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941.
The temperature dependence of the NMR chemical shift of129Xe dissolved in liquid alkanes is examined in the context of the reaction field model. An essential feature of the theory is the inclusion of the temperature dependence of the density of thesolvent. The theory of free volume for liquids is incorporated into the reaction field model to account for this temperature dependence. Comparison of the theory with previously reported measurements indicates the sensitivity of the129Xe chemical shift to the free volume of liquids. Incorporation of free volume improves the agreement between measurement and theory for branched alkane solvents, and resolves the origin of the 62 ppm intercept in the plot of reaction field as a function of129Xe chemical shift for the n-alkanes. 相似文献
942.
943.
P. G. Baranov N. G. Romanov A. Hofstaetter A. Scharmann C. Schnorr F. J. Ahlers K. Pierz 《JETP Letters》1996,64(10):754-759
Two types of excitons, localized at opposite interfaces and characterized by different magnitudes of the exchange interactions
at the same radiation energies, are simultaneously in type-II GaAs/AlAs superlattices. It is shown that the additional long-wavelength
luminescence line in superlattices grown with growth interruptions after the GaAs layers is due to the recombination of an
exciton localized at an inverted interface in regions where the quantum-well width is increased by one monolayer.
Pis’ma Zh. éksp. Teor. Fiz. 64, No. 10, 701–706 (25 November 1996) 相似文献
944.
945.
946.
The behaviour of La-containing strontium zirconate based ceramics is revised. La additions contribute to improve the sinterability
of these materials, but transport properties are also affected. Sr1−xLaxZrO3+δ show some unusual changes in transport properties when samples are exposed to H2-containing atmospheres and then reoxidized. Nevertheless, the transport properties of (Sr,La)(Zr,Y)O3−δ, are still mainly dependent on Y additions, at least for cases when the fraction of Y exceeds the fraction of La. In addition,
lanthanum causes significant changes in lattice parameters. A combination of conductivity measurements in different atmospheres,
ion blocking experiments, and emf measurements has been used to demonstrate that electron hole conductivity increases with
temperature, and the protonic contribution drops. The transport properties at temperatures lower than about 800 °C might be
affected by structural changes.
Paper presented at the 2nd Euroconference on Solid State Ionics, Funchal, Madeira, Portugal, Sept. 10–16, 1995 相似文献
947.
948.
949.
A. Sachdev R. I. Masel J. B. Adams 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,26(1):310-312
The embedded atom method (EAM) was used to determine the equilibrium shapes of small platinum and palladium clusters (N=5–60 atoms). The stability of various polyhedral symmetries was performed at 0K. A search for the presence of any other lower energy structures was also carried out. Pt clusters reconstructed to lower energy clusters even at the magic numbers. Pd also reconstructed to lower energy structures except at the magic number sizes where the icosahedron was found to be the most stable. 相似文献
950.