The solvability conditions for inverse eigenproblem of symmetric and anti‐persymmetric matrices and its approximation

The problem of generating a matrix A with specified eigen‐pair, where A is a symmetric and anti‐persymmetric matrix, is presented. An existence theorem is given and proved. A general expression of such a matrix is provided. We denote the set of such matrices by ??????_Eⁿ. The optimal approximation problem associated with ??????_Eⁿ is discussed, that is: to find the nearest matrix to a given matrix A* by A∈??????_Eⁿ. The existence and uniqueness of the optimal approximation problem is proved and the expression is provided for this nearest matrix. Copyright © 2002 John Wiley & Sons, Ltd.     

基于分形维数的液体爆炸分散中界面破碎形态研究

通过对爆炸抛撒图象的处理,得到液体界面的曲线.采用盒维数的计算方式,计算界面曲线的分形维数.通过对各时刻液体界面分形维数的变化研究,分析爆炸抛撒近场阶段的变化过程,同时观察到蘑菇状尖顶的出现与破碎,以及空化区域的形成和消失现象。     

流动注射-ICP光谱分析中的基体效应和酸效应研究

本文讨论了流动注射-ICP光谱分析中的基体效应和酸效应。当基体(Na、Ca、Fe、Zn)的浓度大于5mg/ml时,待测元素的谱线强度表现出不同程度的降低;上述基体的引入对激发温度和电子密度的影响不明显;基体产生的抑制效应可能与改变了待测元素粒子的激发几率的因素有关;于载流体中加入一定量的基体元素,是消除或降低基体效应的有效方法。酸(HCl、HNO_3、H_2SO_4)对待测元素表现出不同程度的抑制效应,其主要原因是物理干扰所致。     

GaAs/AlAs超晶格的近共振喇曼散射研究

本文介绍GaAs/AlAs超晶格的室温近共振喇曼散射测量结果。由于超晶格中Fr?hlich相互作用的共振增强效应,GaAs LO声子偶模的散射得到了很大的增强。和前人的结果一样,在偏振谱我们观察到了偶模。但和前人的结果不同,在退偏振谱中我们观察到的是奇模,而不是偶模。从而证明了在近共振条件下LO声子限制模仍遵从与非共振时一样的选择定则。二级喇曼散射实验结果表明,在偏振谱中二级谱是由两个偶模组合而成,而在退偏振谱中的二级谱与前人的结果不同,由一个奇模与一个偶模组合而成。上述结果与最近提出的黄朱模型的预言是一 关键词：     

5,10-二(对-氨基)四苯基卟啉和吖啶黄之间激发能量的传递

利用Forster能量传递机制,研究了氯仿溶液中吖啶黄向5、10-二(对-氨基)四苯基卟啉(简称TBP)的激发能量传递和TBP.浓度变化时对能量传递速度常数的影响.实验结果表明,吖啶黄和TBP之间具备能量共振传递的条件,并且计算了能量共振传递的临界距离为0.42nm、传递效率为0.72和传递速度常数为1.42×107s-1.这些数据对复合膜光电转换器件的设计将具有重要意义.     

A trace class operator inequality

In this note, we generalize the inequality about the trace of positive semidefinite matrix trk(AB)?k(trA)k(trB) to Hilbert space, and obtain a relevant inequality about positive trace class operator.     

迭代的计算与估计

对高次多项式函数这类非线性映射给出了一般 n次迭代的一个计算结果 ,还讨论了一维欧氏空间中一些非多项式型映射的迭代 .在二维欧氏空间中 ,我们给出了几类特殊的非线性迭代的结果 .对于一些难以精确计算迭代表达式的映射 ,我们给出了其迭代的估计 .     

Synthesis and optoelectronic properties of silole‐containing polyfluorenes with binary structures

2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high M_w up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007     

17N+197Au反应中碎片与中子的符合测量

在3?3?.4MeV/u ¹⁷N束轰击¹⁹⁷Au靶产生的反应中,利用放置于不同角度组合的17个中子探测器(4°—83°)和14个半导体望远镜(2.3°—9.0°)对反应产物碎片与中子进行了符合测量.经对所得实验角分布积分得到Z=3—6元素的同位素产额分布.在参加者-旁观者模型框架下,采用¹⁷N原子核内部的不同密度分布计算了同位素产额分布并与实验数据做比较.