A Two-Dimensional Operator-Difference Scheme for Fluid Dynamics in Lagrangean Coordinates on an Irregular Triangular Grid with the Property of Local Approximation near the Symmetry Axis

The projection approach is applied to construct and investigate an operator-difference scheme for fluid dynamics in Lagrangean variables which has first-order local approximation in the axisymmetric case near the symmetry axis. The scheme also has operator properties that make it suitable for rederiving and substantiating previous results, methods, and algorithms.     

Weak density of smooth maps for the Dirichlet energy between manifolds

We prove that given a simply connected compact manifold M and a closed manifold N, any map in the Sobolev space W ^1,2(M,N) can be approximated weakly by smooth maps between M and N. Submitted: September 2002, Final version: November 2002.     

Martensite Transformation in Nanoparticles and Nanomaterials

Journal of Nanoparticle Research - It was shown that the thermoelastic martensite transformation B2 ? B19 inside nanoparticles surrounded by amorphous matrix in Ni–Ti–Cu alloys as...     

An Integral Formula for the Complex Intersection Number of Real Cycles in a Real Algebraic Variety with Topologically Rational Singularities

A formula of type indicated in the title is presented and discussed. Bibliography: 7 titles.     

Viscoelastic properties of nanostructured natural rubber/polystyrene interpenetrating polymer networks

The effects of the blend ratio and initiating system on the viscoelastic properties of nanostructured natural rubber/polystyrene‐based interpenetrating polymer networks (IPNs) were investigated in the temperature range of ?80 to 150 °C. The studies were carried out at different frequencies (100, 50, 10, 1, and 0.1 Hz), and their effects on the damping and storage and loss moduli were analyzed. In all cases, tan δ and the storage and loss moduli showed two distinct transitions corresponding to natural rubber and polystyrene phases, which indicated that the system was not miscible on the molecular level. However, a slight inward shift was observed in the IPNs, with respect to the glass‐transition temperatures (T_g's) of the virgin polymers, showing a certain degree of miscibility or intermixing between the two phases. When the frequency increased from 0.1 to 100 Hz, the T_g values showed a positive shift in all cases. In a comparison of the three initiating systems (dicumyl peroxide, benzoyl peroxide, and azobisisobutyronitrile), the dicumyl peroxide system showed the highest modulus. The morphology of the IPNs was analyzed with transmission electron microscopy. The micrographs indicated that the system was nanostructured. An attempt was made to relate the viscoelastic behavior to the morphology of the IPNs. Various models, such as the series, parallel, Halpin–Tsai, Kerner, Coran, Takayanagi, and Davies models, were used to model the viscoelastic data. The area under the linear loss modulus curve was larger than that obtained by group contribution analysis; this showed that the damping was influenced by the phase morphology, dual‐phase continuity, and crosslinking of the phases. Finally, the homogeneity of the system was further evaluated with Cole–Cole analysis. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1680–1696, 2003     

Epoxy based coatings on glass: strengthening mechanisms

Glass may be strengthened by epoxy coatings although the strengthening mechanisms remain unclear. Possible strengthening mechanisms are reviewed and are used to analyse strength data for both a solvent based and a water based coating system. The coatings either fill (solvent based coatings), or partially fill (water based coatings) surface cracks and it is shown that closure stresses arising from the thermal expansion mismatch of the coating within these cracks can account for the observed degrees of strengthening. It is also demonstrated that other suggested mechanisms such as flaw healing cannot fully account for the observed degree of strengthening.     

Inner bounds for the spectrum of quasinormal operators

A linear operator in a separable Hilbert space is called a quasinormal one if it is a sum of a normal operator and a compact one. In the paper, bounds for the spectrum of quasinormal operators are established. In addition, the lower estimate for the spectral radius is derived. Under some restrictions, that estimate improves the well-known results. Applications to integral operators and matrices are discussed. Our results are new even in the finite-dimensional case.

     

Recyclization of 2,3-Disubstituted 5-Arylamino-2,5-dihydro-1,2,4-thiadiazoles and Related Salts into Benzothiazole Derivatives

Russian Journal of General Chemistry -     

Chern numbers for two families of noncommutative Hopf fibrations

We consider noncommutative line bundles associated with the Hopf fibrations of SU_q(2) over all Podle? spheres and with a locally trivial Hopf fibration of S³_pq. These bundles are given as finitely generated projective modules associated via 1-dimensional representations of U(1) with Galois-type extensions encoding the principal fibrations of SU_q(2) and S³_pq. We show that the Chern numbers of these modules coincide with the winding numbers of representations defining them. To cite this article: P.M. Hajac et al., C. R. Acad. Sci. Paris, Ser. I 336 (2003).     

Effect of maltodextrins on the surface activity of small-molecule surfactants

We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na⁺), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed.