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García Ruano JL Gamboa AE Gutiérrez LG Martín Castro AM Rodríguez Ramos JH Yuste F 《Organic letters》2000,2(6):733-736
A new kind of chiral dienophiles, cyclic vinyl-p-tolylsulfilimines (2a and 2b), were obtained from the corresponding (Z)-sulfinylacrylonitriles with HBF(4) and methanol. The asymmetric Diels-Alder reaction of optically pure 2a with cyclopentadiene under mild thermal or catalyzed conditions afforded only the endo-4a adduct with complete endo and pi-facial selectivities. The ability of the sulfilimine moiety to enhance the dienophilic reactivity of the double bond is similar to that of the sulfinyl group. 相似文献
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J.H. Caltenco J. López-Bonilla A. Zúñiga-Segundo 《Czechoslovak Journal of Physics》2002,52(8):901-909
This work shows how the equations which relate the Lanczos potential K
ijr to the conformal tensor C
abpq, can be structured in a simple form when written in terms of the formalism proposed by Geroch-Held-Penrose. As working examples, we present the immediate construction of K
ijk for any spacetime with Petrov type O, N or III. Our findings are in good agreement with already published results, which indicates a relationship between the spin coefficients and the Lanczos spintensor onto the canonical tetrad. 相似文献
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Schoonbeek FS van Esch JH Hulst R Kellogg RM Feringa BL 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(14):2633-2643
Several geminal bis-urea compounds were synthesised by means of an acid-catalysed condensation of various benzaldehydes with different monoalkylureas. Many of these compounds form thermoreversible gels with a number of organic solvents at very low concentrations (<3mM) and which are stable to temperatures higher than 100 degrees C. Electron microscopy revealed a three-dimensional (3D) network of intertwined fibres, which are several tens of micrometers long and have a width ranging from approximately 30 to 300 nm. The possible aggregate forms and aggregate symmetries were evaluated by means of molecular mechanics calculations. 1H NMR, 2D NMR, 13C NMR and 13C-CP/MAS NMR techniques were used to obtain information about the aggregation and possible aggregate symmetry of geminal bis-ureas in solution, in the gel state, and in the solid state. 相似文献
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Marsman AW Havenith RW Bethke S Jenneskens LW Gleiter R van Lenthe JH Lutz M Spek AL 《The Journal of organic chemistry》2000,65(15):4584-4592
Long-range sigma-pi interactions in tetrahydro4H-thiopyran end-capped oligo(cyclohexylidenes) were identified by He(I) photoelectron spectroscopy (PES) and ab initio RHF/6-31G* calculations. The vertical ionization energies Ivj of the highest occupied molecular orbitals (MO's) were assigned using Koopmans' theorem (Iv,j = -epsilonj) and by correlation with the ionizations of related reference compounds. The experimental (PES) and theoretical (RHF/6-31G*) results are in good agreement. For tercyclohexylidene derivatives which contain two nonconjugated pi-bonds splittings deltaIv,j of the pi-bands in the range from approximately 0.5 to 0.7 eV (delta-epsilonj approximately 0.6 to 0.9 eV). For the bi- and tercyclohexylidene compounds containing two sulfur atoms at their alpha- and omega-end positions the pi-type sulfur lone pair bands [Lppi(S)] split significantly by deltaIvj approximately 0.3 to 0.4 eV (delta-epsilonj approximately 0.3 to 0.4 eV), i.e. sigma-pi interactions over distances of ca. 8 and 12 A, respectively, occur. The magnitude of the interactions and the observed splittings are independent of the anti and syn conformations of the oligo(cyclohexylidene) hydrocarbon skeletons. RHF/6-31G* Natural Bond Orbital analyses reveal that the Hax-C-C-Hax precanonical MO's (PCMO's) centered on the cyclohexyl-type rings are paramount for the relay of the through-bond sigma-pi interactions; no through-space sigma-pi interactions were identified. 相似文献
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Abbott T Akiba Y Beavis D Bloomer MA Bond PD Chasman C Chen Z Chu YY Cole BA Costales JB Crawford HJ Cumming JB Debbe R Engelage J Fung SY Gushue S Hamagaki H Hansen O Hayano RS Hayashi S Homma S Huang HZ Ikeda Y Juricic I Kang J Katcoff S Kaufman S Kimura K Kitamura K Kurita K Ledoux RJ Levine MJ Miake Y Morse RJ Moskowitz B Nagamiya S Olness J Parsons CG Remsberg LP Sakurai H Sarabura M Stankus P Steadman SG Stephans GS Sugitate T Tannenbaum MJ van Dijk JH Videbaek F Vient M Vincent P 《Physical review D: Particles and fields》1992,45(11):3906-3920
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J. H. Caltenco R. Linares y M. J. L. López-Bonilla 《Czechoslovak Journal of Physics》2002,52(7):839-842
We show that the trajectory of a point charge in a uniform electromagnetic field is a helix if the Lorentz equation governs
its motion. Our approach is totally relativistic, and it is based on the use of the Frenet-Serret formulae which describe
the intrinsic geometry of world lines in Minkowski spacetime. 相似文献
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FO Ayorinde BE Eribo JH Johnson E Elhilo 《Rapid communications in mass spectrometry : RCM》1999,13(12):1124-1128
Nonylphenol ethoxylates (NPEs) belong to a group of nonionic surfactants that are collectively referred to as alkylphenol ethoxylates (APEs). APEs find widespread use in heavy-duty commercial and household cleaning formulations, shampoos, and industrial processing, i.e. textile manufacture. Their environmental impact depends on the molecular distribution and the extent of their biodegradation in municipal sewage systems, waterways and rivers. We have established two sample preparation methods that have enabled the determination of the molecular distributions of six commercial nonylphenol ethoxylates using matrix-assisted laser desorption/ionization (MALDI) time-of-flight (TOF) mass spectrometry (MS). In both methods, alpha-cyano-4-hydroxycinnamic acid, dissolved in acetonitrile/tetrahydrofuran, was used as the matrix. In one set of experiments, the NPEs were dissolved in an acetonitrile/tetrahydrofuran solvent system prior to mixing with the matrix solution, and the resulting MALDI-TOF mass spectra produced mostly sodiated molecules [M + Na](+). The NPEs, all having the formula 4-(C(9)H(19))-C(6)H(4)-(OCH(2)CH(2))(n)-OH, are Surfonic (R)N-95, N-100, N-102, N-120, N-150 and N-300. Surfonic N-95 and N-100 gave n values of 5-20; Surfonic N-102, N-120, N-150, and N-300 gave n values of 5-21, 5-22, 8-25 and 15-40, respectively. In order to develop a sample preparation method that could be used with less polar NPEs, we dissolved the NPEs (except N-300) in pentane prior to mixing with the matrix solution, and found that the MALDI spectral quality was unaffected by the solvent systems. Copyright 1999 John Wiley & Sons, Ltd. 相似文献