The synthesis,characterization and reactions of a binuclear tetramethylplatinum(IV) complex

Reaction of excess MeLi and MeI with [PtCl₂SMe₂)₂] gives the first binuclear tetramethylplatinum(IV) complex [Pt₂Me₈(μ-SMe₂)₂]. The characterization of this complex, and its reactions with donor ligands to give cis-[PtMe₄L₂] (L₂ = Ph₂PCH₂PPh₂, Ph₂PCH₂CH₂PPh₂, 2,2′-bipyridyl, 1,10-phenanthroline or L = PMe₂Ph, PMePh₂) are described.     

Matrices of bisimple regular semigroups

A semigroup S is a matrix of subsemigroups S_iμ, i ε I, μ ε M if the S_iμ form a partition of S and S_iμS_jν≤S_iν for all i, j in I, μ, ν in M. If all the S_iμ are bisimple regular semigroups, then S is a bisimple regular semigroup. Properties of S are considered when the S_iμ are bisimple and regular; for example, if S is orthodox then each element of S has an inverse in every component S_iμ.     

Translational hull of an inverse semigroup

The theory of ideal extensions of semigroups is dependent upon adequate knowledge of the translational hull. We characterize here certain basic structures in the translational hull, Ω(S), of an arbitrary inverse semigroup S: in particular, the semilattice of idempotents of Ω(S) and the group of units of Ω(S). An isomorphic copy of each of these structures is given in terms of the semilattice of idempotents of S.     

Isotopic sum rules and compliance scheme

It is known that compliance scheme does not provide simple linear isotopic sum rules in λ^?1 similar to the ones in λ in the force constant scheme. The advantage of not having such sum rules in the compliance scheme is discussed in relation to the uniqueness problem of the molecular force field.Incidentally, for the molecules H₂O, D₂O, and HDO, two quadratic relations in terms of the inverse frequency parameters λ^?1 are obtained. These supplement the three obvious product rule relations.     

Quantum vacuum cosmology

It is shown for the case of a conformally flat vacuum that the curvature of space-time may be viewed as the observable consequence of particle interactions involving a scalar field φ, rather than the independent agency of the gravitational field by itself. The quantum nature of gravity comes in as a consequence of the quantum properties of the φ-field (“vacuum fluctuation”), and a direct analogy is drawn between the renormalizations of charge and mass. Cosmological solutions are derived: These being just the conventional Friedmann solutions, or the de Sitter solution. It is pointed out that a totally empty universe must be Minkowskian.     

Frequency and form as determinants of functor sensitivity in English-acquiring infants

High-frequency functors are arguably among the earliest perceived word forms and may assist extraction of initial vocabulary items. Canadian 11- and 8-month-olds were familiarized to pseudo-nouns following either a high-frequency functor the or a low-frequency functor her versus phonetically similar mispronunciations of each, kuh and ler, and then tested for recognition of the pseudo-nouns. A preceding the (but not kuh, her, ler) facilitated extraction of the pseudo-nouns for 11-month-olds; the is thus well-specified in form for these infants. However, both the and kuh (but not her-ler) facilitated segmentation for 8-month-olds, suggesting an initial underspecified representation of high-frequency functors.     

Lattice strain effects on CO oxidation on Pt(111)

Surface strain plays a major role in determining the rate limiting step and catalytic activity of platinum for CO oxidation.     

An ab initio study of 15N-11B spin-spin coupling constants for borazine and selected derivatives

Ab initio equation-of-motion coupled-cluster singles and doubles (EOM-CCSD) calculations have been performed to investigate substituent effects on coupling constants for borazine and selected substituted borazines. For molecules in which F atoms are not bonded to adjacent atoms in the ring, F substitution increases the one-bond (11)B-(15)N coupling constants involving the atom at which substitution occurs but leaves the remaining one-bond B-N coupling constants essentially unchanged. For these molecules, the magnitudes of one-bond B-N coupling constants are only slightly dependent on the number of F atoms present. Fluorine substitution at adjacent B and N atoms in the borazine ring further increases the one-bond B-N coupling constant involving the substituted atoms and has the same effect on the other one-bond coupling constants as observed for corresponding molecules in which substitution occurs at alternate sites. In contrast to the effect of F substitution, substitution of Li at either N or B decreases one-bond B-N coupling constants relative to borazine. The effects of F and Li substitution on one-bond B-N coupling constants for borazine are similar to F and Li substitution effects on (13)C-(13)C coupling constants for benzene.