CRYSTAL AND MOLECULAR STRUCTURE OF A NOVEL Au Ag SUPRACLUSTER COMPOUND [Au_13Ag_12(μ-Br)_4(μ_3-Br)_2(Ph_3P)_10-

<正> [Au13Ag12(μ-Br)1(μ3-Br)2 (Ph3P)10Br2] Br, monoclinic. space group C2/m, a = 36. 496(17). b=16. 878(7), c-=19. 772(9) A , β=99. 87(5)°, V=11998. 9 A3.Z=2. The final R(Rw) is 0. 097(0. 109) for 3779 reflections with I>3σ(I). The structure can he considered as two icosahedral cluster units (AurAg6) sharing one vertex and linked hy six bromine atoms. The Au - Au, Au - Ag. and Ag-Ag distances fall in the ranges of 2. 69-2. 96. 2. 84-3. 02. and 2. 92-3. 26 A, respectively.     

Student Attitudes and Calculus Reform

This paper compares the attitudes about mathematics of students from traditionally taught calculus classes and those from a “reformed” calculus course. The paper is based on three studies, which together present a consistent picture of student attitudes about calculus reform. The reformed course appeared to violate students' deeply held beliefs about the nature of mathematics and how it should be learned. Although during their first months in the reformed course most students disliked it, their attitudes gradually changed. One and 2 years after, reform students felt significantly more than the traditionally taught students that they better understood how math was used and that they had been required to understand math rather than memorize formulas.     

A FOUR-POINT BOUNDARY VALUE PROBLEM FOR NONLINEAR EQUATION

1IntroductionThemethodofupperandlowersolutionshasbecomeastandardtoolforstudyingthesolvabilityoftwo-pointboundaryvalllcproblemsassociatedwitllsecond-ordernonlineardifferentialequations.Inrecent,years,Rachunkovd[1,2,3]studiedthefour--pointboundaryvalueprobl…     

带有硬相互作用的相对论Boltzmann方程整体解存在性的证明

给出了带有硬相互作用的相对论Ｂｏｌｔｚｍａｎｎ方程初值问题整体解存在性的证明     

闪光Ⅰ号应用于X射线爆轰照相——研究金属射流的穿甲效应

闪光X射线照相技术是研究动载荷及其效应的重要测试手段,特别适用于研究物质在爆炸作用下的瞬变过程,本文介绍了闪光Ⅰ号加速器应用于X射线爆轰照相的基本状况,以及用于观察金属射流穿过高密度物质钨靶的实验技术。     

HL－1装置辅助加热等对能量约束的影响

在ＨＬ－１托卡马克上进行了辅助加热、加料、电流驱动的物理实验研究。在改善等离子体约束方面，某些实验取得了较好的结果。在适当的稳定放电条件下，低杂波电流驱动和弹丸注入辅助加料，均能使等离子体能量约束得到一定程度的改善，与相同密度条件下的欧姆加热放电相比，能量约束时间提高了约３０％。在电子回旋共振加热等离子体实验中，等离子体总能量明显增加，但与相同密度条件下的欧姆加热放电相比，能量约束时间减少了约２０％。     

Irradiation-induced reduction and luminescence properties of Sm doped in BaBPO5

Usually, Sm²⁺ ions could be reduced by heating the materials in reducing atmospheres. Exposure to ionizing radiations is also known to cause Sm³⁺→Sm²⁺ conversion. In this work, BaBPO₅ doped with the samarium ion was prepared by high temperature solid-state reaction. Sm²⁺ ions were obtained by two different reduction methods, i.e., heating in H₂ reduced atmosphere and X-ray irradiation. The measurements of X-ray diffraction (XRD), and scanning electron microscope (SEM) were investigated. It is found that the conversion of Sm³⁺→Sm²⁺ is very efficient in BaBPO₅ hosts after X-ray irradiation. Sm²⁺ ions under these two reduction methods exhibit different characteristics that were studied by measurements of luminescence and decay. The results showed that the luminescence properties of Sm²⁺ ions in BaBPO₅ were highly dependent on the sample preparation conditions.     

Cluster and periodic DFT calculations of adsorption and activation of CO2 on the Cu(hkl) surfaces

The adsorption behavior and thermal activation of carbon dioxide on the Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0) surfaces have been investigated by means of density functional theory calculations and cluster models and periodic slabs. According to the cluster models, the optimized results indicate that the basis set of C and O atoms has a distinct effect on the adsorption energy, but an indistinct one on the equilibrium geometry. For the CO₂/Cu(hkl) adsorption systems studied here, the final structure of adsorbed CO₂ is near linear and the preferred modes for the adsorption of CO₂ onto the Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0) surfaces are the side-on adsorption at the cross bridge site with an adsorption energy of 13.06 kJ/mol, the side-on adsorption at the short bridge site (13.54 kJ/mol), and the end-on adsorption on the on-top site with C–O bonds located along the short bridge site (26.01 kJ/mol), respectively. However, the calculated adsorption energies from periodic slabs are lower as compared to the experimental data as well as the cluster model data, indicating that the periodic slab approach of generalized gradient approximation in the density function theory may be not suitable to obtain quantitative information on the interaction of CO₂ with Cu(hkl) surfaces.     

光纤加速度传感器研究进展

光纤加速度传感器与传统加速度传感器相比，不但能抗电磁干扰，而且体小、质轻、动态范围宽、精度高、能在恶劣环境下工作，因此受到各先进国家军事与商业领域的极大重视，各种实用的光纤加速度传感器不断涌现。主要有光强调制型和相位调制型两大类。光强调制式有反射式、透射式和偏振式等等。相位调制式有Ｍａｃｈ－Ｚｅｎｄｅｒ干涉仪、Ｍｉｃｈｅｌｓｏｎ干涉仪和Ｆａｂｒｙ－Ｐｅｒｏｔ干涉仪。有一维的，也有二维的；有与水听器组合在一起的，也有与光纤陀螺仪组合的光纤加速度传感器。最小的已经做到２．５ｃｍ长，直径仅０．２５ｍｍ；测量精度已能达到１μｇ；共振频率可达到１０ｋＨｚ。为了克服温度不稳定性对测量精度的影响，人们采用了３×３耦合器解调法，双光路法，由单臂式改成推挽式等。一旦关键技术得以克服，光纤加速度传感器将会在惯性导航和其它领域发挥更重要的作用。本文将分别介绍目前各种类型光纤加速度传感器的结构、特点、走向实用化存在的问题。     

基于小波变换及布朗分形模型的纹理分割

在研究小波变换及布朗分形模型的基础上，定义了水平分维数，垂直分维数，对角分维数，并将它们作为纹理特征量来实现纹理的分割．实验结果表明，这些特征量能够很好地反映纹理特征，从而分割时不需有关图象中纹理类别的先验信息，较以往方法在准确度和计算复杂程度上都有很大提高．