Coulomb excitation of 72 30Zn42

The reduced transition probability B(E2: 0₁ ⁺→ 2⁺) of ⁷²Zn has been measured for the first time by Coulomb excitation at intermediate energy. The result B(E2: 0₁ ⁺→ 2⁺) = 1740±210 e²fm⁴, corresponds to the deformation parameter β₂ of 0.23, in close agreement with expectations derived from the neighboring nucleus ⁷³Zn. A discussion of the evolution of the N = 40 sub-shell closure as a function of Z is presented. Received: 19 December 2001 / Accepted: 14 March 2002     

Structure of 12Be: intruder d-wave strength at N=8

The breaking of the N=8 shell-model magic number in the 12Be ground state has been determined to include significant occupancy of the intruder d-wave orbital. This is in marked contrast with all other N=8 isotones, both more and less exotic than 12Be. The occupancies of the [FORMULA: SEE TEXT]orbital and the [FORMULA: SEE TEXT], intruder orbital were deduced from a measurement of neutron removal from a high-energy 12Be beam leading to bound and unbound states in 11Be.     

Investigating acidity of metal fluoride surfaces by spectroscopic and chemical methods

Recent investigations into the surface acidity of some aluminium and magnesium fluorides and their derivatives are reviewed with emphases on relative acidities and accessibilities of surface sites. The high specific surface areas of the materials are ideal for their study, either by FTIR spectroscopy using various probe molecules that have different basicity and steric requirements or by carrying out probe reactions that are catalysed by acidic surfaces. Context for some of the recent work is provided by a summary of the commercial catalyst, fluorinated chromia and the related, fluorinated aluminas; a particular emphasis in these sections is their catalysis of reactions that involve carbon–halogen species. For the high surface area metal fluorides and their derivatives, room temperature dehydrochlorination of tert-butyl chloride, employing chlorine-36 labelling to detect surface adsorbed species, enables comparative studies of surface acidity to be undertaken.     

Pattern generation using axicon lens beam shaping in two-photon polymerisation

The fabrication of three-dimensional microstructures by two-photon polymerisation has been widely reported as a viable route to the development of photonic crystals, rotors, bridges and other complex artefacts requiring nanoscale resolution. Conventionally, single point serial writing is used to write the structures but recently multipoint beam delivery using beam division optics has been reported as a method of introducing parallel processing. In this paper we present an alternative and novel approach using an axicon lens to give profiled beam delivery. This enables complete three-dimensional annular structure fabrication without the use of scanning stages. In addition, the concept of axicon delivery is developed further to investigate three-dimensional structure as a function of axicon geometry.A Ti:sapphire laser, with wavelength 795 nm, 80 MHz repetition rate, 100 fs pulse duration and an average power of 700 mW, was used to initiate two-photon polymerisation. The axicon was used, in combination with a 100× microscope objective, to form representative three-dimensional structures based on the annular cell with varying diameter. The structures were written in a Zr-loaded resin prepared on a glass substrate using dip coating deposition of a Zr/PMMA hybrid prepared by the sol-gel method. Annuli with diameters up to 50 μm were characterised in terms of topography and surface roughness using SEM and Zygo interferometer. The writing technique was also extended to fabrication of stacked structures.     

Commissioning of the MAGNEX large-acceptance spectrometer

The MAGNEX large-acceptance spectrometer has been commissioned with beams from the Tandem accelerator at INFN-LNS Catania. The optics were tested with elastically-scattered ⁷Li, ¹⁶O and ⁴⁸Ti beams with various apertures mounted after the target. The momentum dispersion was verified to be in agreement with the optics calculations. A demonstration of the particle identification capabilities of the PSD start detector and the focal plane detector was given by a measurement of the ²⁷Al(⁷Li,⁶Li)²⁸Al transfer reaction at a mean angle of 25°. The measured charge state distribution of ⁴⁸Ti ions is in agreement with predictions for a gold stripping foil. Preliminary results of the software reconstruction of incident angle and excitation energy, obtained through matrices based on a 3D-interpolation of the measured field maps, are encouraging.     

Incorporating dust lift-off into a CFD model of a blast furnace gravity dust-catcher

A gravity dust-catcher separates a mixture of dusts from the spent top gas flow of a blast furnace. These dusts are predominantly made up of limestone, iron ore and coke/coal. As a result of the turbulent gas flow patterns within a dust-catcher, modelling of the flow pattern can be very complex, attributed to the turbulent vortices that can be formed within the main body of the structure. Using data from an experimental prototype test rig, a simple model to capture the lift-off characteristics of particle lift-off from dust pile surfaces is created and incorporated into a computational fluid dynamics (CFD) model of the dust-catcher.The variation of particle separation performance over a typical blast furnace (BF) operational cycle is analysed. An attempt is made to explain the observed phenomena in terms of particle–fluid interaction. It is found that particle separation efficiency is largely unaffected by dust lift-off at low dust-catcher hopper fullness levels, but is significant at higher levels. It is found that the topography of the dust surface is important when predicting particle lift-off trends. It is concluded that this is due to the exposure experienced by a given particle when subjected to a surface velocity.     

The overshoot phenomenon as a function of internal resistance in microbial fuel cells

A method for assessing the performance of microbial fuel cells (MFCs) is the polarisation sweep where different external resistances are applied at set intervals (sample rates). The resulting power curves often exhibit an overshoot where both power and current decrease concomitantly. To investigate these phenomena, small-scale (1 mL volume) MFCs operated in continuous flow were subjected to polarisation sweeps under various conditions. At shorter sample rates the overshoot was more exaggerated and power generation was overestimated; sampling at 30 s produced 23% higher maximum power than at 3 min. MFCs with an immature anodic biofilm (5 days) exhibited a double overshoot effect, which disappeared after a sufficient adjustment period (5 weeks). Mature MFCs were subject to overshoot when the anode was fed weak (1 mM acetate) feedstock with low conductivity (<100 μS) but not when fed with a higher concentration (20 mM acetate) feedstock with high conductivity (>1500 μS). MFCs developed in a pH neutral environment produced overshoot after the anode had been exposed to acidic (pH 3) conditions for 24 h. In contrast, changes to the cathode both in terms of pH and varying catholyte conductivity, although affecting power output did not result in overshoot suggesting that this is an anodic phenomenon.