毫秒
91.
92.
Jean-Baptiste Baugros Cécile Cren-Olivé Barbara Giroud Jean-Yves Gauvrit Pierre Lantéri Marie-Florence Grenier-Loustalot 《Journal of chromatography. A》2009,1216(25):4941-4949
The study proposes an analytical method to quantify 10 alkylphenols and 12 pesticides at ultra-trace levels by liquid chromatography in reverse mode coupled to positive electrospray ionisation–tandem mass spectrometry. The extraction procedure from environmental solids was optimised by pressurised liquid extraction using acetonitrile:isopropanol (1:1, v/v). The influence of several extraction experimental factors, temperature, pressure, duration and number of cycles, related to the PLE was investigated by an original and efficient chemometric approach. The optimised extraction method (80 °C, 40 bar, 10 min, 1 cycle) exhibited recoveries between 67 and 127% with RSD mostly under 13%. The whole method was applied to real samples: sludge, suspended materials, atmospheric fallouts and roof deposit. Pollutant levels were between 1 μg kg−1 and 5.9 mg kg−1. 相似文献
93.
Max Schütz Christian Gemel Maximilian Muhr Christian Jandl Samia Kahlal Jean-Yves Saillard Roland A. Fischer 《Chemical science》2021,12(19):6588
Cluster growth reactions in the system [Cu5](Mes)5 + [Al4](Cp*)4 (Mes = mesitylene, Cp* = pentamethylcyclopentadiene) were explored and monitored by in situ LIFDI-MS and 1H-NMR. Feedback into experimental design allowed for an informed choice and precise adjustment of reaction conditions and led to isolation of the intermetallic cluster [Cu4Al4](Cp*)5(Mes) (1). Cluster 1 reacts with excess 3-hexyne to yield the triangular cluster [Cu2Al](Cp*)3 (2). The two embryonic [Cu4Al4](Cp*)5(Mes) and [Cu2Al](Cp*)3 clusters 1 and 2, respectively, were shown to be intermediates in the formation of an inseparable composite of the closely related clusters [Cu7Al6](Cp*)6 (3), [HCu7Al6](Cp*)6 (3H) and [Cu8Al6](Cp*)6 (4), which just differ by one Cu core atom. The radical nature of the open-shell superatomic [Cu7Al6](Cp*)6 cluster 3 is reflected in its reactivity towards addition of one Cu core atom leading to the closed shell superatom [Cu8Al6](Cp*)6 (4), and as well by its ability to undergo σ(C–H) and σ(Si–H) activation reactions of C6H5CH3 (toluene) and (TMS)3SiH (TMS = tris(trimethylsilyl)).Cu/Al cluster growth reactions leading to open- and closed-shell superatoms are investigated. Therein, LIFDI-MS is presented as a powerful technique for the in situ detection of cluster identities and reactivity patterns. 相似文献
94.
Christelle Machon Lars Petter Jordheim Jean-Yves Puy Isabelle Lefebvre Charles Dumontet Jérôme Guitton 《Analytical and bioanalytical chemistry》2014,406(12):2925-2941
An analytical method coupling online solid-phase extraction (SPE) and liquid chromatography–tandem mass spectrometry (LC-MS/MS) was developed to quantify 16 endogenous nucleoside mono- and triphosphates in cellular samples. Separation was achieved on a porous graphitic carbon (PGC) column without ion-pairing agent in the mobile phase. Low levels of the ion-pairing agent diethylamine (DEA) added to the reconstitution solution were necessary to prevent peak tailing of nucleoside triphosphates. The mass spectrometer, a triple quadrupole with an electrospray ionisation source, was operated in positive mode. Two multiple reaction monitoring (MRM) segments were programmed, each an internal standard. Extraction and separation of nucleoside mono- and triphosphates were obtained within 20 min. The total duration of a single run was 37 min. Calibration curves, performed with labelled nucleotides added to the sample matrix, ranged from 0.29 to 18.8 pmol injected for deoxyribonucleotides and from 3.9 to 3,156 pmol for ribonucleotides. Accuracy did not deviate more than ?14.6 and 10.2 % from nominal values for all compounds at all levels. CV results were all lower than 17.0 % for the LLOQ level and 14.6 % for the other levels. Quality control (QC) samples were also in agreement with acceptance criteria, except for the lower QC of GMP. Ion suppression, matrix effect, extraction recoveries and stability were assessed. After validation, the method was applied to the evaluation of the effects of gemcitabine and hydroxyurea on nucleotide pools in Messa cells. 相似文献
95.
96.
Martine Assié Abdelkrim Meddour Jean-Claude Fiaud Jean-Yves Legros 《Tetrahedron: Asymmetry》2010,21(13-14):1701-1708
Alkylation of racemic 1-(6-methoxynaphth-2-yl)ethyl acetate by potassium dimethyl malonate catalyzed by a chiral palladium-DUPHOS complex afforded the substitution product with 87% ee, along with 6-methoxy-2-vinylnaphthalene that arose from an elimination process, in a 43/57 substitution/elimination ratio. The reaction performed on a mixture of quasi-enantiomeric substrates provided insight into the stereochemical course of the reaction, establishing that—for a given enantiomer of the catalyst, one enantiomer of the substrate afforded mainly the substitution product whereas the other enantiomer underwent elimination. 相似文献
97.
Laurence Rodier Karine Ballerat-Busserolles Jean-Yves Coxam 《The Journal of chemical thermodynamics》2010,42(6):773-780
In order to study the influence of amine structure on absorption of carbon dioxide, enthalpies of solution of CO2 in 2.50 mol · L?1 aqueous solutions of 2-amino-2-hydroxymethyl-1,3-propanediol (THAM), 2-[2-(dimethyl-amino)ethoxy] ethanol (DMAEOE), and 3-dimethyl-amino-1-propanol (DMAP) were measured. The enthalpies of solution are determined as function of gas loading charge (moles of CO2/mole of amine), at temperatures (313.15 and 353.15) K, and pressures range from (0.5 to 2) MPa. Measurements were carried out using a flow calorimetric technique. CO2 solubilities in the aqueous solutions of amine are derived from calorimetric data. Molar volumes of aqueous amine solutions required to handle calorimetric data were determined at 303.15 K using a vibrating tube densimeter. Experimental enthalpies of solution are discussed on the basis of amines alkalinity. 相似文献
98.
Acoustic field distribution was determined in HIFU sonoreactors as well as localization of cavitation activity by crossing different techniques: modeling, hydrophone measurements, laser tomography and SCL measurements. Particular care was taken with quantification of this last technique by pixels or photon counting. Cavitation bubbles generated by HIFU are mainly located on the outer layer of the propagation cone in the post-focal zone. Greatest acoustic activity is not located at the geometrical focal, but corresponds to a high concentration of bubbles zone. On the contrary, the main sonochemical activity shifts slightly toward the transducer, whereas quenching of inertial cavitation is observed directly at the focal. Finally, SCL thresholds have been determined. 相似文献
99.
Florent Hivert Jean-Christophe Novelli Lenny Tevlin Jean-Yves Thibon 《Selecta Mathematica, New Series》2009,15(1):105-119
We prove conjectures of the third author [L. Tevlin, Proc. FPSAC’07, Tianjin] on two new bases of noncommutative symmetric
functions: the transition matrices from the ribbon basis have nonnegative integral coefficients. This is done by means of
two composition-valued statistics on permutations and packed words, which generalize the combinatorics of Genocchi numbers.
相似文献
100.
Let be a finite-dimensional complex reductive Lie algebra and S() its symmetric algebra. The nilpotent bicone of is the subset of elements (x, y) of whose subspace generated by x and y is contained in the nilpotent cone. The nilpotent bicone is naturally endowed with a scheme structure, as nullvariety of
the augmentation ideal of the subalgebra of generated by the 2-order polarizations of invariants of . The main result of this paper is that the nilpotent bicone is a complete intersection of dimension , where and are the dimensions of Borel subalgebras and the rank of , respectively. This affirmatively answers a conjecture of Kraft and Wallach concerning the nullcone [KrW2]. In addition, we introduce and study in this paper the characteristic submodule of . The properties of the nilpotent bicone and the characteristic submodule are known to be very important for the understanding
of the commuting variety and its ideal of definition. The main difficulty encountered for this work is that the nilpotent
bicone is not reduced. To deal with this problem, we introduce an auxiliary reduced variety, the principal bicone. The nilpotent bicone, as well as the principal bicone, are linked to jet schemes. We study their dimensions using arguments
from motivic integration. Namely, we follow methods developed by Mustaţǎ in [Mu]. Finally, we give applications of our results to invariant theory. 相似文献