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Marilyn M. Olmstead James C. Fettinger Soya Gamsey Jacob W. Clary Bakthan Singaram 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(6):o333-o335
The structures of three chiral vinyldioxazaborocanes are reported, namely (2E)‐ and (2Z)‐6‐benzyl‐2‐buten‐2‐yl‐1,3,6,2‐dioxazaborocane, C27H30BNO2, (II) and (III), respectively, and (2Z)‐2‐buten‐2‐yl‐6‐isobutyl‐1,3,6,2‐dioxazaborocane, C24H32BNO2, (IV). These compounds may be useful in asymmetric reactions. In the structures reported here, the N—B donor–acceptor bond is longer than in any previously reported analogous compounds. 相似文献
84.
During the last 55 years there have been many results concerning conditions that force a ring to be commutative. These results were stimulated by Jacobson's famous result and were extensively developed by Herstein. This paper will survey the area by organizing the results according to whether they come from variations on Herstein's conditions, depend on general polynomial conditions, depend on the presence of a derivation, or whether a ring has special properties that make commutativity more easily accessible. Finally, the most recent conditions concern product sets and lead to results in a new area of inquiry. 相似文献
85.
Benjamin Falk Santiago M. Vallinas James V. Crivello 《Journal of polymer science. Part A, Polymer chemistry》2003,41(4):579-596
This article describes the development of optical pyrometry (OP) as a new analytical technique for the continuous monitoring of the progress of both free‐radical and cationic photopolymerizations. The method is rapid, reproducible, and very easy to implement. A temperature profile of a photopolymerization can be obtained. Preliminary studies have shown that the temperatures of some polymerizing monomers can easily reach temperatures in excess of 250 °C. The effects of the mass and reactivity of the monomer, light intensity, structures, and concentrations of the photoinitiators and monomers as well as the presence or absence of oxygen on various free‐radical and cationic photopolymerizations were examined with this method. Coupling of real‐time infrared spectroscopy with OP provides a convenient method for simultaneously monitoring both the chemical conversion and the temperature of a photopolymerization. This combined technique affords new insights into the effects of temperature‐induced autoacceleration on the course of photopolymerizations. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 579–596, 2003 相似文献
86.
Kimberlitic–pyropic peridotite–xenolites, probably of Jurassic–Cretaceous age, were found mixed with a younger Upper Tertiary basanitic diabase, as flow texture of plagioclase laths and ilmenite rods around those xenoliths indicated. Mafic–ultramafic rocks were crushed, sheared, and cropped along a creek about 15–18 km NE of the town of Dreikeesh, NW Syria. 40K–40Ar isotopic dating of a pure fresh black cpx sample, collected from the peridotite xenoliths, yielded an age of about 70 Ma. This age is concurrent to the time when Africa, Eurasia, and America were part of the super continent Pangaea. It also suggests that kimberlite–pyropic peridotitic rocks were located within a cratonic pipe prior to their 2000-km eastward journey (starting from the Mid-Atlantic Rift). Sampled outcrops were located within a ring of about 40 km diameter, considered to be a dome consisting of one or more clusters of kimberlitic pipes. The dome structure, mostly covered with Upper Jurassic–Cretaceous carbonate beds, was tilted westward, and rifted and sheared along its eastern edge. Tilting and crushing were accomplished after the opening of the Red Sea in the Miocene, and the counterclockwise movements of the Arabian plate, which folded the carbonate beds to form the N–S-trending Alawite mountain range along the Syrian coast. Olivine, cpx, and pyrope were the major phases in peridotite. Pyrope, including its Cr–Ni-contents, was found to be the best indicator to decipher the temperature–pressure (T–P) conditions for the system. The inferred temperature was found to be about 1460 °C, at a pressure of 62 kb (around 207 km-depth). Petrographic studies revealed many zoned, resorbed, octahedral and non-metasomatized tiny grains, associated with partly to wholly metasomatized and iddingsitized olivines. 相似文献
87.
Let G be a d‐regular graph G on n vertices. Suppose that the adjacency matrix of G is such that the eigenvalue λ which is second largest in absolute value satisfies λ = o(d). Let Gp with p = α/d be obtained from G by including each edge of G independently with probability p. We show that if α < 1, then whp the maximum component size of Gp is O(log n) and if α > 1, then Gp contains a unique giant component of size Ω(n), with all other components of size O(log n). © 2003 Wiley Periodicals, Inc. Random Struct. Alg., 2004 相似文献
88.
O. Moze M. Hofmann J. M. Cadogan K. H. J. Buschow D. H. Ryan 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,36(4):511-518
The magnetic structure and ordering temperatures of three intermetallic compounds which crystallize in the tetragonal ThCr2Si2 structure, TbCr2Si2, HoCr2Si2 and ErCr2Si2, have been determined by neutron diffraction, differential scanning calorimetry and magnetization measurements. The Cr-sublattice orders anti-ferromagnetically with Néel temperatures of 758 K for TbCr2Si2, 718 K for HoCr2Si2 and 692 K for ErCr2Si2. Chromium atoms located at 4d crystallographic sites are aligned anti-parallel along the c-axis, with GZCr magnetic modes. In contrast with metallic bcc Cr, the refined room temperature value of the ordered Cr moment is anomalously large for all three compounds. No long range magnetic order of the R sublattice in TbCr2Si2 and HoCr2Si2 is observed, whilst the Er sublattice in ErCr2Si2 orders independently of the Cr sublattice below 2.4 K with moments ferromagnetically aligned in the basal plane.Received: 4 November 2003, Published online: 30 January 2004PACS:
75.25. + z Spin arrangements in magnetically ordered materials (including neutron and spin-polarized electron studies, synchrotron-source X-ray scattering, etc.) - 75.30.Cr Saturation moments and magnetic susceptibilities - 75.50.Ee Antiferromagnetics 相似文献
89.
We present several simple algorithms for accurately computing the sum of n floating point numbers using a wider accumulator. Let f and F be the number of significant bits in the summands and the accumulator, respectively. Then assuming gradual underflow, no overflow, and round-to-nearest arithmetic, up to ?2 F?f /(1?2?f )?+1 numbers can be accurately added by just summing the terms in decreasing order of exponents, yielding a sum correct to within about 1.5 units in the last place. In particular, if the sum is zero, it is computed exactly. We apply this result to the floating point formats in the IEEE floating point standard, and investigate its performance. Our results show that in the absence of massive cancellation (the most common case) the cost of guaranteed accuracy is about 30–40% more than the straightforward summation. If massive cancellation does occur, the cost of computing the accurate sum is about a factor of ten. Finally, we apply our algorithm in computing a robust geometric predicate (used in computational geometry), where our accurate summation algorithm improves the existing algorithm by a factor of two on a nearly coplanar set of points. 相似文献
90.