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61.
Sedimentation and erosion processes in sedimentary basins can be modeled by a parabolic equation with a limiter on the fluxes and a constraint on the time variation.This limiter happens to satisfy a stationary scalar hyperbolic inequality,within a constraint,for which the authors prove the existence and the uniqueness of the solution.Actually,this solution is shown to be the maximal element of a convenient convex set of functions.The existence proof is obtained thanks to the use of a numerical scheme. 相似文献
62.
The purpose of this article is to support the idea that “whenever we can prove a limit theorem in the classical sense for a dynamical system, we can prove a suitable almost-sure version based on an empirical measure with log-average”. We follow three different approaches: martingale methods, spectral methods and induction arguments. Our results apply, among others, to Axiom A maps or flows, to systems inducing a Gibbs–Markov map, and to the stadium billiard. 相似文献
63.
Aza-Michael addition of optically pure 4-phenyl-2-oxazolidinone to 3,3,3-trifluoro-1-nitropropene proceeds smoothly at low temperature with a high yield. Diastereoselectivity of the addition depends on the base used and lithiated species proved to be highly efficient affording 92% de. Optically pure 1,2-diamino-3,3,3-trifluoropropane is prepared in 58% yield from the aza-Michael addition product through a three-step procedure. 相似文献
64.
Jerzy Król 《Foundations of Physics》2006,36(7):1070-1098
We analyse the proposition that the spacetime structure is modified at short distances or at high energies due to weakening of classical logic. The logic assigned to the regions of spacetime is intuitionistic logic of some topoi. Several cases of special topoi are considered. The quantum mechanical effects can be generated by such semi-classical spacetimes. The issues of: background independence and general relativity covariance, field theoretic renormalization of divergent expressions, the existence and definition of path integral measures, are briefly discussed in the proposal. The connection with some problems in foundations of mathematics and differential topology are also discussed. 相似文献
65.
66.
Tian Le LIN Bao Zhen YAN Gao Fei HU Mei WANG 《中国化学快报》2006,17(7):937-940
Complex formation between aluminium and quercetin(Q) in methanol was investigated by means of 27^Al solid-state, 13^C and 1^H NMR and MS(ESI), UV and IR spectra. Formation of the 1:2 complex was favored in methanol relative to all other solvent and the predominant species observed of Al(Ⅲ) has a 1:2 stoichiometry. The fine structure of 1:2 aluminum complex of quercetin was that the aluminum central atom chelated with two quereetin molecules and two methoxyl groups between two five membered rings, its coordination is six, the chelated site was 3-hydroxy-4-carbonyl. 相似文献
67.
68.
We consider an M/G/1 queue with symmetric service discipline. The class of symmetric service disciplines contains, in particular, the preemptive
last-come-first-served discipline and the processor-sharing discipline. It has been conjectured in Kella et al. [1] that the
marginal distribution of the queue length at any time is identical for all symmetric disciplines if the queue starts empty.
In this paper we show that this conjecture is true if service requirements have an Erlang distribution. We also show by a
counterexample, involving the hyperexponential distribution, that the conjecture is generally not true.
AMS Subject Classifications Primary—60K25; Secondary—90B22 相似文献
69.
M. Le Vassor D’yerville D. Monge D. Cassagne J. P. Albert 《Optical and Quantum Electronics》2002,34(5-6):445-454
We present here a tight-binding-like modelling of two-dimensional (2D) photonic crystals (PCs). Adopted from solid-state physics,
the concept of generalized Wannier functions is used to construct a localized state basis that allows a parameter-free ab
initio study of defects in PCs. We demonstrate here for a 2D triangular lattice of dielectric rods in air, the existence of
this localized basis and the possibility to study large scale complex dielectric structures deviating from periodicity. Specific
numerical simulations on a split waveguide embedded in this triangular lattice are performed, and they demonstrate the superiority
of this method over plane wave based techniques. 相似文献
70.
A phenanthridinium salt was prepared in four steps, including an intramolecular CH-arylation and a hydride abstraction reaction. Treatment with sterically demanding bases does not lead to the corresponding carbene, but rather to addition products: the planar-constrained geometry significantly enhances the electrophilicity over the acidity of C-aryl iminium salts. 相似文献