MHD stagnation point flow towards a stretching sheet

The steady two-dimensional MHD stagnation point flow towards a stretching sheet with variable surface temperature is investigated. The governing system of partial differential equations are transformed into ordinary differential equations, which are then solved numerically using a finite-difference scheme known as the Keller-box method. The effects of the governing parameters on the flow field and heat transfer characteristics are obtained and discussed. It is found that the heat transfer rate at the surface increases with the magnetic parameter when the free stream velocity exceeds the stretching velocity, i.e. ε>1, and the opposite is observed when ε<1.     

Drag force of moving quark in STU background

In this paper we consider a quark moving in D=5, supergravity thermal plasma. By using the three charges non-extremal black hole solution (STU solution) we calculate the drag force on the quark and the diffusion constant from the AdS/CFT correspondence.     

The Analytical Solution of Charged Black Hole and Calculation of Quantities (<Emphasis Type="Italic">T</Emphasis>,<Emphasis Type="Italic">s</Emphasis>,<Emphasis Type="Italic">f</Emphasis>)

One of the most remarkable features of black hole is the connection between properties of the classical solutions and thermodynamics. We include the electric and magnetic charges and this lead us to resolve Einstein equations. We obtain thermodynamic properties, such as temperature, entropy density and speed of sound with analytical solution. In that case we characterize equation of state in to V(φ) language.     

A sulfonic acid functionalized ionic liquid as a homogeneous and recyclable catalyst for the one-pot synthesis of α-aminophosphonates

A sulfonic acid functionalized ionic liquid is used as a Brønsted acid catalyst for the one-pot, three-component synthesis of α-aminophosphonates from aldehydes and ketones at room temperature in water. This homogeneous catalytic procedure is simple and efficient and the catalyst can be reused at least six times without any noticeable decrease in catalytic activity.     

Volumetric and viscosity studies of interactions between sodium phosphate salts and poly(propylene glycol) 400 in aqueous solutions at different temperatures

Density and sound velocity at the 288.15–313.15 K and viscosity at the 298.15–313.15 K temperature range at 5 K intervals for polypropylene glycol (PPG) in aqueous solutions of sodium di-hydrogen phosphate, di-sodium hydrogen phosphate and tri-sodium phosphate with salt mass fractions 0.00, 0.010 and 0.020 are reported at atmospheric pressure. From the experimental density and sound velocity data, the apparent specific volume, excess specific volume, isentropic compressibility and isentropic compressibility deviation values have been determined. The infinite dilution apparent specific volume and isentropic compressibility values of PPG have been obtained and from which the infinite dilution apparent specific volumes of transfer of PPG from water to aqueous sodium phosphate solutions have been obtained for the investigated salt concentrations and temperatures. The excess specific volume, isentropic compressibility and viscosity deviation are negative and decrease in magnitude as temperature, concentration of sodium phosphate and charge on the anion of electrolyte increases.     

Thermodynamic properties of surfactant sodium n-heptyl sulfonate in water and in aqueous solutions of poly(ethylene glycol) at different temperatures

The volumetric, compressibility and electrical conductivity properties of sodium n-heptyl sulfonate (C₇SO₃Na) in pure water and in aqueous poly(ethylene glycol) (PEG) solutions were determined at different temperatures below and above the micellar composition range. At each temperature, the infinite dilution apparent molar volumes of the monomer and micellar state of C₇SO₃Na in aqueous PEG solutions respectively are smaller and larger than those in pure water. However, the values of the infinite dilution apparent molar isentropic compressibility of both monomer and micellar states of C₇SO₃Na in aqueous PEG solutions are larger than those in pure water. Thermodynamic parameters of micellization of investigated surfactant in water and in aqueous solutions of PEG at different temperatures were estimated and it was found that the micelle formation process is endothermic and therefore, this process must be driven by entropy increase. The calculated Gibbs free energies of micellization for aqueous PEG solutions are more negative than those for pure water and become more negative by increasing temperature. The variation of the critical micelle concentration (CMC) of C₇SO₃Na in water and in aqueous PEG solutions with temperature was obtained and a comparison between the CMC of C₇SO₃Na obtained from different thermodynamic properties was also made.     

Copper (II) ion selective liquid membrane electrode based on new Schiff base carrier

Cu2+ selective PVC membrane electrode based on new Schiff base 2, 2'-[1,9 nonanediyl bis (nitriloethylidyne)]-bis-(1-naphthol) as a selective carrier was constructed. The electrode exhibited a linear potential response within the activity range of 1.0 x 10(-6) - 5.0 x 10(-3) moll(-1) with a Nernstian slope of 29 +/- 1 mV decade(-1) of Cu2+ activity and a limit of detection 8.0 x 10(-7) mol l(-1). The response time of the electrode was fast, 10 s, and stable potentials were obtained within the pH range of 3.5- 6.5. The potentiometric selectivity coefficients were evaluated using two solution method and revealed no important interferences except for Ag+ ion. The proposed electrode was applied as an indicator electrode to potentiometric titration of Cu2+ ions and determination of Cu2+ content in real samples such as black tea leaves and multivitamin capsule.     

Spectrophotometric determination of rifampicin through chelate formation and charge transfer complexation in pharmaceutical preparation and biological fluids

Two simple and accurate spectrophotometric methods for determination of Rifampicin (RIF) are described. The first method is based on charge transfer (CT) complex formation of the drug with three pi-electron acceptors either 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 7,7,7,8-Tetracyanoquinodimethane (TCNQ) or 2,3,5,6-Tetrachloro-1,4-benzoquinone (p-chloranil) in acetonitrile. The method is followed spectrophotometrically by measuring the maximum absorbance at 584 nm, 761 nm (680 nm) or 560 nm for DDQ, TCNQ and p-chloranil, respectively. Under the optimized experimental conditions, the calibration curves showed a linear relationship over the concentration ranges of 5-140 microg/ml, 2-45 microg/ml (5-120 microg/ml) and 15-200 microg/ml, respectively. The second method is based on the reaction of RIF with iron(III) forming a water insoluble violet complex which is extracted into chloroform. The method determines RIF in concentration range of 10-240 microg/ml at 540 nm. The proposed methods applied to determination of RIF in capsule, human serum and urine samples with good accuracy and precision. The results were compared statistically with the official method and showed no significant different between the methods compared in terms of accuracy and precision.     

Computation of cascade flutter by uncoupled and coupled methods

A computational method for flutter prediction of turbomachinery cascades is presented. The flow through multiple blade passages is calculated using a time-domain approach with coupled aerodynamic and structural models. The unsteady Euler/Navier-Stokes equations are solved in quasi-three-dimensions using a second-order implicit scheme with dual time-stepping and a multigrid method. A structural model for the blades with bending and torsion degrees of freedom is integrated in time together with the flow field. Information between structural and aerodynamic models is exchanged until convergence in each real-time step. Computational results for a cascade are presented and compared with those obtained by the conventional energy method and with experimental and numerical data by other authors. Significant differences are found between the coupled and uncoupled methods at low mass ratios. A transonic test case with strong nonlinear phenomena is investigated with the fluid-structure coupled method. Results for inviscid flow are compared with results of Navier-Stokes computations.     

Spherical Kadomtsev-Petviashvili Solitons in a Suprathermal Complex Plasma

The nonlinear aspects of nonplanar dust acoustic (DA) solitary waves are investigated in an unmagnetized complex plasma comprising of cold dust grains, kappa-distributed ions as well as electrons. The nonplanar DA solitons are studied based on the reductive perturbation technique. It is shown that the evolution of DA solitons is governed by a spherical Kadomtsev-Petviashvili (sKP) equation and then the impact of suprathermality on the spatial structure as well as the nature of DA soliton is studied. It seems that the properties of DA solitons in nonplanar geometry are quite different from that of the planar solitons.