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71.
Janusz B. Kyzio Krzysztof Ejsmont 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(2):o77-o79
The title compound, C19H15N3, was prepared by condensation of 3‐nitrosocarbazole and aniline with subsequent methylation. The structure is built up of stacks of almost planar molecules. Density functional theory (DFT) calculations predict a completely planar conformation, different from that observed in the crystal lattice. HOMA (harmonic oscillator model of aromaticity) indices, calculated for three aromatic rings, demonstrate the small influence of the azo substituent on π electrons in the carbazole system. 相似文献
72.
Tomasz Klis Sergiusz Lulinski Janusz Serwatowski 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(3):o145-o146
The molecule of the title compound, 2,3‐F2‐4‐(CHO)C6H2B(OH)2 or C7H5BF2O3, contains a formyl group coplanar with the benzene ring. The boronic acid group is twisted with respect to the benzene ring plane. The molecules are organized into infinite chains via intermolecular O—H⋯O hydrogen bonds. These chains are additionally connected via strong O—H⋯O hydrogen bonds, producing a folded layer structure perpendicular to the a axis. These layers are paired due to B⋯F interactions. 相似文献
73.
It is shown that enantioselective solvent-generated liquid-liquid and liquid-solid Chromatographic systems with -cyclodextrin derivatives can be realized. The liquid-liquid systems are based on ternary solvent systems of limited miscibility, containing chiral additives; the chiral stationary phase is spontaneously generated on the porous microparticulate silica used as a solid support. In the solvent-generated adsorption systems a very small proportion of -cyclodextrin derivatives is added to the mobile phase. These components act as column activators, since they are strongly adsorbed on the RP solid support where they form new stereoselective adsorption sites. It is demonstrated that dynamically generated systems with -cyclodextrin derivatives as chiral agents are powerful and versatile tools for enantioseparation of different types of compounds. This technique creates not only a new type of selectivity but also leads to very stable and reproducible Chromatographic columns.Dedicated to Professor J. F. K. Huber on the occasion of his 65th birthday 相似文献
74.
Headspace solid phase microextraction (headspace SPME) has been demonstrated to be an excellent solvent-free sampling method. One of the major factors contributing to the success of headspace SPME is the concentrating effect of the fiber coating toward organic compounds. The affinity of the fiber coating toward very volatile analytes, such as chloromethane, may, however, not be large enough for detection at the parts per trillion concentration level. Static headspace analysis, on the other hand, is very effective for these very volatile compounds. As analyte volatility decreases, the sensitivity of static headspace analysis drops. The complementary nature of these two sampling methods can be exploited by combining the SPME device with a gastight syringe. The sensitivity of the new sampling device is better than that of SPME for very volatile compounds or that of static headspace analysis for less volatile compounds. This new method can sample a wide range of compounds from chloromethane (b.p. −24°C) to bromoform (b.p. 149°C) with estimated limits of detection at the low parts per trillion level. 相似文献
75.
Janusz Wasilewski Jan F. Biernat 《Journal of inclusion phenomena and macrocyclic chemistry》1991,10(1):109-118
Lipophilic bis-substituted ester and ether derivatives of benzo-15-crown-5 have been synthesised. The correlation between the structure and potentiometric ion-selectivity has been studied in PVC membrane ion-selective electrodes. An ion-selective potassium sensitive electrode based on 4,5-bis (biphenyloxymethyl)benzo-15-crown-5 exhibited the best electrode properties. The detection limit was loga
K = -5.4; logK
K,Na
ppot = -3.5. The effect of the lipophilicity of neutral carriers upon electrode performance has been also discussed. 相似文献
76.
Diastereoselective C2-elongation processes of N-mono- 1a-c and N,N-diprotected 1d-fl-alaninals, using vinylmagnesium bromide and chloride, are described. A substantial difference between effects of the N-protecting groups replacing either one or two amino protons was observed. 相似文献
77.
Magdalena Leśniak Marcin Gajek Janusz Partyka Maciej Sitarz 《Journal of Thermal Analysis and Calorimetry》2017,130(1):165-176
In this work, the structure and thermal properties of aluminosilicate fritted glazes in SiO2–Al2O3–CaO–MgO–Na2O–K2O–ZnO system with (4.0 mol%) and without addition of ZnO were examined by GIXRD, FTIR, MAS-NMR and thermal methods (DTA, DIL). It has been found that the all experimental glazes are amorphous material (transparent glazes). On the base of spectroscopic investigations, it was found that zinc ions exist in the network glazes in the octahedral coordination—Zn2+ ions play a network modifier role in structure of glazes. An analysis of the data obtained from thermal tests showed that addition of ZnO into chemical composition results in decrease in glass transition temperature value (T g) for all glazes (DTA, DIL). The coefficient of thermal expansion (α) is decreased as the whole measurement range for one series of fritted glazes. 相似文献
78.
79.
Synthesis of β-cyclodextrin-lysozyme conjugates and their physicochemical and biochemical properties
Tomasz Marek Goszczyński Maciej Gawłowski Beata Girek Konrad Kowalski Janusz Boratyński Tomasz Girek 《Journal of inclusion phenomena and macrocyclic chemistry》2017,87(3-4):341-348
Recently a great interest in the field of protein engineering and the design of innovative drug delivery systems employing specific ligands such as cyclodextrins is observed. The paper reports the solid state, thermal method for protein coupling with β-cyclodextrin and the physicochemical and biological properties of the obtained conjugates. The structure of the obtained conjugates was investigated via liquid chromatography-mass spectrometry, dynamic light scattering and circular dichroism analysis. The presented conjugates were biologically active and covalently bound β-cyclodextrin preserved the ability to form inclusion complexes with the model compound. This report demonstrates the great potential of cyclodextrin as a modifying unit that can be used to modulate the properties of therapeutic proteins, additionally giving such conjugates the possibility to transport many therapeutic substances in the form of inclusion complexes. In addition, the paper presents the potential of protein-cyclodextrin conjugates to construct innovative bioactive molecules for biological and medical applications. 相似文献
80.