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31.
Andreia PeixotoMariette M. Pereira M.Graça P.M.S. NevesArtur M.S. Silva José A.S. Cavaleiro 《Tetrahedron letters》2003,44(30):5593-5595
Formyl derivatives of protoporphyrin-IX dimethyl ester metal complexes were obtained via hydroformylation reactions, catalysed by rhodium-triphenylphosphine complexes. The regioselectivity of the reaction is remarkably dependent on the metal centre of the porphyrin, yielding 100% of the branched aldehyde with zinc(II) complexes and 75% with the nickel(II). The NMR characterisation of the new compounds was carried out after their derivatisation into acetals. 相似文献
32.
David Hoff 《Journal of Mathematical Fluid Mechanics》2005,7(3):315-338
We prove the global existence of weak solutions of the Navier–Stokes equations of compressible flow in a half-space with the boundary condition proposed by Navier: the velocity on the boundary is proportional to the tangential component of the stress. This boundary condition allows for the determination of the scalar function in the Helmholtz decomposition of the acceleration density, which in turn is crucial in obtaining pointwise bounds for the density. Initial data and solutions are small in energy-norm with nonnegative densities having arbitrarily large sup-norm. These results generalize previous results for solutions in the whole space and are the first for solutions in this intermediate regularity class in a region with a boundary. 相似文献
33.
A data set of 29 experimentally determined Newby shifts in rare-earth nuclei is examined for the reliability of each values.
Using this data set, Newby shifts are obtained which are free from the Coriolis and the particle-particle coupling effects.
These new empirical values help resolve the failure of a recently proposed rule for the sign of the Newby shift in the {5/2[413]p − 5/2[642]n} configuration of160Tb and the {5/2[402]p − 5/2[512]n} configuration of174Lu. Also the Newby shifts are significantly modified in two other cases namely the {1/2[411]p − 1/2[521]n} configuration in168Tm and the {1/2[541]p − 1/2[521]n} configuration in172Lu. Only marginal changes are seen in the rest of the cases in the rare-earth nuclei. 相似文献
34.
The collapse of a charged and radiating ball in the diffusion limit is studied using a method reported by Herrera and collaborators. The interior solution is matched with the exterior Reissner-Nordström-Vaidya metric to obtain a system of differential equations at the surface of the distribution, which can be integrated numerically for some set of initial data. For one model, the profiles of the physical variables are obtained at any piece of the material in terms of Schwarzschild-like coordinates. 相似文献
35.
Some basic concepts about curvature collineations are reviewed and the existing results on this topic are applied to the case of perfect fluids, giving a characterization of those amongst them which admit proper curvature collineations. 相似文献
36.
Jorge F. J. Coelho Ana M. F. P. Silva Anatoliy V. Popov Virgil Percec Mariana V. Abreu Pedro M. O. F. Gonalves M. H. Gil 《Journal of polymer science. Part A, Polymer chemistry》2006,44(9):3001-3008
The synthesis of a block copolymer poly(vinyl chloride)‐b‐poly(n‐butyl acrylate)‐b‐poly(vinyl chloride) is reported. This new material was synthesized by single‐electron‐transfer/degenerative‐chain‐transfer‐mediated living radical polymerization (SET‐DTLRP) in two steps. First, a bifunctional macroinitiator of α,ω‐di(iodo)poly (butyl acrylate) [α,ω‐di(iodo)PBA] was synthesized by SET‐DTLRP in water at 25 °C. The macroinitiator was further reinitiated by SET‐DTLRP, leading to the formation of the desired product. This ABA block copolymer was synthesized with high initiator efficiency. The kinetics of the copolymerization reaction was studied for two PBA macroinitiators with number–average molecular weight of 10 k and 20 k. The relationship between the conversion and the number–average molecular weight was found to be linear. The dynamic mechanical thermal analysis suggests just one phase, indicating that copolymer behaves as a single material with no phase separation. This methodology provides the access to several block copolymers and other complex architectures that result from combinations of thermoplastics (PVC) and elastomers (PBA). From industrial standpoint, this process is attractive, because of easy experimental setup and the environmental friendly reaction medium. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3001–3008, 2006 相似文献
37.
Jorge F. J. Coelho Ana M. F. P. Silva Anatoliy V. Popov Virgil Percec Mariana V. Abreu Pedro M. O. F Gonalves M. H. Gil 《Journal of polymer science. Part A, Polymer chemistry》2006,44(9):2809-2825
Living radical polymerization of n‐butyl acrylate was achieved by single electron transfer/degenerative‐chain transfer mediated living radical polymerization in water catalyzed by sodium dithionate. The plots of number–average molecular weight versus conversion and ln[M]0/[M] versus time are linear, indicating a controlled polymerization. This methodology leads to the preparation of α,ω‐di(iodo) poly (butyl acrylate) (α,ω‐di(iodo)PBA) macroinitiators. The influence of polymerization degree ([monomer]/[initiator]), amount of catalyst, concentration of suspending agents and temperature were studied. The molecular weight distributions were determined using a combination of three detectors (TriSEC): right‐angle light scattering (RALLS), a differential viscometer (DV), and refractive index (RI). The methodology studied in this work represents a possible route to prepare well‐tailored macromolecules made of butyl acrylate in an environmental friendly reaction medium. Moreover, such materials can be subsequently functionalized leading to the formation of different block copolymers of composition ABA. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2809–2825, 2006 相似文献
38.
Ana I. R. N. A. Barros Artur M. S. Silva 《Monatshefte für Chemie / Chemical Monthly》2006,137(12):1505-1528
Summary. Several nitroflavone derivatives were synthesized by cyclodehydrogenation of 2′-hydroxychalcones and by the Baker-Venkataraman approach, starting from 2′-hydroxyacetophenones and benzoic acid derivatives. Nitroflavones synthesised by the first synthetic
approach were obtained in better global yields than those obtained by the later method. The structures of all new compounds
were elucidated by microanalyses, 1D and 2D NMR, IR, and mass spectroscopic measurements. 相似文献
39.
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