Real-space renormalization group for two-dimensional quantum spin systems

A generalization of the Niemeijer and Van Leeuwen real-space renormalization group method for quantum lattice spin systems is presented. A proposed rotationally invariant transformation which preserves the symmetry of the spin space is applied to several quantum systems on a triangular lattice. For the spin-1/2XY-model in both first- and second-order cumulant expansions a nontrivial fixed point exists, giving in the best approximation a critical interactionK _XY ^c =0.453 and critical exponent =1.65. A method of the reduction of the generalized arbitrary spin anisotropic Heisenberg model to the spin-half model is presented.     

Influence of a continuous quenching procedure on the initial stages of spinodal decomposition

Instead of the standard assumption in the theory of phase separation where an instantaneous quench from an initial equilibrium state to the final state in the two-phase region is assumed, we consider the more realistic situation that the change of the external control parameter (e.g. temperature) can only be performed with finite rates. During the initial stages of spinodal decomposition the system then has some memory of the states intermediate between the initial and the final one. This influence of the finite quench rate in continuous quenching procedures is studied within the linearized theory of spinodal decomposition, with the Langer-Baron-Miller decoupling, and with Monte Carlo simulations. Both the case of thermally activated mobilities (applicable to solid metallic alloys) and the case of nearly temperature-independent mobilities (applicable to fluid polymer mixtures) are treated, and possible experimental applications are discussed. We find drastic deviations from the standard instantaneous quench situations in all cases of experimental interest.     

Low temperature anharmonicity in Sn(CH3)4 due to methyl group reorientation: A Mössbauer study

The detailed temperature variation of the Mössbauer spectral intensity in Sn(CH₃)₄ displays a pronounced drop of the Debye temperature from _D 96K below the transition temperature (T _t 43K) to _D 76K above it. The transition atT _t is discussed in terms of recent INS and NMR results where increased motion of inequivalent CH₃ groups has been observed around the temperatureT _t .Supported by the U.S.-Israel Binational Science Foundation     

A new concept for sequencing DNA by capillary electrophoresis.

It is proposed that the scaling symmetry of constant charge density with increasing molecular weight, which prevents the separation by electrophoresis of DNA molecules in solution (with respect to molecular weight) be broken by the attachment of a perturbing entity (protein, virus or charged sphere) to one end of the molecule. An application of this idea to a concept for sequencing DNA by capillary electrophoresis is discussed, and the possibility of using the reattachment of the RecA protein to separate large segments of DNA in solution by electrophoresis following sequence-specific cleavage is mentioned.     

2.6 Foods

Abstracts2 Particular products and fields of application

2.6 Foods     

Umsetzung von hydrobromiertem 1,4-Polybutadien mit lithiumorganischen Verbindungen

Ohne ZusammenfassungMit 1 Abbildung und 1 Tabelle     

THE PHOTOSENSITIZED OXIDATION OF SULPHIDES

Abstract— The rates of photosensitized oxidation of a number of sulphides were determined under standard conditions in 1, 1, 2,2-tetrachloroethane and in methanol. It was found that the ratio of the rates of reaction in the two solvents was not constant for different sulphides and that t -butyl sulphide does not react in methanol. It is inferred that the presence of an H atom in the α position is essential for reaction in polar solvents and an appropriate mechanism is suggested. The results indicate that reaction in chlorinated solvents may take place by a different mechanism which possibly involves H-abstraction by triplet sensitizer.     

Effect of solidified salts on1 3 7Cs leaching from bituminized products

The leaching rate of^{1 3 7}Cs from bituminized products was studied by leach tests conducted for two years.