Quasinormal Modes of a Coupled Scalar Field in the Acoustic Black Hole Spacetime

By using the third-order Wentzel-Kramers-Brillouin approximation and the monodromy methods, the quasnormal modes of a coupled scalar field in the canonical non-rotating acoustic black hole spacetime are investigated. It is shown that the coupling between the scalar field and background metric affects the quasinormal frequencies. At low overtones, both the real part and the magnitude of imaginary part increase with the couple factor ξ. For the larger ξ, both of them are almost linearly related to the couple factor. At high overtones, it is found that the frequency formula of the quasinormal modes is 2πω/κ = ln （ 1 ＋ 2 cos√9-24ξ/5 π） - i（2n ＋ 1）π, which means that 5 when ξ is larger, the real part is the linear function of ξ^1/2.     

闪耀光栅光强分布的一种求解方法

以反射式闪耀光栅为例,提出了一种根据多孔夫琅禾费衍射性质来计算闪耀光栅夫琅禾费衍射光强分布的方法,得到的结果和教材完全一致.     

关于非时齐马氏过程的分枝点

从一般的非时齐马氏过程出发引入并讨论了基本随机连续拓扑和分枝点,证明了分枝点与基本随机连续函数的密切联系并给出了分枝点的充分必要条件.     

具有红色荧光性质的掺硒碳点在生物传感和抗菌中的多功能应用

以易得的苯亚硒酸(BA)和邻苯二胺(o-PDA)作为前体，通过一步水热法成功设计并合成了掺杂硒的碳点(Se-CDs)。制备的Se-CDs发出红色波段的荧光，并被用于开发一种检测microRNA-21(miR-21)的灵敏荧光传感器。通过脱氧核糖核酸酶Ⅰ(DNase Ⅰ)介导的信号放大方法，将miR-21的检测限从78 nmol·L^-1改进到了6.8 nmol·L^-1。此外，Se-CDs对大肠杆菌等革兰氏阴性菌具有理想的抑制活性。     

ANALYTIC EQUATION OF STATE FOR GENERALIZED LENNARD-JONES SOLID INCLUDING LOWEST-ORDER ANHARMONIC AND CORRELATION CORRECTIONS*

Based on the cell model, the general formula for the free energy of solids is derived analytically with the lowest order anharmonic modification and correlation effect taken into account. Combining a method of summing over lattice sites, the analytic equation of state for generalized Lennard-Jones solid is derived. The calculations show that the agreement between theory and computer simulation is quite good and is significantly improved as compared with the numerical results in literature. The comparison of different effects shows the theory including all neighbors but only considering the lowest anharmonic and correlation effects may be a good and convenient approximation for practical solids. The approximation can be easily extended to the quantum case and other generalized potentials.     

甘松不同溶剂提取物的抗氧化活性研究

采用DPPH、ABTS、羟自由基、超氧阴离子和还原力五种体外抗氧化测定方法对甘松95%乙醇提取物以及石油醚萃取物,乙酸乙酯萃取物,正丁醇萃取物和水萃取物等4个不同极性部位的抗氧化活性进行评价,同时分析抗氧化活性与其总多酚和总黄酮含量的相关性。研究结果表明,除水和石油醚萃取物外,甘松其他3个萃取物均表现出一定的抗氧化活性,且与总多酚和总黄酮含量呈显著相关。其中,乙酸乙酯萃取物中总黄酮和总多酚含量最高,分别为(157.22±1.89)mg·g-1和(99.43±1.23)mg·g-1,其清除DPPH、ABTS、超氧阴离子和羟自由基的IC50分别为(0.20±0.02)mg·mL-1、(0.15±0.01)mg·mL-1、(0.29±0.02)mg·mL-1和(0.35±0.02)mg·mL-1。甘松的乙酸乙酯萃取物具有显著的抗氧化活性,可以成为天然抗氧化活性化合物的良好来源。     

Synthesis and Crystal Structure of a Bimetallic Cyanide-bridged Complex Derived from Manganese(Ⅲ) Schiff-base Complex and Pentacyanidonitrosylferrate(Ⅱ) Building Blocks

A new cyanide-bridged bimetallic assembly [Mn(3-meosalpn)(H2O)]2[Fe(CN)5NO](1) was obtained by the reaction of [Fe(CN)5NO]2-with [Mn(3-meosalpn)]+,and characterized by elemental analysis,IR and single-crystal X-ray structure analysis.The complex crystallizes in the monoclinic system,space group P21/c with a = 12.992(5),b = 13.274(6),c = 14.644(6) ,β = 115.198(4)o,V = 2285.2(16)3,Z = 2,C43H44FeMn2N10O11,Mr = 1042.61,Dc = 1.515 g/cm3,F(000) = 1072,μ = 0.928 mm-1,S = 1.052,the final R = 0.0347 and wR = 0.0957 for 17377 observed reflections(Ⅰ 2σ(Ⅰ)).X-ray single-crystal diffraction analysis reveals that 1 has a trinuclear molecular structure,in which the two [Mn(3-meosalpn)(H2O)]+ cations are linked by the central [Fe(CN)5NO]2-anion via two trans CN-groups.Furthermore,the two [Mn(3-meo-salpn)(H2O)]+ cations and [Fe(CN)5NO]2-anion are connected into a one-dimensional zigzag chain through hydrogen bonding interactions.     

色散作用能更简捷的推导

基于色散作用的本质，利用宏观电介质形式，更一般且更简捷地得到了各种维度的色散作用能。     

Ca/Al物质的量比对Ni/CaO-Al_2O_3结构及其催化重整性能的影响

合成兼具催化、吸附性能的复合催化剂是实现CO_2吸附强化CH_4/H_2O重整制氢过程的关键。研究采用共沉淀法制备了一系列具有类水滑石结构前驱体的Ni/Ca O-Al_2O_3复合催化剂,考察了制备过程中Ca/Al物质的量比对复合催化剂结构及性能的影响。结果表明,Ca/Al物质的量比可调控活性组分Ni与载体之间的相互作用力,进而调变复合催化剂的比表面积和活性组分Ni的分散度。当Ca/Al物质的量比为3时,Ni与载体之间相互作用力适宜,复合催化剂具有最大的比表面积(12.9 m~2/g)和最高的Ni分散度(1.07%);该复合催化剂在CO_2吸附强化CH_4/H_2O重整制氢过程中可得到95%的H_2浓度和88%的CH_4转化率,循环10次后,H2浓度仍能保持在93%以上。     

纳米粒子的控制生长和自组装研究进展

由于在纳米器件上潜在应用,通过化学方法控制的纳米粒子生长,以及纳米粒子自组装的一维、二维和三维点阵受到人们的广泛关注。本文介绍来近年来纳米粒子的控制生长和组装研究的现状。主要探讨了有机稳定剂对纳米粒子形状和尺寸控制的影响。含配位基团和长链烷烃的有机化合物不但可以用控制纳米粒子生长的稳定剂,而且可以用作纳米粒子自组装的模板剂。