Selectively protected galactose derivatives for the synthesis of branched oligosaccharides

Synthesis and characterization of several new anomerically pure galactose derivatives, based on simple and effective protective group manipulations of benzyl β-d-galactopyranoside, are reported. The monosaccharides described contain selectively protected/deprotected hydroxyl functionalities at their 1,2,3,4- and 6-positions rendering them useful as building blocks for construction of branched oligosaccharides.     

Physical processes underlying the development of shear turbulence

A physical model of the development of turbulence in free shear flows is proposed. The model is based on the results of numerical simulations of turbulent flow development. The main ideas of the proposed theory of turbulence are stated as follows: the onset of turbulence begins with the formation of large vortices; spectral energy transfer involves both direct and inverse cascades; and the inertial range of the energy spectrum develops as a result of concurrent direct and inverse cascades. The dominant physical factors that determine the spectrum include Joukowski forces.     

First-principles calculations of the hyperfine fields on ligands in fluorides

In solid-state physics, a crystal lattice is frequently approximated by an array of interacting ions. In this case, the wave functions of individual ions are assumed to be a fairly good zeroth approximation in calculating the matrix elements of the interaction Hamiltonian of electrons and nuclei of the lattice from first principles. Use of the second-quantization method is proposed for such calculations in the basis of these functions. As an example, the electron transition amplitude from a ligand to the central ion is estimated. The results agree well with the experimental data.