全文获取类型
收费全文 | 234篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 162篇 |
力学 | 5篇 |
数学 | 21篇 |
物理学 | 55篇 |
出版年
2019年 | 1篇 |
2018年 | 3篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 13篇 |
2012年 | 9篇 |
2011年 | 13篇 |
2010年 | 10篇 |
2009年 | 3篇 |
2008年 | 14篇 |
2007年 | 4篇 |
2006年 | 6篇 |
2005年 | 15篇 |
2004年 | 3篇 |
2003年 | 6篇 |
2002年 | 9篇 |
2001年 | 5篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 3篇 |
1997年 | 6篇 |
1996年 | 16篇 |
1995年 | 4篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 10篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1959年 | 1篇 |
1958年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有243条查询结果,搜索用时 234 毫秒
41.
42.
Norman Blackburn 《Monatshefte für Mathematik》1985,99(1):1-18
The lower central series and the power structure of the groups with the property in the title are calculated. 相似文献
43.
3-pyrrol-2-ones, 4, and 2-butynamides, 5, are formed by reaction of N,N-dialkylated pyruvamides, 2, with diethyl (diazomethyl)phosphonate (1). The selectivity of the C-H insertion reaction to give 4 and the basis for it are discussed. 相似文献
44.
45.
F. R. Blackburn Marcus T. Cicerone M. D. Ediger 《Journal of Polymer Science.Polymer Physics》1994,32(16):2595-2604
Time-resolved optical spectroscopy is used to investigate the reorientation of three rigid probes and one labeled chain in bulk polystyrene. Orientational correlation times for these probes and labels are found to be in the range of 10?8–10?10 s at temperatures of 180–300°C. Consistent with previous studies, the attachment of a chromophore into the chain backbone slows its dynamics by about an order of magnitude. The temperature dependences of the correlation times are similar to the temperature dependence of the viscosity. When combined with probe reorientation times near and below Tg, these results indicate that probe reorientation tracks the temperature dependence of the viscosity quite well over twelve decades in time. In contrast, literature results for the translational diffusion of similarly sized probes indicates a substantially weaker temperature dependence near Tg. Thus it appears that a fundamental change in the mechanism of probe motion occurs near Tg. © 1994 John Wiley & Sons, Inc. 相似文献
46.
47.
H. M. Blackburn 《Experiments in fluids》1994,18(1-2):134-136
A short series of experiments was conducted with the aim of assessing the possible effect of tunnel blockage on spanwise correlation lengths measured in the near-wake of a circular cylinder. The results indicate that increasing blockage acts to increase spanwise correlation. This finding has important implications for the conduct and reporting of both physical and numerical experiments on bluff-body wake flows. 相似文献
48.
Z.M. Babar Wan Mohd Azizi Solachuddin JA Ichwan Qamar Uddin Ahmed Abul Kalam Azad Imranul Mawa 《Natural product research》2019,33(15):2266-2270
The current study provides a way of extraction for both active NSO and WSE from Nigella sativa seeds using 98% methanol. About 1?kg of ground seeds was macerated by 1:2.5 w/v (g/mL) for 72?hours. After rotary evaporation and 7 days of continuous drying and chilling at 50 and 4?°C, NSO and WSE were obtained at the same instant. Solubility tests of 24 solvents and 11 thin layer chromatographic analyses while 2, 2-diphenyl-1-picrylhydrazyl free radical scavenging assay of NSO (73.66) , WSE (33.32) and NSO?+?WSE (78.22) against ascorbic acid (IC50?=?4.28?mg/mL) was performed. WSE was found to be highly soluble in water and 5% NaOH exhibiting the same Rf value of 0.95 for EtOH:DMSO (9:1) against the honey. WSE has revealed more than twofold higher anti-oxidant activity than others. Formulation of WSE with Tualang honey may provide better targeted hydrophilic drug delivery systems. 相似文献
49.
50.
Paul C. DeRose Melody V. Smith Klaus D. Mielenz Douglas H. Blackburn Gary W. Kramer 《Journal of luminescence》2008,128(2):257-266
Standard Reference Material® (SRM®) 2941 is a cuvette-shaped, uranyl-ion-doped glass, recommended for use for relative spectral correction of emission and day-to-day performance validation of fluorescence spectrometers. Properties of this standard that influence its effective use or contribute to the uncertainty in its certified emission spectrum have been explored here. These properties include its photostability, absorbance, dissolution rate in water, anisotropy, temperature coefficient of fluorescence intensity, and fluorescence lifetimes. The expanded uncertainties in the certified spectrum are about 4% around the peak maximum at 526 nm, using an excitation wavelength of 427 nm. The SRM also exhibits a strong resistance to photodegradation, with no measurable decrease in fluorescence intensity even after 8 h of laser irradiation. 相似文献