A Self‐Binding,Melt‐Castable,Crystalline Organic Electrolyte for Sodium Ion Conduction

The preparation and characterization of the cocrystalline solid–organic sodium ion electrolyte NaClO₄(DMF)₃ (DMF=dimethylformamide) is described. The crystal structure of NaClO₄(DMF)₃ reveals parallel channels of Na⁺ and ClO₄⁻ ions. Pressed pellets of microcrystalline NaClO₄(DMF)₃ exhibit a conductivity of 3×10⁻⁴ S cm⁻¹ at room temperature with a low activation barrier to conduction of 25 kJ mol⁻¹. SEM revealed thin liquid interfacial contacts between crystalline grains, which promote conductivity. The material melts gradually between 55–65 °C, but does not decompose, and upon cooling, it resolidifies as solid NaClO₄(DMF)₃, permitting melt casting of the electrolyte into thin films and the fabrication of cells in the liquid state and ensuring penetration of the electrolyte between the electrode active particles.     

Hall effect in the normal phase of the organic superconductor (TMTSF)2PF6

We report accurate Hall effect measurements performed in the normal phase of the quasi-one-dimensional organic conductor (TMTSF)2PF6 at ambient pressure. The Hall coefficient is found to be strongly temperature dependent all the way from 300 K down to the spin density wave onset arising around 12 K. These new results emphasize the existence of a high temperature regime above 130 K where the Fermi liquid model is not satisfactory.     

Charge transport along the lambda-DNA double helix

We have measured the conductivity sigma along the lambda phage DNA (lambda-DNA) double helix at microwave frequencies using lyophilized DNA in and also without a buffer. The conductivity is strongly temperature dependent around room temperature with a crossover to a weakly temperature dependent conductivity at low temperatures. Removal of the water mantle around the double helix leads to reduced conductivity.     

Spin transport properties in a non-uniform quantum wire modulated by both Rashba and Dresselhaus spin–orbit couplings

Spin transport properties in a non-uniform quantum wire (QW) in the presence of both the Rashba and Dresselhaus spin–orbit couplings (SOCs) is investigated by using the non-equilibrium Green's function (NEGF) method combined with the Landauer Büttiker formalism. It is found that such a non-uniform quantum wire exhibits considerable spin polarization in its conductance in the influence of both the Rashba and Dresselhaus SOCs, and that the two SOCs' strengths strongly affect both the magnitude and sign of the electron spin polarization. Interestingly, the Rashba and Dresselhaus SOCs play the same modulating role in the electron spin polarization. The proposed nanostructure can potentially be utilized to devise an all-electrical spintronic device.     

An Augmented Formulation for Mechanical Systems with Non-Generalized Coordinates: Application to Rigid Body Contact Problems

In computational multibody algorithms, the kinematic constraintequations that describe mechanical joints and specified motiontrajectories must be satisfied at the position, velocity andacceleration levels. For most commonly used constraint equations, onlyfirst and second partial derivatives of position vectors with respect tothe generalized coordinates are required in order to define theconstraint Jacobian matrix and the first and second derivatives of theconstraints with respect to time. When the kinematic and dynamicequations of the multibody systems are formulated in terms of a mixedset of generalized and non-generalized coordinates, higher partialderivatives with respect to these non-generalized coordinates arerequired, and the neglect of these derivatives can lead to significanterrors. In this paper, the implementation of a contact model in generalmultibody algorithms is presented as an example of mechanical systemswith non-generalized coordinates. The kinematic equations that describethe contact between two surfaces of two bodies in the multibody systemare formulated in terms of the system generalized coordinates and thesurface parameters. Each contact surface is defined using twoindependent parameters that completely define the tangent and normalvectors at an arbitrary point on the body surface. In the contact modeldeveloped in this study, the points of contact are searched for on lineduring the dynamic simulation by solving the nonlinear differential andalgebraic equations of the constrained multibody system. It isdemonstrated in this paper that in the case of a point contact andregular surfaces, there is only one independent generalized contactconstraint force despite the fact that five constraint equations areused to enforce the contact conditions.     

Transport properties in mixtures involving carbon dioxide at low and moderate density: test of several intermolecular potential energies and comparison with experiment

It is the purpose of this paper to extract unlike intermolecular potential energies of five carbon dioxide-based binary gas mixtures including CO₂–He, CO₂–Ne, CO₂–Ar, CO₂–Kr, and CO₂–Xe from viscosity data and compare the calculated potentials with other models potential energy reported in literature. Then, dilute transport properties consisting of viscosity, diffusion coefficient, thermal diffusion factor, and thermal conductivity of aforementioned mixtures are calculated from the calculated potential energies and compared with literature data. Rather accurate correlations for the viscosity coefficient of afore-cited mixtures embracing the temperature range 200 K < T < 3273.15 K is reproduced from the present unlike intermolecular potentials energy. Our estimated accuracies for the viscosity are to within ±2%. In addition, the calculated potential energies are used to present smooth correlations for other transport properties. The accuracies of the binary diffusion coefficients are of the order of ±3%. Finally, the unlike interaction energy and the calculated low density viscosity have been employed to calculate high density viscosities using Vesovic–Wakeham method.     

Synchronization in a multiplex network of gene oscillators

Study of the synchronization in the network of gene oscillator network has vital importance in understanding of rhythmicity of molecular and cellular activities. In this paper, we analyze a network of linearly coupled genetic oscillators in a multiplex structure. The coupling strength values are changed and the coupling range is considered to be fixed, but different in the two layers. The analyses are done in two cases of periodic and chaotic oscillations. By computing the statistical measures, the interlayer and intralayer synchronization states are studied. The results show that the layer with higher coupling range has more enhanced synchrony and is less affected by the turbulent behavior of the other layer. On the other hand, the layer with lower coupling range approaches synchronization by strengthening the interlayer and intralayer couplings. The interlayer synchronization is also achieved in high coupling strength values.     

Process equation as a model for the development of cells

The European Physical Journal Special Topics - This paper proposes a behavioral model for cells that shows their different dynamics from a high pluripotent stem cell to any distinct cell fate. The...     

Synergistic Effects of Plant Growth Regulators and Elicitors on α-Humulene and Zerumbone Production in Zingiber zerumbet Smith Adventitious Root Cultures

Zingiber zerumbet, also known as ‘Lempoyang’, possesses various phytomedicinal properties, such as anticancer, antimicrobial, anti-inflammatory, antiulcer, and antioxidant properties. Secondary metabolites possessing such properties i.e., zerumbone and α-humulene, are found dominantly in the plant rhizome. Synergistic effects of plant growth hormones and elicitors on in vitro α-humulene and zerumbone production, and biomass growth, in adventitious root culture (AdRC) of Z. zerumbet cultivated in a two-stage culture are reported. The culture was induced by supplementation of 1.0 mg/L NAA and 2.0 mg/L IBA (dark), and subsequently maintained in medium supplemented with 1 mg/L NAA and 3 mg/L BAP (16:08 light-dark cycle), yielded the production of zerumbone at 3440 ± 168 µg/g and α-humulene at 3759 ± 798 µg/g. Synergistic elicitation by 400 μM methyl jasmonate (MeJa) and 400 μM salicylic acid (SA) resulted in a 13-fold increase in zerumbone (43,000 ± 200 µg/g), while 400 μM MeJa and 600 μM SA produced a 4.3-fold increase in α-humulene (15,800 ± 5100 µg/g) compared to control.     

High-Q and temperature stable photonic biosensor based on grating waveguides

Optical and Quantum Electronics - Evaluation of polarization control by polarization attractor based on stimulated Raman scattering in optical fiber is presented. Performed simulations are...