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31.
The electron capture from the inner atomic shells by multiply charged ions at intermediate and high collision energies is considered. The cross section scaling laws, as well as the reduced energy parameter, are discussed. Universal curves for the reduced cross section versus the reduced collision energy are presented for electron capture from the K, L and M shells of Ar atoms colliding with multiply charged ions. A comparison of theoretical results with the existing experimental data is given. 相似文献
32.
33.
J.?Lecointre D. S.?Belic J. J.?Jureta R. K.?Janev P.?Defrance 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2009,55(3):557
Absolute cross-sections have been measured for electron-impact dissociativeexcitation and ionization of CD 2 + leading toformation of CD 2 2+ , CD+, C+,D 2 + and D+. The animated crossed-beams methodis applied in the energy range from the reaction threshold up to 2.5 keV.The maximum total cross-sections are found to be (1.2±0.1)×10-17 cm2, (6.1±0.7)×10-17 cm2, (6.4±0.7)×10-17 cm2, (26.3±3.8)×10-19 cm2 and (14.9±1.4)×10-17 cm2 forCD 2 2+ , CD+, C+,D 2 + and D+ respectively. Individualcontributions for dissociative excitation and dissociative ionization aredetermined for each singly-charged product, which are of significantinterest in fusion plasma edge modelling and diagnostics. Conforming to thescheme recently applied in the CD 4 + and in theCD 3 + articles, the cross-sections are presented inclosed analytic forms convenient for implementation in plasma simulationcodes. Kinetic-energy-release distributions are determined for each ionicfragment at selected electron energies. 相似文献
34.
Bhupinder Singh Sumedha Ahuja Renu Pandey RK Singhal 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(3):1315-1320
Root release of organic compounds and rate of the vascular sap flow are important for understanding the nutrient and the source-sink dynamics in plants, however, their determination is procedurally cumbersome and time consuming. We report here a simple method involving 14C labeling for rapid and reliable measurement of root exudates and vascular sap flow rate in a variable groundnut population developed through seed gamma irradiation using a cobalt source (60Co). An experimental hypothesis that a higher 14C level in the vascular sap would indicate a higher root release of carbon by the roots into the rhizosphere was verified. 相似文献
35.
Three new 2-component unsubstituted ( 4P ), diiodo- ( 5P ), and dibromo- ( 6P ) distyryl-BODIPY-bridged cyclotriphosphazene dimers were designed and synthesized. The newly synthesized BODIPY-cyclotriphosphazene systems were characterized by 1 H, 13 C, and 31 P NMR spectroscopy. The photophysical properties of the distryl-BODIPYs (4–6) and BODIPY-cyclotriphosphazene dyads ( 4P – 6P ) were studied by UV-Vis absorption and fluorescence emission spectroscopy. In these derivatives, the bino-type cyclotriphosphazene derivative bearing unsubstituted BODIPY unit 4P exhibited high fluorescence and no singlet oxygen generation due to the lack of spin converter. The attachment of heavy atoms (iodine and bromine) enabled the production of singlet oxygen. The bino-type BODIPY-cyclotriphosphazenes ( 5P and 6P ) were also used as triplet photosensitizers in the photooxidation of 1,3-diphenylisobenzofuran to endoperoxide via generation of the singlet oxygen in dichloromethane. The singlet oxygen production of these compounds was also investigated via a direct method and produced a singlet oxygen phosphorescence peak at 1270 nm. 相似文献
36.
37.
J. Lecointre D. S. Belic J. J. Jureta R. K. Janev P. Defrance 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2009,55(3):569-580
Absolute cross-sections have been measured for electron-impact dissociative
excitation and ionization of CD2+ leading to
formation of CD22+, CD+, C+,
D2+ and D+. The animated crossed-beams method
is applied in the energy range from the reaction threshold up to 2.5 keV.
The maximum total cross-sections are found to be (1.2±0.1)×10-17 cm2, (6.1±0.7)×10-17 cm2, (6.4±0.7)×10-17 cm2, (26.3±3.8)×10-19 cm2 and (14.9±1.4)×10-17 cm2 for
CD22+, CD+, C+,
D2+ and D+ respectively. Individual
contributions for dissociative excitation and dissociative ionization are
determined for each singly-charged product, which are of significant
interest in fusion plasma edge modelling and diagnostics. Conforming to the
scheme recently applied in the CD4+ and in the
CD3+ articles, the cross-sections are presented in
closed analytic forms convenient for implementation in plasma simulation
codes. Kinetic-energy-release distributions are determined for each ionic
fragment at selected electron energies. 相似文献
38.
39.
The quasi-stationary spectrum of highly excited (Rydberg) states in the field of a multiply charged ion is calculated in the asymptotic region. The result is used to obtain the electron transfer cross section, within the decay approximation, for the process. 相似文献
40.
Osman
ZTÜRK Aydn HAMOLU Ouz Kaan
ZDEMR nci KARAASLAN Ali ems AHSEN 《Turkish Journal of Chemistry》2021,45(5):1336
A series of thin Pt-Co films with different metal ratios were deposited by using the sequential cosputtering directly on a commercial hydrophobic carbon paper substrate at room temperature and in ultra-high vacuum (UHV) conditions. Their electrocatalytic properties toward the oxygen reduction reaction were investigated in 0.5 M H2SO4 solution by means of cyclic voltammetry (CV) and linear sweep voltammetry (LSV) on rotating disc electrode (RDE). The results showed that Pt particles, deposited by dc-magnetron gun, surround the large Co-clusters deposited by rf-magnetron gun. In addition, the increase of Co content led to an increase in the electrochemical active surface area (EASA) from 23.75 m2/gPt to 47.54 m2/gPt for pure Pt and Pt:Co (1:3), respectively, which corresponded the improvement of the utilization of Pt by a factor of 1.91. This improvement indicated that the sequential magnetron cosputtering was one of the essential technique to deposit homogeneous metal clusters with desirable size on the gas diffusion layer by adjustment plasma parameters. 相似文献