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971.
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option. 相似文献
972.
Andrzej?Z.?Górski Jacek?SzmigielskiEmail authorView authors OrcID profile 《Journal of Nonlinear Science》2018,28(4):1361-1377
We derive isospectral flows of the mass density in the string boundary value problem corresponding to general boundary conditions. In particular, we show that certain class of rational flows produces in a suitable limit all flows generated by polynomials in negative powers of the spectral parameter. We illustrate the theory with concrete examples of isospectral flows of discrete mass densities which we prove to be Hamiltonian and for which we provide explicit solutions of equations of motion in terms of Stieltjes continued fractions and Hankel determinants. 相似文献
973.
The nuclear shape correction to the g factor of a bound electron in the 1S state is calculated for a number of nuclei in the range of charge numbers from Z=6 up to Z=92. The leading relativistic deformation correction has been derived analytically, and also its influence on one-loop quantum electrodynamic terms has been evaluated. We show the leading corrections to become significant for mid-Z ions and for very heavy elements to even reach the 10(-6) level. 相似文献
974.
The key role of carbohydrates in biological processes and their visible existence in our everyday life have stimulated the interest of leading research groups on the smart and simple synthesis of common and rare sugar molecules. Now, more than 120 years after Fischer's first synthesis of (D)-glucose (1890), we are witnessing important development in this field of total synthesis. Using modern methods of direct activation of carbonyl compounds chemists can prepare sugars in an elegant and efficient way similar to that of Nature. This tutorial review presents recent impressive progress in the area of de novo synthesis of carbohydrates by using organocatalytic direct aldol reaction as a key step. 相似文献
975.
Photodegradation of endocrine disrupting butylparaben (BP) in aerated aqueous solutions was studied using 4,4′,4″,4‴-(porphine-5,10,15,20-tetrayl)tetrakis(benzenesulphonic
acid) (TPPS4), as a sensitiser. Influence of various parameters, such as initial sensitiser and BP concentration, pH of the reaction solution
and oxygen content in the reaction solution, on the photosensitised oxidation was examined. It was found that the dominant
pathway of BP degradation occurred in the reaction with molecular singlet oxygen 1O2, i.e. via photosensitised oxidation mechanism of type II. Kinetic parameters of the BP reaction with 1O2 were estimated. 相似文献
976.
Leitch JJ Collins J Friedrich AK Stimming U Dutcher JR Lipkowski J 《Langmuir : the ACS journal of surfaces and colloids》2012,28(5):2455-2464
Quantitative subtractively normalized interfacial Fourier transform infrared reflection spectroscopy (SNIFTIRS) was used to determine the conformation and orientation of sodium dodecyl sulfate (SDS) molecules adsorbed at the single crystal Au(111) surface. The SDS molecules form a hemimicellar/hemicylindrical (phase I) structure for the range of potentials between -200 ≤ E < 450 mV and condensed (phase II) film for electrode potentials ≥500 mV vs Ag/AgCl. The SNIFTIRS measurements indicate that the alkyl chains within the two adsorbed states of SDS film are in the liquid-crystalline state rather than the gel state. However, the sulfate headgroup is in an oriented state in phase I and is disordered in phase II. The newly acquired SNIFTIR spectroscopy measurements were coupled with previous electrochemical, atomic force microscopy, and neutron reflectivity data to improve the current existing models of the SDS film adsorbed on the Au(111) surface. The IR data support the existence of a hemicylindrical film for SDS molecules adsorbed at the Au(111) surface in phase I and suggest that the structure of the condensed film in phase II can be more accurately modeled by a disordered bilayer. 相似文献
977.
Pierre Degond Alexei Lozinski Jacek Narski Claudia Negulescu 《Journal of computational physics》2012,231(7):2724-2740
The concern of the present work is the introduction of a very efficient asymptotic preserving scheme for the resolution of highly anisotropic diffusion equations. The characteristic features of this scheme are the uniform convergence with respect to the anisotropy parameter 0 < ε ? 1, the applicability (on cartesian grids) to cases of non-uniform and non-aligned anisotropy fields b and the simple extension to the case of a non-constant anisotropy intensity 1/ε. The mathematical approach and the numerical scheme are different from those presented in the previous work [P. Degond, F. Deluzet, A. Lozinski, J. Narski, C. Negulescu, Duality-based asymptotic-preserving method for highly anisotropic diffusion equations, Communications in Mathematical Sciences 10 (1) (2012) 1–31] and its considerable advantages are pointed out. 相似文献
978.
J Gaudin C Ozkan J Chalupský S Bajt T Burian L Vyšín N Coppola SD Farahani HN Chapman G Galasso V Hájková M Harmand L Juha M Jurek RA Loch S Möller M Nagasono M Störmer H Sinn K Saksl R Sobierajski J Schulz P Sovak S Toleikis K Tiedtke T Tschentscher J Krzywinski 《Optics letters》2012,37(15):3033-3035
The interaction of free electron laser pulses with grating structure is investigated using 4.6±0.1 nm radiation at the FLASH facility in Hamburg. For fluences above 63.7±8.7 mJ/cm2, the interaction triggers a damage process starting at the edge of the grating structure as evidenced by optical and atomic force microscopy. Simulations based on solution of the Helmholtz equation demonstrate an enhancement of the electric field intensity distribution at the edge of the grating structure. A procedure is finally deduced to evaluate damage threshold. 相似文献
979.
980.
We consider a class of structured cell population models described by a first order partial differential equation perturbed
by a general birth operator which describes in a unified way a wide class of birth phenomena ranging from cell division to
the McKendrick model. Using the theory of positive stochastic semigroups we establish new criteria for an asynchronous exponential
growth of solutions to such equations. 相似文献