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991.
The nanocrystal samples of titanium dioxide doped with europium ion (Eu3+/TiO2 nanocrystal) are synthesized by the sol-gel method with hydrothermal treatment. The Eu3+ contents (molar ratio) in the samples are 0, 0.5%, 1%, 2%, 3% and 4%. The X-ray diffraction, UV-Vis spectroscopy data and scanning electron microscope image show that crystallite size is reduced by the doping of Eu3+ into TiO2. Comparing the Raman spectra of TiO2 with Eu3+/TiO2 (molar ratio Eu3+/TiO2=1%, 2% and 4%) nanocrystals at different annealing temperatures indicates that the anatase-to-rutile phase transformation temperatures of Eu3+/TiO2 nanocrystals are higher than that of TiO2. This is due to the formation of Eu-O-Ti bonds on the surface of the TiO2 crystallite, as characterized by the X-ray photoelectron spectroscopy. The photoluminescence spectra of TiO2 in Eu3+/TiO2 nanocrystals are interpreted by the surface self-trapped and defect-trapped exciton relaxation. The photoluminescence of Eu3+ in Eu3+/TiO2 nanocrystals has the strongest emission intensity at 2% of Eu3+ concentration. 相似文献
992.
Y. Qu J.X. Zhang A. Uddin C.Y. Liu S. Yuan M.C.Y. Chan B. Bo G. Liu H. Jiang 《Applied Physics A: Materials Science & Processing》2006,82(2):305-308
Ridge-waveguide InGaAsN triple-quantum-well strain-compensated lasers grown by metal organic chemical vapor deposition were fabricated with pulsed anodic oxidation. The laser’s output power reached 145 mW in continuous-wave mode at room temperature for a 4-?m -stripe-width laser. Continuous-wave single longitudinal mode operation was maintained at a high injection current level with a wavelength of 1287.3 nm at room temperature. Single longitudinal mode operation at 1317.2 nm was achieved at twice the threshold current at 100 °C. The band gap of InGaAsN in the quantum wells at different temperatures was calculated and compared to the measured temperature-dependent laser wavelength. 相似文献
993.
Direct measurement of fluid velocity gradients at a wall by PIV image processing with stereo reconstruction 总被引:1,自引:0,他引:1
Velocity gradient is typically estimated in Particle Image Velocimetry (PIV) by differentiating a measured velocity field,
which amplifies noise in the measured velocities. If gradients near a boundary are sought, such noise is usually greater than
in bulk fluid, because of small tracer displacement, uncertainty in the effective positions of velocity vectors, intense deformation
of tracer patterns, and laser reflection. We consider here a modified form of the Particle Image Distortion (PID) method todirectly calculate velocity gradients at a fixed wall, and refer it as “PIV/IG” (“Interface Gradiometry”). Results from synthetic
2D PIV images suggest our method achieves higher SNR and accuracy than velocity differentiation. Also, we have developed a
procedure to reconstruct three-dimensional velocity gradient at a fixed wall the two non-zero components from PIV/IG data
obtained in stereo views; these equations simplify considerably thanks to the no-slip condition. Experimental data from the
bottom wall of turbulent open channel flow appear to suffer from a form of pixel locking. As with standard PIV, this underlines
the importance of adequate tracer diameter in the images, sufficient seeding density, and of dynamic range of the camera sensor. 相似文献
994.
The effect of gradients in hardness, structure and composition in the surface layers on magnetic Barkhausen noise (MBN) was investigated in two widely used low alloy steels. One material was case hardened by induction hardening. The other was case carburised. Similar hardness profiles were produced by the two treatments. It was found that the variation in structure and hardness through the case in the induction-hardened steel had a minor effect on the MBN profile. In contrast, the inhomogeneity in the case-carburised material showed up clearly. This took the form of a broadened or two-peak MBN profile. When the surface layer containing the case was removed by etching, the broadened profile was replaced by a profile with a single peak. It is concluded that the shape and position of the MBN profile is significantly affected when a gradient in microstructure is induced by a gradient in carbon content. On the other hand, a gradient in microstructure induced by heat treatment with a constant carbon level has much less affect on the MBN profile for the induction-hardened steel. 相似文献
995.
996.
E. Mathieu Y. Foucher P. Dellamonica J. P. Daures 《Methodology and Computing in Applied Probability》2007,9(3):389-397
In AIDS control, physicians have a growing need to use pragmatically useful and interpretable tools in their daily medical
taking care of patients. Semi-Markov process seems to be well adapted to model the evolution of HIV-1 infected patients. In
this study, we introduce and define a non homogeneous semi-Markov (NHSM) model in continuous time. Then the problem of finding
the equations that describe the biological evolution of patient is studied and the interval transition probabilities are computed.
A parametric approach is used and the maximum likelihood estimators of the process are given. A Monte Carlo algorithm is presented
for realizing non homogeneous semi-Markov trajectories. As results, interval transition probabilities are computed for distinct
times and follow-up has an impact on the evolution of patients.
相似文献
997.
T. Hansel J. Müller C. Falldorf C. von Kopylow W. Jüptner R. Grunwald G. Steinmeyer U. Griebner 《Applied physics. B, Lasers and optics》2007,89(4):513-516
Digital holographic shape measurements using femtosecond laser pulses are reported. For contouring of very fast moving objects,
the simultaneous generation of at least two spectrally separated ultrashort pulses is required. To deliver this particular
spectral signature at high pulse energies, a chirped-pulse Ti:sapphire laser amplifier was modified to emit two spectrally
separated pulses with energies above 1 μJ each. The wavelength separation of these pulses was adjustable within the 50 nm
gain bandwidth, cutting out two distinct wavelength peaks by a variable double-slit assembly in a prism sequence. A Michelson-type
interferometer was employed to perform the two-wavelength contouring. The phases of the holograms and the phase differences
are calculated numerically, which allow us to deduce the contour lines of the topology of the object. The suitability of the
light source for digital holography is demonstrated with contouring of stationary objects and the potential for high-speed
applications is indicated.
PACS 42.40.-i; 42.60.By 相似文献
998.
A. M. Kharitonov 《Thermophysics and Aeromechanics》2007,14(1):3-11
Sergey Alekseevich Khristianovich is one of the famous Russian mechanical engineers of the 20th century together with N.E.
Zhukovsky, S.A. Chaplygin, N.E. Kochin, and others. He made an immense contribution to some aspects of mechanics, such as
aerogasdynamics, rock mechanics, theory of plasticity, filtration theory, and environmental power engineering. All this was
preceded by a long, hard, and fruitful life full of outstanding events. 相似文献
999.
1000.
In this study a novel technique for 2D spray temperature measurement is presented. For this purpose the thermographic phosphor (TP) Mg4GeO5.5F:Mn was dispersed in n-dodecane and atomised using a conventional semi solid-cone nozzle. The thermographic phosphor was excited electronically by a frequency tripled Nd:YAG laser (355 nm). An ICCD-camera in combination with an image doubler detected the subsequently emitted phosphorescence at both peak emission wavelengths located at 633 nm and 659 nm, respectively. Utilising suitable calibration measurements, the local spray temperature was determined by evaluating the intensity ratio of both emission wavelengths. To the knowledge of the authors this is the first approach of spray temperature measurement exploiting the temperature dependent intensity ratio of thermographic phosphors. PACS 07.20.Dt; 32.50.+d 相似文献