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71.
A new chemiluminescence method for the determination of carbamazepine (CBZ) has been developed. The method is based on the chemiluminescence produced in the reaction of tris(2,2'-bipyridine)ruthenium(III) and CBZ in an acidic medium. The chemiluminescence intensity was enhanced by organic solvents in the reaction system. Under the optimum experimental conditions, the calibration curve was linear over the range 4.0 x 10(-3)-8.6 x 10(-7) mol/L for CBZ. The detection limit (S/N = 3) was 2.5 x 10(-7) mol/L and the relative standard deviation of six replicate measurements was 2.6% for 4.0 x 10(-4) mol/L of CBZ. The possible reaction mechanism were also discussed. The chemiluminescence method was successfully applied to assay the CBZ contents in pharmaceutical tablets. 相似文献
72.
The Cahn-Hilliard equation is modeled to describe the dynamics of phase separation in glass and polymer systems. A priori error estimates for the Cahn-Hilliard equation have been studied by the authors. In order to control accuracy of approximate solutions, a posteriori error estimation of the Cahn-Hilliard equation is obtained by discontinuous Galerkin method. 相似文献
73.
We study the stationary measure for the two-dimensional Boussinesq equation with random forcing. We prove the ergodicity for the two-dimensional stochastically forced Boussinesq equation. We also study the Galerkin truncations of the three-dimensional Boussinesq equations under degenerate stochastic forcing. We follow closely the previous results on the stochastically forced Navier–Stokes equations. 相似文献
74.
75.
Hyun Chul Choi Min Kyu Lee Hyun Joon Shin Seung Bin Kim 《Journal of Electron Spectroscopy and Related Phenomena》2003,130(1-3):85-96
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous. 相似文献
76.
Yong Lee Kazuhiko Hosomi Hiroyuki Uchiyama Toshio Katsuyama Shinya Kominami Tomoyoshi Mishima 《Optical Review》2003,10(1):38-42
An InGaAsP slab-type asymmetric-coupled-waveguide-based dispersion compensator with a mode selector has been designed and fabricated. The mode selector is necessary to select either a symmetric [with a positive group-velocity dispersion (GVD)] or antisymmetric (with a negative GVD) supermode. These supermodes exist simultaneously in the dispersion-compensation region of the device. Pulse-compression experiments were used to test the dispersion compensator, evaluating the function of the mode selector. A theoretical study of the experimental results shows that the mode selector obtains a very strong selectivity (nearly 100%) for the antisymmetric supermode. 相似文献
77.
J. H. Lu Y. Y. Yang C. C. Chen C. H. Kuan H. T. Chen S. C. Lee 《Infrared Physics & Technology》2003,44(5-6):399-409
Superlattices have been demonstrated previously by our group in the design of the multicolor infrared photodetector. In general, the period number of the superlattice may be up to several dozens. In this paper, we have investigated the performance of the infrared photodetectors especially with 3, 5 and 15 periods. The detector structure contains a thick blocking barrier embedded between two superlattices with different period numbers but with the same well and barrier widths. This double-superlattice structure shows switchable spectral responses between two spectral regions by the voltage polarities. The photoresponse in each spectral region is also tunable by the magnitude of the applied voltage. The voltage-dependent behavior reveals the photoelectron relaxation and transport mechanism in the superlattice miniband. Superlattice with few periods has high electron group velocity, less relaxation effect and less collection efficiency. Therefore the superlattice with few periods may have better responsivity and narrower photoresponse range than the one with many periods. Based on the experimental results of our devices, it is observed that the superlattice with fewer periods has better detectivity, responsivity, wider range of the operational temperature, and more flexible miniband engineering than the conventional multiple quantum well infrared photodetector. 相似文献
78.
79.
The system design must be started from the concept with low cost and high performance. In this point, the topological shape of the structure is very important in the view of the structural rigidities and light-weight design.In this paper, the optimization methodology is presented in the design stage of the large optical mirror. We obtain the optimal layout through the topology optimization and then design the details through the size or shape optimization for structural rigidity. 相似文献
80.
Digital image processing techniques have been applied to the analysis of cellular smoked foil patterns from gaseous detonations. In particular, the two-dimensional autocorrelation function is applied to digital cell pattern images and an orientational correlation parameter is calculated. Taking line profiles along the directions of highest correlation provides an unbiased method of determining the mean cell size in each of the two principal directions. By analyzing the width, amplitude and angular position of the orientational correlation plots, information can be extracted concerning the cellular pattern regularity, the relative angular correlation between two sets of transverse waves in two directions, and the mean shape or elongation of the cells within the pattern. The technique is applied to smoked foils from oxyacetylene mixtures with argon dilutions ranging from 0 to 75% to quantify the increase in regularity with argon dilution. This method provides a simple and useful way of analyzing cellular patterns and constitutes a promising technique for improving smoked foil diagnostics. 相似文献