全文获取类型
收费全文 | 339篇 |
免费 | 7篇 |
国内免费 | 3篇 |
专业分类
化学 | 150篇 |
晶体学 | 3篇 |
力学 | 12篇 |
数学 | 21篇 |
物理学 | 163篇 |
出版年
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 10篇 |
2018年 | 7篇 |
2017年 | 9篇 |
2016年 | 11篇 |
2015年 | 8篇 |
2014年 | 14篇 |
2013年 | 26篇 |
2012年 | 13篇 |
2011年 | 19篇 |
2010年 | 13篇 |
2009年 | 12篇 |
2008年 | 17篇 |
2007年 | 10篇 |
2006年 | 7篇 |
2005年 | 7篇 |
2004年 | 11篇 |
2003年 | 1篇 |
2002年 | 6篇 |
2001年 | 2篇 |
1998年 | 6篇 |
1996年 | 6篇 |
1995年 | 7篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 14篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 6篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 5篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1972年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有349条查询结果,搜索用时 15 毫秒
81.
Computation of non-linearity parameter (B/A), molecular radius (r
m) and intermolecular free length (L
f) for H2O, C6H6, C6H12, CH3OH, C2H5OH and their deuterium-substituted compounds have been carried out at four different temperatures, viz., 293.15, 303.15, 313.15
and 323.15 K. The aim of the investigation is an attempt to study the isotopic effects on the non-linearity parameter and
the physicochemical properties of the liquids, which in turn has been used to study their effect on the intermolecular interactions
produced thereof. 相似文献
82.
Recently, there has been increasing interest in field of Optical CDMA due to its potential for offering unmatched features at ultra high data rates in field of local and metro area networks. In this paper, a very simple method of Optical CDMA encoding known as the Temporal Phase Encoding is discussed and the performance of the system with this encoding technique is evaluated on the basis of number of users, length of the spreading code for 4-phase and 8-phases. Simulation results for the system are presented for upto seven users. Bit error rate curves are plotted with data rate of 1 Gbps. This has been found that performance improves if normalized threshold higher than 0.5 is used. 相似文献
83.
84.
Parth?Soni Jasmine?Kaur Kulbhushan?TikooEmail author 《Journal of nanoparticle research》2015,17(1):18
The present study highlights the beneficial synergistic blend of anticancer drug paclitaxel (PTX) and thymoquinone (TQ) in MCF-7 breast cancer cells. We aimed to augment the therapeutic index of PTX using a polymeric nanoparticle system loaded with PTX and TQ. PLGA nanoparticles encapsulating the two drugs, individually or in combination, were prepared by single emulsion solvent evaporation method. The formulated nanoparticles were homogenous with an overall negative charge and their size ranging between 200 and 300 nm. Entrapment efficiency of PTX and TQ in the dual drug-loaded nanoparticles was found to be 82.4 ± 2.18 and 65.8 ± 0.45 %, respectively. The release kinetics of PTX and TQ from the nanoparticles exhibited a biphasic pattern characterised by an initial burst, followed by a gradual and continuous release. The anticancer activity of nanoparticles encapsulating both the drugs was higher as compared to the free drugs in MCF-7 breast cancer cells. The combination index for the dual drug-loaded NPs was found to be 0.688 which is indicative of synergistic interaction. Thus, here, we propose the synthesis and use of dual drug-loaded TQ and PTX NPs which exhibits enhanced anticancer activity and can additionally help to alleviate the toxic effects of PTX by lowering its effective dose. 相似文献
85.
86.
Reetz MT Soni P Fernández L Gumulya Y Carballeira JD 《Chemical communications (Cambridge, England)》2010,46(45):8657-8658
Mutants of the lipase from Bacillus subtilis, previously engineered for enhanced thermostability using directed evolution based on the B-FIT method, show significantly increased tolerance to hostile organic solvents. 相似文献
87.
Jalpa C. Trivedi Kuldip D. Upadhyay Sudhir K. Joshi Erik De Clercq 《Tetrahedron letters》2007,48(48):8472-8474
Two closely structurally related coumarins, 4-hydroxy-8-isopropyl-5-methylcoumarin and 4-hydroxy-6-chloro-7-methylcoumarin were acylated at C-3 and further converted to the respective chalcones and two series of eighteen new compounds, which were evaluated for possible antiviral activity. 相似文献
88.
Nagao H Hirano T Tsuboya N Shiota S Mukaida M Oi T Yamasaki M 《Inorganic chemistry》2002,41(24):6267-6273
The reaction of cis-[Ru(NO)(CH(3)CN)(bpy)(2)](3+) (bpy = 2,2'-bipyridine) in H(2)O at room temperature proceeded to afford two new nitrosylruthenium complexes. These complexes have been identified as nitrosylruthenium complexes containing the N-bound methylcarboxyimidato ligand, cis-[Ru(NO)(NH=C(O)CH(3))(bpy)(2)](2+), and methylcarboxyimido acid ligand, cis-[Ru(NO)(NH=C(OH)CH(3))(bpy)(2)](3+), formed by an electrophilic reaction at the nitrile carbon of the acetonitrile coordinated to the ruthenium ion. The X-ray structure analysis on a single crystal obtained from CH(3)CN-H(2)O solution of cis-[Ru(NO)(NH=C(O)CH(3))(bpy)(2)](PF(6))(3) has been performed: C(22)H(20.5)N(6)O(2)P(2.5)F(15)Ru, orthorhombic, Pccn, a = 15.966(1) A, b = 31.839(1) A, c = 11.707(1) A, V = 5950.8(4) A(3), and Z = 8. The structural results revealed that the single crystal consisted of 1:1 mixture of cis-[Ru(NO)(NH=C(O)CH(3))(bpy)(2)](2+) and cis-[Ru(NO)(NH=C(OH)CH(3))(bpy)(2)](3+) and the structural formula of this single crystal was thus [Ru(NO)(NH=C(OH(0.5))CH(3))(bpy)(2)](PF(6))(2.5). The reaction of cis-[Ru(NO)(CH(3)CN)(bpy)(2)](3+) in dry CH(3)OH-CH(3)CN at room temperature afforded a nitrosylruthenium complex containing the methyl methylcarboxyimidate ligand, cis-[Ru(NO)(NH=C(OCH(3))CH(3))(bpy)(2)](3+). The structure has been determined by X-ray structure analysis: C(25)H(29)N(8)O(18)Cl(3)Ru, monoclinic, P2(1)/c, a = 13.129(1) A, b = 17.053(1) A, c = 15.711(1) A, beta = 90.876(5) degrees, V = 3517.3(4) A(3), and Z = 4. 相似文献
89.
Glass-fiber reinforced epoxy composites were fabricated from the matrix resin liquid diglycidyl ether of bisphenol-C (DGEBC) using various amines as curing agents with and without fortifier (20 phr). The epoxy laminates were evaluated for their mechanical properties, such as flexural strength, interlaminar shear strength (ILSS), tensile strength and shore-D hardness. Dielectric properties, such as the dielectric constant, tan δ, dielectric loss and the resistivity of the laminated samples, were measured. The effect of the chemical reagents on the mechanical properties (i.e. flexural strength, lLSS) was also studied. 相似文献
90.
The present paper is in continuation to our recent paper [6] in these proceedings. Therein, three composition formulae for
a general class of fractional integral operators had been established. In this paper, we develop the Mellin transforms and
their inversions, the Mellin convolutions, the associated Parseval-Goldstein theorem and the images of the multivariableH-function together with applications for these operators. In all, seven theorems and two corollaries (involving the Konhauser
biorthogonal polynomials and the Jacobi polynomials) have been established in this paper. On account of the most general nature
of the polynomials S
n
m
[x] and the multivariableH-function whose product form the kernels of our operators, a large number of (new and known) interesting results involving
simpler polynomials and special functions (involving one or more variables) obtained by several authors and hitherto lying
scattered in the literature follow as special cases of our findings. We give here exact references to the results (in essence)
of seven research papers which follow as simple special cases of our theorems. 相似文献