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41.
42.
Xiao Feng Jean-Charles Lancelot Herv Prunier Sylvain Rault 《Journal of heterocyclic chemistry》1996,33(6):2007-2011
The synthetic pathway leading to 4-H-furo[3,2-f]pyrrolo[1,2-a][1,4]diazepines is described in five steps starting from 2-hydroxyketones via 2-amino-3-furonitriles. 相似文献
43.
Jean-Charles Delvenne 《Applied mathematics and computation》2009,215(4):1368-1374
A computer is classically formalised as a universal Turing machine or a similar device. However over the years a lot of research has focused on the computational properties of dynamical systems other than Turing machines, such cellular automata, artificial neural networks, mirrors systems, etc.In this paper we propose a unifying formalism derived from a generalisation of Turing’s arguments. Then we review some of universal systems proposed in the literature and show that are particular case of this formalism. Finally, we review some of the attempts to understand the relation between dynamical and computational properties of a system. 相似文献
44.
This paper addresses a single machine scheduling problem in which the following simple constraint is added: a set of time
slots is forbidden for starting a task, that is no task can start at any forbidden time point. We show that the single machine
problem with makespan minimization is strongly -complete and we give polynomial algorithms to solve the problems with a small number of forbidden start times.
相似文献
45.
α-Fluoro-α,β-unsaturated esters 2 were efficiently synthetized via diethylzinc-promoted Wittig reaction using a phosphonium-supported triphenylphosphine SCG-PPh31, which possesses similar reactivity as its parent analog triphenylphosphine. The main advantage of this system is the use of a novel low-molecular-weight support that is soluble in solvents of medium polarities for the attachment of reagents and insoluble in solvents of low polarities. 相似文献
46.
Stereoselective radical additions have excellent potential as mild, nonbasic carbon-carbon bond constructions for direct asymmetric amine synthesis. Efficient intermolecular radical addition to C=N bonds with acyclic stereocontrol has previously been limited mainly to secondary and tertiary radicals, a serious limitation from the perspective of synthetic applications. Here, we provide full details of the use of photolysis with manganese carbonyl to mediate stereoselective intermolecular radical addition to N-acylhydrazones. Photolysis (300 nm) of alkyl halides and hydrazones in the presence of Mn2(CO)10 and InCl(3) as a Lewis acid led to reductive radical addition; diastereomer ratios ranged from 93:7 to 98:2 at ca. 35 degrees C. The reaction tolerates additional functionality in either reactant, enabling subsequent transformations as shown in an efficient asymmetric synthesis of coniine. A series of hydrazones bearing different substituents on the oxazolidinone auxiliary were compared; consistently high diastereocontrol revealed that the identity of the substituent had little practical effect on the diastereoselectivity. Further mechanistic control experiments confirmed the intermediacy of radicals and showed that independently prepared alkyl- or acylmanganese pentacarbonyl compounds do not undergo efficient addition to the N-acylhydrazones under thermal or photolytic (300 nm) conditions. These Mn-mediated conditions avoid toxic tin reagents and enable stereoselective intermolecular radical additions to C=N bonds with the broadest range of alkyl halides yet reported, including previously ineffective primary alkyl halides. 相似文献
47.
A new dynamic programming formulation for scheduling independent tasks with common due date on parallel machines 总被引:1,自引:0,他引:1
Nguyen Huynh Tuong Ameur Soukhal Jean-Charles Billaut 《European Journal of Operational Research》2010,202(3):646-653
This paper deals with a scheduling problem of independent tasks with common due date where the objective is to minimize the total weighted tardiness. The problem is known to be ordinary NP-hard in the case of a single machine and a dynamic programming algorithm was presented in the seminal work of Lawler and Moore [E.L. Lawler, J.M. Moore, A functional equation and its application to resource allocation and sequencing problems, Management Science 16 (1969) 77–84]. In this paper, this algorithm is described and discussed. Then, a new dynamic programming algorithm is proposed for solving the single machine case. These methods are extended for solving the identical and uniform parallel-machine scheduling problems. 相似文献
48.
Lepailleur A Bureau R Paillet-Loilier M Fabis F Saettel N Lemaître S Dauphin F Lesnard A Lancelot JC Rault S 《Journal of chemical information and modeling》2005,45(4):1075-1081
The present study discusses the well-known 5-HT7/5-HT1A selectivity issue through a new series of phenylpyrrole derivatives. The first hits emerged from a virtual screening performed on a chemolibrary. Further study led to an optimization of a preliminary 5-HT7 pharmacophore model. The importance of each pharmacophoric feature is confirmed, but these characteristics have to be coupled to geometric constraints in order to achieve a 5-HT7 selectivity. Indeed, 5-HT1A affinity probably arises from extended conformations, whereas a bent one appears to be best suited for 5-HT7 selectivity. 相似文献
49.
Tissot JD Sanchez JC Vuadens F Scherl A Schifferli JA Hochstrasser DF Schneider P Duchosal MA 《Electrophoresis》2002,23(7-8):1203-1206
In 1993, we reported the presence of an IgM-associated peptide (M(r) 44 kDa; pI 5.45) in all immunoglobulin M (IgM) fractions purified from plasma/serum by various methods. This peptide was absent in Ig fractions of non-IgM isotypes. The N-terminal sequence was determined as being APPSGVRLVGGLH. To gain insight into the nature of this peptide, we further analyzed, using modern proteomic tools, the IgM-associated peptide isolated from cryoglobulins. Mass spectrometry revealed three peptides of different masses: 2203.13 (ELGCGAASGTPSGILYEPPAEK), 1564.83 (KPIWLSQMSCSGR), and 1544.77 (EATLQDCPSGPWGK). Theses sequences together with the already known N-terminal sequence allowed us to identity the IgM-associated peptide as Sp alpha (O43866 in TrEMBL database; CD5 antigen-like). Sp alpha is a member of the scavenger receptor cysteine-rich superfamily of proteins. This family includes the T-and B-cell antigens CD5 and CD6, and several of its members influence immune cell fate. Our finding may have important implications in the understanding of the homeostasis of IgM antibodies. 相似文献
50.
For some years it has been possible to control the particle size of fly ashes, by-products of thermal power stations. Incorporating these very fine particles (obtained by grinding and/or pneumatic selection) improves the physical-mechanical characteristics of mortars and concretes. In this study, we measured the lime consumption of the various fractions (granulometric and densimetric) and identified by X-ray diffraction the neoformed phases by the pozzolanic reaction, to show that it is not sufficient to simply define the pozzolanicity of products based on lime consumption since it does not take into account the nature of the phases formed. The size of the particles used in the test samples also has a determining effect on the quantity of lime consumed. Before comparing results, it is necessary to ensure that the size of the particles (of the global ash and its constituents) be the same. Two distinct neoformed ohases appear: CSH in the largest granular fractions (d〉 40 μm) and C3AH6 in the smaller fractions. 相似文献