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31.
32.
van Zutphen S Pantoja E Soriano R Soro C Tooke DM Spek AL den Dulk H Brouwer J Reedijk J 《Dalton transactions (Cambridge, England : 2003)》2006,(8):1020-1023
New asymmetric trans-platinum(II) complexes, composed of an isopropylamine, an azole and two carboxylate leaving groups, are presented. The crystal and molecular structures of one of the complexes has been determined and the cytotoxicity and reactivity with 5'-guanosine monophosphate is reported. The complexes show a reduced reactivity, but no decrease in cytotoxic activity compared to their chloro-counterparts. Furthermore the complexes largely overcome cisplatin resistance, they therefore present an interesting class of antitumour active trans-platinum complexes. 相似文献
33.
In this work, two narrow-bore capillary columns with different internal diameters (I.D.) 0.15 mm (15 m length, 0.15 microm film thickness) and 0.10 mm (10 m length, 0.10 microm film thickness) with the same stationary phase (5% diphenyl 95% dimethylsiloxane), phase ratio and separation power were compared with regard to their advantages, practical limitations and applicability in fast GC on commercially available instrumentation. The column comparison concerns fast GC method development, speed and separation efficiency, the sample transfer into the column utilizing split and splitless inlet, sample capacity, detection (analysing compounds of a wide range of polarities and volatilities--even n-alkanes C16-C28 and selected pesticides) and ruggedness (in the field of ultratrace analysis of pesticide residues in real matrix). Under conditions corresponding to speed/separation efficiency trade-off 0.10 mm I.D. versus 0.15 mm I.D. column provides a speed gain of 1.74, but all other parameters investigated were better for the 0.15 mm I.D. column concerning more efficient sample transfer from inlet to the column using splitless injection, no discrimination with split injection. Better sample capacity (three times higher for the 0.15 mm than for the 0.10 mm I.D. column) resulted in improved ruggedness and simpler fast GC-MS method development. 相似文献
34.
Jaap F. Vente Steven McIntosh Wim G. Haije Henny J. M. Bouwmeester 《Journal of Solid State Electrochemistry》2006,10(8):581-588
The present paper discusses the oxygen transport properties, oxygen stoichiometry, phase stability, and chemical and mechanical
stability of the perovskites (BSCF) and (SCF) for air separation applications. The low oxygen conductive brownmillerite phase in SCF is characterized using in-situ
neutron diffraction, thermographic analysis and temperature programmed desorption but this phase is not present for BSCF under
the conditions studied. Although both materials show oxygen fluxes well above 10 ml/cm2·min at T=1,273 K and pO2=1 bar for self-supporting, 200 μm-thick membranes, BSCF is preferred as a membrane material due to its phase stability. However,
BSCF’s long-term stable performance remains to be confirmed. The deviation from ideal oxygen stoichiometry for both materials
is high: δ>0.6. The thermal expansion coefficients of BSCF and SCF are 24×10−6 and 30×10−6 K−1, respectively, as determined from neutron diffraction data. The phenomenon of kinetic demixing has been observed at pO2<10−5 bar, resulting in roughening of the surface and enrichment with alkaline earth metals. Stress–strain curves were determined
and indicated creep behavior that induces undesired ductility at T=1,073 K for SCF. Remedies for mechanical and chemical instabilities are discussed. 相似文献
35.
We describe a new method to measure the decorrelation rate of the optical coherence tomography (OCT) magnitude simultaneously in space and time. We measure the decorrelation rate of the OCT magnitude in a Fourier-domain OCT system for a large range of translational diffusion coefficients by varying the sphere diameter. The described method uses the sensitivity advantage of Fourier-domain OCT over time-domain OCT to increase the particle diffusion imaging speed by a factor of 200. By coherent gating, we reduce the contribution of multiple scattering to the detected signal, allowing a quantitative study of diffusive particle dynamics in high concentration samples. We demonstrate that this technique is well suited to image diffusive particle dynamics in samples with a complex geometry as we measure the morphology and diffusive particle dynamics simultaneously with both high spatial and high temporal resolution. 相似文献
36.
37.
Yanbo Mei Dong‐Jun Wu Dr. Jaap E. Borger Prof. Dr. Hansjörg Grützmacher 《Angewandte Chemie (International ed. in English)》2018,57(19):5512-5515
A simple synthesis of sodium 2‐phosphanaphthalene‐3‐olate ( 1 ) based on the extrusion of N2 from phthalazine using Na[OCP] is reported. This heterocycle can be readily functionalized at the negatively charged oxygen center using a variety of electrophilic substrates. The coordination chemistry of both 1 and its neutral derivatives was explored, revealing their facile use as P‐donor ligands for late‐transition‐metal complexes. 相似文献
38.
Martijn J.J. Mulder Huub Kooijman Anthony L. Spek Jaap. G. Haasnoot Jan Reedijk 《Journal of chemical crystallography》2002,32(9):347-351
The crystal structure of the title compound, tetrabutylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III), [N(C4H9)4][Ni(C3S5)2], is the fourth known phase of this polymorphous compound. It is monoclinic space group P21/c, with a = 20.040(2) Å, b = 13.1151(17) Å, c = 12.1093(15) Å, = 105.456(15)°, and V = 3067.5(6) Å3 with Z = 4, for D
calc = 1.503 g cm–3. The [Ni(dmit)2] anion packing arrangement consists of arrays of side-on touching anions and these arrays are connected via head-to-tail close S S contacts. 相似文献
39.
Arno F. Stassen Huub Kooijman Anthony L. Spek Jaap G. Haasnoot Jan Reedijk 《Journal of chemical crystallography》2001,31(6):307-314
The compounds hexakis(1-(2-chloroethyl)-tetrazole-N4)copper(II) tetrafluoroborate mono(1-(2-chloroethyl)-tetrazole) (1) and hexakis(1-(2-chloroethyl)-tetrazole-N4) copper(II) perchlorate mono(1-(2-chloroethyl)-tetrazole) (2) were obtained from the crystallization of 1-(2-chloroethyl)-tetrazole (teec) with the respective copper salt. The X-ray structures are reported. Both compounds crystallize in the monoclinic space group C2/c for 1: a = 25.754(3) Å, b = 18.162(3) Å, c = 10.298(2) Å = 104.294(7)° and Z = 4 and for 2: a = 25.745(3) Å, b = 18.197(3) Å, c = 10.29355(3) Å = 104.512(10)° and Z = 4. The CuII ions are octahedrally surrounded by six teec ligands. One free teec ligand is present in the structures. The Cu–N distances in the centrosymmetrical units are 2.01, 2.04, and 2.39 Å in both compounds, consistent with a Jahn–Teller elongated octahedron. The ligand field spectra of both compounds show a signal in the visible range at about 15.200 cm–1 and by an EPR spectrum the following values are found: g
| = 2.29 and g = 2.03. The compounds are both paramagnetic and the T value of 0.37 cm–1 K mol–1, which is associated with S = 1/2, is what would be expected for a mononuclear CuII complex. 相似文献
40.
Castricum HL Sah A Kreiter R Blank DH Vente JF ten Elshof JE 《Chemical communications (Cambridge, England)》2008,(9):1103-1105
Unprecedented hydrothermal stability in functional membranes has been obtained with hybrid organic-inorganic nanoporous materials, enabling long-term application in energy-efficient molecular separation, including dehydration up to at least 150 degrees C. 相似文献