全文获取类型
收费全文 | 3268篇 |
免费 | 94篇 |
国内免费 | 17篇 |
专业分类
化学 | 2054篇 |
晶体学 | 20篇 |
力学 | 128篇 |
数学 | 457篇 |
物理学 | 720篇 |
出版年
2023年 | 29篇 |
2022年 | 34篇 |
2021年 | 58篇 |
2020年 | 70篇 |
2019年 | 67篇 |
2018年 | 48篇 |
2017年 | 36篇 |
2016年 | 81篇 |
2015年 | 68篇 |
2014年 | 69篇 |
2013年 | 145篇 |
2012年 | 185篇 |
2011年 | 200篇 |
2010年 | 105篇 |
2009年 | 89篇 |
2008年 | 171篇 |
2007年 | 173篇 |
2006年 | 168篇 |
2005年 | 144篇 |
2004年 | 88篇 |
2003年 | 87篇 |
2002年 | 67篇 |
2001年 | 52篇 |
2000年 | 43篇 |
1999年 | 35篇 |
1998年 | 41篇 |
1997年 | 36篇 |
1996年 | 37篇 |
1995年 | 32篇 |
1994年 | 38篇 |
1993年 | 44篇 |
1992年 | 44篇 |
1991年 | 32篇 |
1990年 | 33篇 |
1989年 | 30篇 |
1988年 | 26篇 |
1986年 | 32篇 |
1985年 | 24篇 |
1984年 | 39篇 |
1983年 | 29篇 |
1982年 | 38篇 |
1981年 | 43篇 |
1980年 | 48篇 |
1979年 | 29篇 |
1978年 | 33篇 |
1977年 | 42篇 |
1976年 | 35篇 |
1975年 | 32篇 |
1974年 | 25篇 |
1973年 | 28篇 |
排序方式: 共有3379条查询结果,搜索用时 0 毫秒
81.
82.
A simple correction accounting for the effect of truncating the atomic orbital basis on the calculation of N.M.R. shielding is proposed. This correction is obtained from the expression for the magnetic shielding as a sum of orbital pair contributions: a spurious term that vanishes only if a complete basis is used appears in this expression. It is demonstrated both theoretically and numerically (using the example of PH3) that removing this term from the results obtained with a truncated basis improves significantly the agreement with the experimental values. As a by-product the gauge dependence of the numerical results is much reduced. The additional computing time is negligible. 相似文献
83.
Thomas Weymuth Moritz P. Haag Karin Kiewisch Sandra Luber Stephan Schenk Christoph R. Jacob Carmen Herrmann Johannes Neugebauer Markus Reiher 《Journal of computational chemistry》2012,33(27):2186-2198
We present the software package MO VI PAC for calculations of vibrational spectra, namely infrared, Raman, and Raman Optical Activity (ROA) spectra, in a massively parallelized fashion. MO VI PAC unites the latest versions of the programs SNF and AKIRA alongside with a range of helpful add‐ons to analyze and interpret the data obtained in the calculations. With its efficient parallelization and meta‐program design, MO VI PAC focuses in particular on the calculation of vibrational spectra of very large molecules containing on the order of a hundred atoms. For this purpose, it also offers different subsystem approaches such as Mode‐ and Intensity‐Tracking to selectively calculate specific features of the full spectrum. Furthermore, an approximation to the entire spectrum can be obtained using the Cartesian Tensor Transfer Method. We illustrate these capabilities using the example of a large π‐helix consisting of 20 (S)‐alanine residues. In particular, we investigate the ROA spectrum of this structure and compare it to the spectra of α‐ and 310‐helical analogs. © 2012 Wiley Periodicals, Inc. 相似文献
84.
The main conclusions in studies on polymerization catalysts and the nature of chain transfer in the polymerization of cyclic imino ethers were that there is extensive chain transfer in the 2-alkyl oxazolines to produce polymer with a reactive end. Toward the end of polymerization, these chain-transferred molecules repolymerize back on the active center producing a multibranched star polymer. A theory for the data was developed. 相似文献
85.
Thermodynamic properties of Dysprosium rhodite (DyRhO3) are measured in the temperature range from 900 to 1,300 K using a solid-state electrochemical cell incorporating yttria-stabilized zirconia as the electrolyte. The standard Gibbs free energy of formation of DyRhO3 with O-type perovskite structure from its components binary oxides, Dysprosia with C-rare earth structure and β-Rh2O3 with orthorhombic structure, can be represented by the equation: $$ {{{\varDelta G_{{f\left( {ox} \right)}}^o\left( {\pm 182} \right)}} \left/ {{{\mathrm{J} ~ \mathrm{mo}}{{\mathrm{l}}^{{ - 1}}}}} \right.} = - 52710 + 3.821\left( {{{T} \left/ {\mathrm{K}} \right.}} \right). $$ By using the thermodynamic data for DyRhO3 from experiment and auxiliary data for other phases from the literature, the phase relations in the system Dy-Rh-O are computed. Thermodynamic data for intermetallic phases in the binary system Dy-Rh, required for constructing the chemical potential diagrams, are evaluated using calorimetric data available in the literature for three intermetallics and Miedema’s model, consistent with the phase diagram. The results are presented in the form of Gibbs triangle, oxygen potential–composition diagram, and three-dimensional chemical potential diagram at 1,273 K. Temperature–composition diagrams at constant oxygen partial pressures are also developed. The decomposition temperature of DyRhO3 is 1,732 (±2.5) K in pure oxygen and 1,624 (±2.5) K and in air at standard pressure. 相似文献
86.
Mostafa Mesgar Dr. Payam Kaghazchi Prof. Dr. Timo Jacob Dr. Ernesto Pichardo‐Pedrero Dr. Margret Giesen Dr. Ernesto Pichardo‐Pedrero Dr. Margret Giesen Prof. Dr. Harald Ibach Dr. Noelia B. Luque Prof. Dr. Wolfgang Schmickler 《Chemphyschem》2013,14(1):233-236
Motivated by experimental studies of two‐dimensional Ostwald ripening on Au(100) electrodes in chlorine‐containing electrolytes, we have studied diffusion processes using density functional theory. We find that chlorine has a propensity to temporary form AuCl complexes, which diffuse significantly faster than gold adatoms. With and without chlorine, the lowest activation energy is found for the exchange mechanism. Chlorine furthermore reduces the activation energy for the detachment from kink sites. Kinetic Monte Carlo simulations were performed on the basis of extensive density functional theory calculations. The island‐decay rate obtained from these Monte Carlo simulations, as well as the decay rate obtained from the theoretical activation energies and frequency factors when inserted into analytical solutions for Ostwald ripening, are in agreement with experimental island‐decay rates in chlorine‐containing electrolytes. 相似文献
87.
Katia Wehbe Jacob Filik Mark D. Frogley Gianfelice Cinque 《Analytical and bioanalytical chemistry》2013,405(4):1311-1324
The study of individual cells with infrared (IR) microspectroscopy often requires living cells to be cultured directly onto a suitable substrate. The surface effect of the specific substrates on the cell growth—viability and associated biochemistry—as well as on the IR analysis—spectral interference and optical artifacts—is all too often ignored. Using the IR beamline, MIRIAM (Diamond Light Source, UK), we show the importance of the substrate used for IR absorption spectroscopy by analyzing two different cell lines cultured on a range of seven optical substrates in both transmission and reflection modes. First, cell viability measurements are made to determine the preferable substrates for normal cell growth. Successively, synchrotron radiation IR microspectroscopy is performed on the two cell lines to determine any genuine biochemically induced changes or optical effect in the spectra due to the different substrates. Multivariate analysis of spectral data is applied on each cell line to visualize the spectral changes. The results confirm the advantage of transmission measurements over reflection due to the absence of a strong optical standing wave artifact which amplifies the absorbance spectrum in the high wavenumber regions with respect to low wavenumbers in the mid-IR range. The transmission spectra reveal interference from a more subtle but significant optical artifact related to the reflection losses of the different substrate materials. This means that, for comparative studies of cell biochemistry by IR microspectroscopy, it is crucial that all samples are measured on the same substrate type. Figure
Cell separation by PCA due to the refractive index of the substrate used, revealing transmission artifact. 相似文献
88.
89.
The determination of the phase diagram of the binary system sodium perchlorate – water is reported. Beside the eutectic point, two polymorph crystal structures of sodium perchlorate dihydrate were determined. The two crystal structures are discussed, compared to each other and to other known sodiumhalide dihydrate crystal structures. The two polymorphs of the perchlorate dihydrate represent the two variants of connected octahedra in the layer structure found for sodium halide dihydrates. 相似文献
90.
Abstract A series of three oligosaccharides, α-d-Glc-(1→4)-β-d-GlcA-1ωe, β-d-GlcA-(1→4)-α-d-Glc-(1→4)-β-d-GlcA-lωe and α-d-Glc-(1→4)-β-d-GlcA-(1→4)-α-d-Glc-(1→4)-β-d-GlcA-1ωe was prepared by a short synthetic route, using maltose and glucuronic acid derivatives as starting materials. The oligosaccharides contain glucose residues instead of glucosamines, and have a less complicated structure than the corresponding unsulphated structures found in native heparin and heparan sulphate. This simplification in structure has diminished the number of synthetic steps and raised the total yield compared to the preparation of the corresponding heparin/heparan sulphate structures which have been found to bind acidic and basic FGF. 相似文献