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771.
Marini RD Groom C Doucet FR Hawari J Bitar Y Holzgrabe U Gotti R Schappler J Rudaz S Veuthey JL Mol R Somsen GW de Jong GJ Ha PT Zhang J Van Schepdael A Hoogmartens J Briône W Ceccato A Boulanger B Mangelings D Vander Heyden Y Van Ael W Jimidar I Pedrini M Servais AC Fillet M Crommen J Rozet E Hubert P 《Electrophoresis》2006,27(12):2386-2399
772.
Schmidt K Brovelli S Coropceanu V Brédas JL Bazzini C Caronna T Tubino R Meinardi F 《The journal of physical chemistry. A》2006,110(38):11018-11024
We discuss the electron-vibration coupling in mono-aza-[5]helicenes on the basis of a Franck-Condon analysis and density functional theory (DFT) calculations of the fluorescence and phosphorescence spectra measured in ethanol. The geometries of the initial states were obtained from time-dependent DFT (S(1)) and unrestricted DFT (T(1)) excited-state optimizations. In general, the position of the nitrogen atom has only a minor impact on the vibronic fine-structure in both absorption and emission. The shapes of the emission spectra from the lowest singlet and triplet states are found to be determined by contributions from multiple normal modes. The results of the calculations demonstrate how the interplay among these normal modes results in qualitatively and quantitatively different spectra for fluorescence and phosphorescence. 相似文献
773.
Cristobal G Arbouet L Sarrazin F Talaga D Bruneel JL Joanicot M Servant L 《Lab on a chip》2006,6(9):1140-1146
Sub-nanolitre droplets engineered in microfluidic devices constitute ideal microreactors to investigate the kinetics of chemical reactions on the millisecond time scale. Up to date, fluorescence detection has been extensively used in chemistry and biology to probe reactants and resultant products within such nanodroplets. However, although fluorescence is a very sensitive technique, it lacks intrinsic specificity as frequently fluorescent labels need to be attached to the species of interest. This weakness can be overcome by using vibrational spectroscopy analysis. As an illustrative example, we use confocal Raman microspectroscopy in order to probe the concentration profiles of two interdiffusing solutes within nanolitre droplets transported through a straight microchannel. We establish the feasibility of the experimental method and discuss various aspects related to the space-time resolution and the quantitativeness of the Raman measurements. Finally, we demonstrate that the droplet internal molecular mixing is strongly affected by the droplet internal flow. 相似文献
774.
Sanchez-Carrera RS Coropceanu V da Silva Filho DA Friedlein R Osikowicz W Murdey R Suess C Salaneck WR Brédas JL 《The journal of physical chemistry. B》2006,110(38):18904-18911
The vibrational coupling in the ground and excited states of positively charged naphthalene, anthracene, tetracene, and pentacene molecules is studied on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. Our theoretical and experimental results reveal that, while the main contribution to relaxation energy in the ground state of oligoacene systems comes from high-energy vibrations, the excited-state relaxation energies show a significant redistribution toward lower-frequency vibrations. A direct correlation is found between the nature of the vibronic interaction and the pattern of the electronic state structure. 相似文献
775.
Sanguinet L Pozzo JL Guillaume M Champagne B Castet F Ducasse L Maury E Soulié J Mançois F Adamietz F Rodriguez V 《The journal of physical chemistry. B》2006,110(22):10672-10682
This paper presents a series of acidoswitchable NLO-phores combining the 9-methylbenzimidazolo[2,3-b]oxazolidine core with various pi systems such as phenylethenyl, phenylethynyl, and naphthylethenyl. All the prepared derivatives are shown to display acidochromic behavior at ambient temperature. The remarkable contrast in the NLO response along the reversible transformations observed in HRS experiments is rationalized by high level theoretical calculations. 相似文献
776.
A novel palladium-catalyzed allylation of H3PO2 with allylic alcohols is described. The phosphorus-carbon bond-forming reaction produces allylic-H-phosphinic acids and water, in the absence of additives. Primary H-phosphinic acids are obtained in excellent yields, whereas secondary H-phosphinic acids react sluggishly. A reusable polymer-supported catalyst is also described. The reaction provides an environmentally sound approach to H-phosphinic acids. 相似文献
777.
Protein peak spectrum assignment is a prerequisite of the nuclear magnetic resonance study of a molecule. We present here a computer tool which proposes the determination of the amino acid type from the values of the chemical shifts. This tool is based on two consensus algorithms based on several published typing algorithms and was trained and extensively tested against the Biological Magnetic Resonance Bank chemical shift data bank. The first one accomplishes the analysis with support vector machine technology, grouping related amino acids together, and presents a mean rate of success above 90% on the test set. The second one uses a classical consensus algorithm of vote. Furthermore, secondary structural prediction is available. This tool can be used for assisting manual assignment of peptides and proteins and can also be used as a step in an automated approach to assignment. This program has been called CRAACK and is publicly available at the following URL: http://abcis.cbs.cnrs.fr/craack. 相似文献
778.
In order to enhance chromatographic performances in terms of efficiency and rapidity, LC has recently evolved in the development of short columns packed with small particles (sub-2 microm) working at high pressures (> 400 bar). This approach has been described 30 years ago according to the fundamental chromatographic equations. However, systems and columns compatible with such high pressures have been introduced in the market in 2004 only. Advantages of small particles working at high pressure will be discussed in terms of sensitivity, efficiency, resolution, and analysis time. Potential problems encountered with high pressure in terms of frictional heating and solvent compressibility will also be discussed even if systems working at a maximum pressure of 1000 bar are not influenced by these parameters and give reliable and reproducible results. Several applications will highlight the potential and interest of this new technology. 相似文献
779.
Zhou Z Liu R Wang J Li S Liu M Brédas JL 《The journal of physical chemistry. A》2006,110(7):2322-2324
Hartree-Fock ab initio and density functional theory calculations suggest that intra- and intermolecular proton transfer between neutral and protonated triazole tautomers play a vital role in the observed dramatic proton conduction in triazole-based polymer electrolyte membranes. 相似文献
780.
Based on essential-state models for three-photon absorption (3PA), we have investigated the structure-property relationships for stilbene-based dipolar and quadrupolar chromophores. The emphasis lies on the evolution of the 3PA cross section with the degree of ground-state polarization. For dipolar systems, we find a dominant role played by Deltamu, which expresses the change in dipole moment between the ground state and the 3PA active excited state. Thus, the strategies usually applied to maximize the second-order polarizability beta are also applicable to optimize the 3PA cross section. For quadrupolar systems, the 3PA response is dominated by contributions from channels including various low-lying two-photon allowed states, which limits the applicability of essential-state models. Optimization strategies can be proposed but vary for different ranges of ground-state polarization. 相似文献