Direct Arylation in the Presence of Palladium Pincer Complexes

Direct arylation is an atom-economical alternative to more established procedures such as Stille, Suzuki or Negishi arylation reactions. In comparison with other palladium sources and ligands, the use of palladium pincer complexes as catalysts or pre-catalysts for direct arylation has resulted in improved efficiency, higher reaction yields, and advantageous reaction conditions. In addition to a revision of the literature concerning intra- and intermolecular direct arylation reactions performed in the presence of palladium pincer complexes, the role of these remarkably active catalysts will also be discussed.     

Operator inequalities related to the Corach–Porta–Recht inequality

We prove some refinements of an inequality due to X. Zhan in an arbitrary complex Hilbert space by using some results on the Heinz inequality. We present several related inequalities as well as new variants of the Corach–Porta–Recht inequality. We also characterize the class of operators satisfying $6{\mathit{SXS}}^{-1}+S^{-1}\mathit{XS}+\mathit{kX}6?(k+2)6X6$ under certain conditions.     

Analysis of the formation and evolution of oriented microstructures on laser ablated silicon

A theoretical approach and qualitative analysis of the changes induced on the surface morphology and the formation of microstructures on silicon targets irradiated by excimer laser are presented. This study is based on theoretical principles of the laser ablation process, in particular, on the analysis of the contribution of the laser energy density, which involves the laser beam parameters and also the physical properties of the target material. For different laser incident angles, the formation of micro-columns oriented towards the laser incident direction is explained. Moreover, numerical simulations and ablation experiments carried out with an excimer laser corroborate the theoretical analysis.     

Thermolysis of titanocene methyl compounds bearing t-butyl- and benzyltetramethylcyclopentadienyl ligands

Elimination of methane during thermolysis of title compounds results in the formation of σ-Ti-C bond to t-butyl or benzyl group. The t-butyl-containing titanocene methyl compound [Ti(III)Me(η⁵-C₅Me₄t-Bu)₂] (5) eliminates methane at 110 °C to give cleanly [Ti(III)(η⁵:η¹-C₅Me₄CMe₂CH₂)(η⁵-C₅Me₄t-Bu)] (6). The methyl derivative of analogous benzyl-containing titanocene [Ti(III)Me(η⁵-C₅Me₄CH₂Ph)₂] was not isolated because it eliminated methane at ambient temperature to give [Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)(η⁵-C₅Me₄CH₂Ph)] (7) with one phenyl ring linked to titanium atom in ortho-position. The corresponding titanocene dimethyl compound [TiMe₂{η⁵-C₅Me₄t-Bu)}₂] (9) eliminates two methane molecules at 110 °C to give the singly tucked-in 1,1-dimethylethane-1,2-diyl-tethered titanocene [Ti{η⁵:η¹:η¹-C₅Me₃(CH₂)(CMe₂CH₂)}(η⁵-C₅Me₄t-Bu)] (11). In distinction, the analogous benzyl derivative [TiMe₂(η⁵-C₅Me₄CH₂Ph)₂] (10) eliminates at 110 °C only one methane molecule to afford [TiMe(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)(η⁵-C₅Me₄CH₂Ph)] (12) containing one phenyl group attached to titanium in o-position and one methyl group persisting on the titanium atom. This compound is stable at 150 °C for at least 3 h. The crystal structures of 5, 6, 7, and 10 were determined.     

Preferential Co partitioning to α-Fe in nanocrystalline CoFeNbB alloys by Mn addition

Influence of Mn addition on the microstructure and hyperfine parameters of amorphous and nanocrystalline Co₆₀(FeMn)₁₈Nb₆B₁₆ alloys has been studied. Although Mn addition does not yield significant differences in crystallization kinetics and in the phases formed after each transformation, it seriously affects the partitioning of Co during nanocrystallization. Whereas for Mn free alloy Co is homogeneously distributed throughout the amorphous matrix and the nanocrystals, in Mn containing alloy Co is enriched in the α-FeCo nanocrystals. This fact prevents the exhaustion in Fe of the amorphous matrix and the crystalline volume fraction achieved at the end of nanocrystallization in the case of Mn containing alloy is ∼20% higher than in the Mn free alloy.     

Dehalogenation of α -haloketones and vic-dibromides with nickel boride

α-Haloketones and $\text{vic}$-dibromides are converted to the corresponding ketones and alkenes respectively with nickel boride generated $\text{in situ}$ from sodium borohydride and nickel chloride.     

Planar point-objective location problems with nonconvex constraints: A geometrical construction

The planar point-objective location problem has attracted considerable interest among Location Theory researchers. The result has been a number of papers giving properties or algorithms for particular instances of the problem. However, most of these results are only valid when the feasible region where the facility is to be located is the whole space ², which is a rather inaccurate approximation in many real world location problems.In this paper, the feasible region is allowed to be any closed, not necessarily convex, setS in ². The special structure of this nonconvex vector-optimization problem is exploited, leading to a geometrical resolution procedure when the feasible regionS can be decomposed into a finite number of (not necessarily disjoint) polyhedra.     

Protective Properties of a Sol-Gel Coating on Zinc Coated Steel

Galvanised and galvannealed steels are widely used due to their good corrosion resistance in aqueous solutions. However, when additional protection is required, organic coatings, corrosion inhibitors or conversion coatings are used to improve their corrosion protection. In this work, sol-gel coating was used to improve the corrosion behaviour of these two materials. This paper analyses the final protective properties of a sol-gel coating prepared by basic catalysis and its dependence on the sintering temperature and time of treatment. The influence of the sintering conditions on the galvanised and galvannealed substrates is a decisive factor for the coating quality and for the barrier affect against the aggressive media. While heat treatment time is the controlling factor for the galvannealed steels, the temperature is determining in the case of the galvanised. Corrosion mechanisms for sol-gel galvanised steels did not changed with respect to the uncoated steel. However for galvannealed steel, after coating the mechanism is not purely cathodic.