Anthracylmethyl Benzoazacrown Ether as Selective Fluorescence Sensors for Zn^2＋

A new benzoazacrown ether fluorescence sensor was synthesized with 9-anthrylmethyl chloride and benzoaza-15-crown-5 in CH3CN, which particularly shows a strong affinity for Zn^2 .Its fluorescence quantum yield increase more than one order of magnitude and a red shift could be noticed when passing from the apolar to the polar solvent.     

三聚氰胺(C_3N_6H_6)的高压Raman与压致结构相变研究

本文在8 7GPa压力范围内研究了三聚氰胺(C3N6H6)的高压原位Raman光谱。通过内、外Raman活性模的压致效应,发现在1 5GPa和6 0GPa压力下该分子晶体发生了压致结构相变。用空间群相关原理确认在1 5GPa压力下它从单斜相转变为三斜相;在6 0GPa压力下又发生了另一次结构相变。然后在室温高压条件下对三聚氰胺进行了原位同步辐射能量散射x-ray衍射实验(EDXD),在14 7GPa压力范围内,观察到常压下为单斜晶系的三聚氰胺经历了两次压致结构相变。在1 3GPa下,三聚氰胺分子晶体从单斜相转变为三斜相;在8 2GPa又转变为正交相。本实验结果为利用三聚氰胺碳氮有机分子晶体高温高压合成超硬C3N4共价晶体的研究提供了重要信息。     

离子交换法从N-Ac-DL-Methionine的酶拆分液中分离制备L-Methionine和N-Ac-D-Methionine

依据N-Ac-DL-Methionine的酶拆分液及其组分特有的性质，采用强酸型阳离子交换柱成功地将拆分液中各组分进行分组．分析了流出液的pH和L-Met浓度的变化规律和原因；讨论并确定了柱的交换容量与所加拆分液中钠的含量的最佳比值范围．本实验方法不仅可以获得L-Met，且兼得N-Ac-D-Met，二者的收率在小试中分别达到85％以上75％左右．     

ICP-AES法测定人血清中的硒

采用消化法预处理血清样品 ,并用ICP AES法测定样品中的Se ,同时 ,探索Fe的存在对测定的干扰情况以及干扰的消除方法。结果表明 ,Se的检测限为 0 0 0 76μg·mL- 1 ,加标回收率为 91 6 % ,1 0次测定的RSD(n =1 0 )为 2 1 4 7% ;在样品中加入KOH ,可以大大降低Fe对Se测定的干扰。     

求解资源约束项目调度问题的启发式算法综述

本文综述了求解RCPSP的启发式算法.首先在对各种优先权规则进行归纳的基础上,概述基于优先权规则的RCPSP启发式算法研究现状;其次,综述项目进度的表述方式及常用超启发式策略,汇总求解RCPSP的超启发式算法的研究成果.此外,简要介绍除上述两大类启发式算法之外的其他几种启发式算法;最后,对全文进行总结,并指出该领域几个有希望的研究方向.     

Optical Waveguide Formed in Yb：KLu（WO4）2 Crystal by 6.0 MeV O^＋ Implantation

A planar optical waveguide is formed in monoclinic double rare-earth-tungstate laser crystal Yb：KLu（WO4）2 by 6.0 Me V oxygen ion implantation with a dose of 2 × 10^16 ions/cm^2 at room temperature. Subsequently, annealing at 300℃ for an hour in air is performed on the sample to decrease colour centres to improve the thermal stability of the waveguide. The refractive index profiles of the waveguide are reconstructed by an effective refractive index method. Dark modes of the waveguide are observed at wavelengths of 633 nm and 1539 nm. TRIM＇98 is used to simulate the damage profile caused by the implantation process. It is found that the refractive index change may be mainly due to the damage induced by the nuclear energy loss.     

Copper(Ⅱ) and 2,2′-Biimidazolyl-promoted Ullmann Coupling Reaction of Phenols and Aryl Iodides

Ullmann-type diaryl ether synthesis can be performed at 100℃ in good to excellent yields by aryl iodides asthe substrates under the assistance of copper(Ⅱ)and 2,2'-biimidazolyl.     

非连通图G_1uG_2及G_1uG_2uK_2的优美性

将k-优美图的概念进行了推广,引入了k～l 优美图及标号间距的概念,并以此为基础, 分别推出了一般情形下判定非连通图G_1 ∪G_2及G_1 ∪G_2 ∪K_2是优美图的两个充分条件;同时得出了图(C_3 ∨(?)_n)∪St(m)∪K_2是优美图,其中k、l 为自然数,l相似文献   

Study on the acoustic emission-model of concrete damage

I.lntroductiollBecausetherearethedefects.cracksandnon-homologousmicrostructurewithdifferentpropertiesincollcrete,whenaloadisputonconcretematerialthedamageandbreakagemayresultandsoonafterwardsexpanded.Itisadifficutproblem,howtodecidethedamageofconcretematerialwithcracksanddefects.TheacousticemissionisanassociatedphenomenollwiththeprocessofthenonhomologousdeformationorthebreakaeandexPansiollofmaterial.InthispaPertherelationshipbetweentheacousticemis8ionparametersandthedamageparameters,andthedam…