全文获取类型
收费全文 | 238篇 |
免费 | 15篇 |
国内免费 | 4篇 |
专业分类
化学 | 154篇 |
晶体学 | 3篇 |
力学 | 4篇 |
数学 | 57篇 |
物理学 | 39篇 |
出版年
2023年 | 2篇 |
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 12篇 |
2019年 | 11篇 |
2018年 | 15篇 |
2017年 | 17篇 |
2016年 | 17篇 |
2015年 | 11篇 |
2014年 | 14篇 |
2013年 | 29篇 |
2012年 | 23篇 |
2011年 | 19篇 |
2010年 | 13篇 |
2009年 | 12篇 |
2008年 | 10篇 |
2007年 | 9篇 |
2006年 | 3篇 |
2005年 | 1篇 |
2004年 | 5篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1975年 | 2篇 |
1973年 | 2篇 |
排序方式: 共有257条查询结果,搜索用时 31 毫秒
11.
Input design has a dominant role in developing the dynamic model of an autonomous underwater vehicle (AUV) through system identification. Optimal input design is the process of generating informative inputs that can be used to provide a good-quality dynamic model of AUV. In this paper, amplitude-modulated pseudo-random binary signal (APRBS) inputs are optimally designed in order to estimate the hydrodynamic derivatives of an AUV’s nonlinear dynamic model. The input controls are designed so as to minimize uncertainty in estimating hydrodynamic derivatives. The employed approach can design multiple inputs and apply constraints on an AUV system’s inputs and outputs. The genetic algorithm is utilized to solve the constraint optimization problem. The presented algorithm is used for designing the input signals of Hydrolab300 AUV, and the estimation obtained by these inputs is compared with that of zigzag maneuver. According to the results, the designed APRBS inputs improve the uncertainties that exist in estimating hydrodynamic derivatives better than zigzag inputs. 相似文献
12.
This paper considers the scenario of supply chain with multiple products and multiple suppliers, all of which have limited capacity. We assume that received items from suppliers are not of perfect quality. Items of imperfect quality, not necessarily defective, could be used in another inventory situation. Imperfect items are sold as a single batch, prior to receiving the next shipment, at a discounted price. The demand over a finite planning horizon is known, and an optimal procurement strategy for this multi-period horizon is to be determined. Each of products can be sourced from a set of approved suppliers, a supplier-dependent transaction cost applies for each period in which an order is placed on a supplier. A product-dependent holding cost per period applies for each product in the inventory that is carried across a period in the planning horizon. Also a maximum storage space for the buyer in each period is considered. The decision maker, the buyer, needs to decide what products to order, in what quantities, with which suppliers, and in which periods. Finally, a genetic algorithm (GA) is used to solve the model. 相似文献
13.
Jafar Akbari Akbar Heydari Leila Ma’mani Seyed Hassan Hosseini 《Comptes Rendus Chimie》2010,13(5):544-547
An efficient and practical protocol for the chemoselective N-Boc protection of various structurally different aryl, aliphatic and heterocyclic amines was carried out with (Boc)2O using protic 1, 1, 3, 3-tetra-methylguanidinium acetate (10 mol%) as recyclable catalyst under solvent free condition at ambient temperature. No competitive side reactions (isocyanate, urea and N, N-di-Boc) were observed. α-Amino alcohols afforded the N-Boc-derivative without oxazolidinone formation. 相似文献
14.
15.
16.
Copper/Graphene/Clay Nanohybrid: A Highly Efficient Heterogeneous Nanocatalyst for the Synthesis of Novel 1,2,3‐Triazolyl Carboacyclic Nucleosides via ‘Click’ Huisgen 1,3‐Dipolar Cycloaddition
下载免费PDF全文
![点击此处可从《Helvetica chimica acta》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Mohammad Navid Soltani Rad Somayeh Behrouz S. Jafar Hoseini Hasan Nasrabadi Maryam Saberi Zare 《Helvetica chimica acta》2015,98(9):1210-1224
A very mild and highly efficient synthesis of some novel 1H‐1,2,3‐triazolyl carboacyclic nucleosides via a ‘Click’ Huisgen cycloaddition of N‐propargyl nucleobases and azido alcohols using Cu/aminoclay/reduced graphene oxide nanohybrid (Cu/AC/r‐GO nanohybrid) as nanocatalyst is described. The preparation and characterization of Cu/AC/r‐GO nanohybrid are discussed. This catalyst was characterized by X‐ray diffraction, FT‐IR, TEM, and energy‐dispersive analysis of X‐ray techniques. Cu/AC/r‐GO nanohybrid is a stable and highly efficient heterogeneous nanocatalyst that can be easily prepared, used, and restored from the reaction mixture by simple filtration, and reused for many consecutive trials without significant decrease in activity. 相似文献
17.
Let (R,m) be a commutative Noetherian regular local ring of dimension d and I be a proper ideal of R such that mAss R (R/I) = Assh R (I). It is shown that the R- module Hht(I) I (R) is I-cofinite if and only if cd(I,R) = ht(I). Also we present a sufficient condition under which this condition the R-module H i I (R) is finitely generated if and only if it vanishes. 相似文献
18.
Ghassan?ShobakiEmail author Jafar?Jamal 《Computational Optimization and Applications》2015,60(2):343-376
This article presents an exact algorithm for the precedence-constrained traveling salesman problem, which is also known as the sequential ordering problem. This NP-hard problem has applications in various domains, including operational research and compilers. In this article, the problem is presented and solved in the context of minimizing switching energy in compilers. Most previous work on minimizing switching energy in the compiler domain has been limited to simple heuristics that are not guaranteed to give an optimal solution. In this work, we present an exact algorithm for solving the switching energy minimization problem using a branch-and-bound approach. The proposed algorithm is simple and intuitive, yet powerful. It is the first exact algorithm for the switching energy problem that is shown to solve real instances of the problem within a few seconds per instance. Compared to previous work in the operational research domain, the proposed algorithm is believed to be the most powerful exact algorithm that does not require a linear programming formulation. The proposed algorithm is experimentally evaluated using instances taken from a production compiler. The results show that with a time limit of 10 ms per node, the proposed algorithm optimally solves 99.8 % of the instances. It optimally solves instances with up to 598 nodes within a few seconds. The resulting switching cost is 16 % less than that produced without energy awareness and 5 % less than that produced by a commonly used heuristic. 相似文献
19.
Synthesis of Novel α‐(Acyloxy)‐α‐(quinolin‐4‐yl)acetamides by a Three‐Component Reaction between an Isocyanide,Quinoline‐4‐carbaldehyde,and Arenecarboxylic Acids
下载免费PDF全文
![点击此处可从《Helvetica chimica acta》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Jafar Taran Ali Ramazani Sang Woo Joo Katarzyna Ślepokura Tadeusz Lis 《Helvetica chimica acta》2014,97(8):1088-1096
Novel α‐(acyloxy)‐α‐(quinolin‐4‐yl)acetamides were synthesized by the Passerini three‐component reaction between an isocyanide, quinoline‐4‐carbaldehyde, and arenecarboxylic acids in H2O. The reactions were carried out in one pot at room temperature with quantitative yields. 相似文献
20.
Jafar Ezzati Nazhad DolatabadiOmid Mashinchian Baharak AyoubiAli Akbar Jamali Ahmad MobedDusan Losic Yadollah Omidi Miguel de la Guardia 《Trends in analytical chemistry : TRAC》2011,30(3):459-472
In the past two decades, nanoscale advanced materials have been explored for biosensing molecules, so new horizons have opened up for identifying and quantifying biomolecules, and possible early diagnosis of diseases.DNA nanobiosensors show promise. This article provides an overview on their optical and electrochemical aspects. We discuss recent progress in this field, describing basic concepts of molecular beacons and quantum dots as optical nano-imaging systems. Also, carbon nanotubes provide a platform for development and advancement of electrochemical DNA nanobiosensors, which are increasingly being implemented as robust tools for detection in biomedical sciences. 相似文献