Slow crack growth in blends of HDPE and model copolymers

The resistance to slow crack growth (SCG) was measured in binary blends of high density polyethylene (HDPE) and 5–10% concentrations of model ethylene-butene random copolymers by measuring the time to failure (t_f) under a constant stress intensity. An increase of t_f with the addition of the copolymer if the copolymer could crystallize and the increase was greater the higher branch density. The copolymer with 117 branches/1000C could not crystallize and therefore its blend had a t_f that was less than that of the HDPE. The fracture energies of the blends as determined by their resistance to SCG were compared with the energy by rapid fracture, J_c, as previously measured by Rhee and Crist. It is concluded that SCG is more sensitive to variations in the microstructure than is rapid fracture and that the differences in SCG behavior can be qualitatively explained in terms of the differences in microstructure of the blends. ©1995 John Wiley & Sons, Inc.     

Radioanalytical monitoring of the formation of barium sulfate in aqueous solutions

The formation of barium sulfate in aqueous media causes problems of insoluble scale formation. On the other hand, the coprecipitation of uranium and transuranium elements with barium sulfate has been suggested for the determination of these elements in environmental monitoring processes. Therefore, the study of barium sulfate crystal growth is required. The investigations done so far suffer from the low sensitivity of the analytical methods used. In the present work we have overcome this problem by using¹³¹Ba for the preparation of supersaturated solutions. Thus kinetics parameters such as induction time and precipitation rates were measured. The polynuclear mechanism was found to be operative at high and the spiral growth at low supersaturations.     

Nonlinear sigma-model with a composite gauge field

A nonlinear gauge-invariant -model of a general type on a homogeneous space G/H is reformulated in terms of a composite gauge field. In the approximation under consideration, the one-loop effective action of the model is obtained. It is shown that one can choose the parameters in such a way that the theory is both free from ultraviolet divergences and does not lead to a dynamical generation of a composite boson.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 22–25, March, 1988.In conclusion, the author wants to thank I. V. Tyutin and S. V. Ketov for their attention to this work and useful discussions.     

Experimental study of regions of reversed magnetization in an amorphous layer of Co70Fe5Si10B15

The characteristics of the distribution of magnetization and remagnetization of microsections of the surface in the amorphous alloy Co₇₀Fe₅Si₁₀B₁₅, prepared in the form of thin ribbons, were studied by the magnetooptical method. It was found that the magnetization I on the surface of the amorphous ribbon studied was strongly nonuniform. It was established that heat treatment (HT) of the sample leads to the appearance of regions of reversed magnetization in the surface layer of the ribbon, while thermomagnetic annealing reduces the nonuniformity of I. The conservation of the transverse component in the HT sample in fields where the magnitude of the component of magnetization parallel to the length of the ribbon remains virtually unchanged suggested that a domain structure of the magnetization ripple type, owing to the strong microdispersion of the magnetic anisotropy, is realized in this sample.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 89–94, March, 1988.     

On a method of constructing the solutions of boundary-value problems of the theory of bendings of surfaces of positive curvature

A new method is proposed for constructing the solutions of boundary-value problems of Riemann-Hilbert type for noncanonical linear and quasilinear first-order elliptic systems in a simply connected bounded region of the plane. For a linear boundary condition we obtain complete results; for a nonlinear boundary condition we study the solvability in a neighborhood of zero. Applications are given to the problem of isometric transformations of a surface diffeomorphic to the disk and having positive curvature all the way to the boundary under prescribed boundary conditions.Translated from Ukrainskií Geometricheskií Sbornik, Issue 29, 1986, pp. 56–82.     

Synthesis and crystal and molecular structure of newN-substituted γ-hydroxybutyramides

TheN-(2-phenylethyl)amide of-(1, 1-ethylenedioxy)-ethyl--hydroxybutyric acid (II) and theN-(p-methoxybenzyl)amide of-(1, 1-ethylenedioxy)-ethyl--hydroxybutyric acid (III) have been synthesized and the crystal structure ofIII has been solved. CompoundIII, C₁₆H₂₃O₅N, crystallizes in the monoclinic space groupP2₁/c witha=12.572(2),b=11.149(2),c=12.317(2) Å and=106.53(1)°. The structure was solved by direct methods, and refined by full-matrix least squares to giveR=0.040 (R _w =0.047) for 2004 intensities. The dioxolane ring has a deformed half-chair conformation.     

Crystal structure and vibrational spectra of hydrazinium (2+) tri-μ-fluoro bis[pentafluorozirconate (IV)] fluoride and vibrational spectra of its hafnium analogue

Monoclinic (N₂H₆)₃Zr₂F₁₃·F crystallizes in space group P2₁-C ₂ ² (No. 4) with unit cell dimensionsa=5.670(1),b=10.984(2),c=10.601(2) Å,=93.88(1)°,V=658.7(4) ų andZ=2. Two different types of N₂H₆ ²⁺ ions are present. One is involved in strong H-bonds to F^– ions in infinite chains running along the a axis (the shortest N-F distance is 2.437(5) Å), and the other links the structure through weaker bi- and trifurcated H-bonds to fluorine ligands of the Zr₂F₁₃ ^5– ions. The N-N bond lengths range from 1.430(5) to 1.446(5) Å with apparently no meaningful correlation to the type of N₂H₂ ²⁺ ions. The Zr₂F₁₃ ^5– ions have very nearly C₂ point symmetry and are formed by joining two distorted bicapped trigonal prisms of ZrF₈-units through a common face. Distances of Zr-F terminal bonds range from 2.015(2) to 2.112(2) Å and of bridging bonds from 2.133(2) to 2.212(2) Å. (N₂H₆)₃Hf₂F₁₃·F is isomorphous. The vibrational spectra of the two compounds are nearly identical, with the exception of a strong infrared band, which is assigned to a stretching mode with the moving central atom within the anion. The anion part of the spectrum is simple, showing broad unresolved bands. The cation part shows two types of N₂H₆ ^– ions. H-Bonding is strongly present in the spectra, but no simple correlations with the H-bond strength is evident.     

Behavior on the real line of entire functions represented by Dirichlet series with complex exponents

It is shown, in particular, that if _{n k} when n k, Re _n > 0, and , then an entire function F that is bounded on the real line and represented by a Dirichlet series d_n exp (_nz) that is uniformly and absolutely convergent on each compactum in is identically zero.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 42, No. 7, pp. 882–888, July, 1990.     

A numerical analysis of chaotic behaviour in Bianchi IX models

In this paper we investigate the chaotic behaviour of the Bianchi IX cosmological models using techniques developed in the study of dynamical systems and chaotic behaviour. We numerically calculate the Lyapunov exponent, , and show that instead of converging to a constant value, it decreases steadily. We study this effect further by studying the Lyapunov exponent using short-time averages. We show that the usual method of calculating is invalid in the case of a cosmological model.     

Random fields and quantum effects in proton glasses

The effects of quantum fluctuations on the proton glass phase in mixed hydrogen-bonded ferro-antiferroelectric systems are considered. The system is described in terms of the infinite-ranged Ising pseudospin glass model in a transverse tunneling field in the presence of random parallel fields. The stability limit of the high-temperature proton glass phase is determined within the thermofield dynamic approach, and the behavior or linear and nonlinear susceptibility is evaluated.