Recent Developments in Solid-Propellant Binders

Abstract

The complex and important role of the propellant binder in solid-propellant rockets is described. The severe weight problems of space exploratrion cause high propellant performance to be of major concern in a highly competitive field. Binders contribute to performance, not only in terms of fuel value, but by being compatible with energetic components and by providing good mechanical properties. Both sterilization required for planetary landings and compatibility problems of new energetic oxidizers generate new requirements too stringent for existing binders; only binders composed essentially of saturated aliphatic hydrocarbon are predicted to be suitable. Several saturated-binder developments are in progress. The achievements of one of these programs, based on free-radical synthesis, are evaluated against the goals of the new binder.     

The embeddability ordering of topological spaces

For K a set of topological spaces and X,Y∈K, the notation Xh_⊆Y means that X embeds homeomorphically into Y; and X∼Y means Xh_⊆Yh_⊆X. With , the equivalence relation ∼ on K induces a partial order h_? well-defined on K/∼ as follows: if Xh_⊆Y.For posets (P,P_?) and (Q,Q_?), the notation (P,P_?)?(Q,Q_?) means: there is an injection such that p₀P_?p₁ in P if and only if h(p₀)Q_?h(p₁) in Q. For κ an infinite cardinal, a poset (Q,Q_?) is a κ-universal poset if every poset (P,P_?) with |P|?κ satisfies (P,P_?)?(Q,Q_?).The authors prove two theorems which improve and extend results from the extensive relevant literature.

Theorem 2.2. There is a zero-dimensional Hausdorff space S with|S|=κsuch that(P(S)/∼,h_?)is a κ-universal poset.     

Possible mesonic effects on inelastic proton scattering to the 10.24 MeV 1+ state in 48Ca

Differential cross sections and analyzing powers were measured for inelastic scattering of 160 MeV protons to the ⁴⁸Ca 10.24 MeV, 1⁺ state. DWIA calculations with shell-model wave functions which fit inelastic electron scattering form factors predict too much cross section at small q and too little at large q for inelastic proton scattering. These results are consistent with the q-dependent modification of magnetic transitions anticipated from mesonic effects such as virtual Δ(1232)-hole excitations.     

Formal hydride transfer mechanism for photoreduction of 3-phenylquinoxalin-2-ones by amines. Association Of 3-phenylquinoxalin-2-one with aliphatic amines

The photophysical and photochemical behavior of 1-methyl-3-phenylquinoxalin-2-one (MeNQ) and 3-phenylquinoxalin-2-one (HNQ) in the presence of amines is reported. While HNQ fluorescence shows an auxochromic effect and a bathochromic shift with added amines, explained by association of HNQ with amine in the ground state and emission from both excited species HNQ and [HNQ-amine], both MeNQ and HNQ are photoreduced efficiently on irradiation in the presence of amines, leading to the semireduced quinoxalin-2-ones, MeNQH(-) and HNQH(-), respectively, via an electron-proton-electron transfer, with unit quantum yields at high amine concentrations. The semireduced quinoxalin-2-ones XNQH(-) (X = H, Me) revert almost quantitatively to the parent XNQ in a dark thermal reaction with an activation free energy for MeNQH(-) of 17.4 and 25.9 kcal/mol in acetonitrile and benzene, respectively. Kinetic and spectroscopic (UV and NMR) evidence supports the proposed reaction mechanism for the reversible photoreduction.     

ABSORPTION AND EMISSION STUDIES OF ELECTRONIC STATES OF N-ARYLBENZAMIDES

Abstract— Absorption and emission spectra of several N-arylbenzamides have been measured. The quantum yields for their fluorescence were found to be dependent on matrix viscosity and temperature. Singlet-triplet splittings for these compounds were determined from their emission spectra and found to be abnormally small for π. π* states (˜ 1500 cm^-1). Indeed, the phosphorescence maxima of N-arylbenzamides occur slightly to the blue relative to their fluorescence maxima. Intersystem crossing efficiencies were determined for several of these compounds and are consistent with S₁→ S ₀ radiationless decay.