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21.
S.V. Dordevic D.N. Basov R.C. Dynes B. Ruzicka V. Vescoli L. Degiorgi H. Berger R. Gaál L. Forró E. Bucher 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,33(1):15-23
We present a comprehensive analysis of the optical constants of the two-dimensional dichalcogenide materials 2
H
-
TaSe
2
and 2
H
-
NbSe
2
, in an attempt to address the physics of two-dimensional correlated systems. The title compounds were studied over several
decades in frequency, from the far-infrared to the ultraviolet. Measurements with linearly polarized light have allowed us
to obtain both the in-plane and out-of-plane components of the conductivity tensor. Although the electromagnetic response
of dichalcogenides is strongly anisotropic, both the in-plane and out-of-plane components of the conductivity tensor share
many common features, including the presence of a well-defined metallic component, as well as a “mid-infrared band”. We discuss
the implications of these results in the context of the spectroscopic results of other classes of low-dimensional conductors
such as the high-temperature superconducting cuprates. In particular, the analysis of the redistribution of the spectral weight
as a function of temperature, as well as the behavior of the quasiparticles relaxation rate, points to significant distinctions
between the charge dynamics of dichalcogenides and other classes of low dimensional conductors.
Received 28 October 2002 / Received in final form 10 March 2003 Published online 23 May 2003
RID="a"
ID="a"e-mail: degiorgi@solid.phys.ethz.ch 相似文献
22.
Albrecht M Maret M Kohler J Gilles B Poinsot R Hazemann JL Tonnerre JM Teodorescu C Bucher E 《Physical review letters》2000,85(25):5344-5347
We report the first observation of a weak ferromagnetic state of Cr in Cr/Ru(0001) superlattices, based on magnetic hysteresis and corroborated by x-ray magnetic circular dichroism at the CrL(2,3) edges. In situ reflection high-energy electron diffraction, x-ray diffraction, and Cr K-edge polarized x-ray absorption investigations have shown that the Cr layers thinner than 8 angstroms adopt a slightly distorted hcp structure, accompanied by a large atomic volume expansion of up to 14% compared to the bcc packing volume. The expanded hcp structure clearly induces the observed ferromagnetism, in agreement with theory. 相似文献
23.
Inside Cover: Synthesis and Characterization of Carbazole‐Linked Porphyrin Tweezers (Chem. Eur. J. 34/2015) 下载免费PDF全文
24.
An importance sampling technique for linear and non-linear dynamical systems subjected to random excitations is presented. Applying a transformation of probability measures, controls are introduced in the system of Itô stochastic differential equations such that the sample trajectories can be influenced in a predetermined way. As is shown, there exist controls resulting in unbiased zero-variance estimators. However, these optimal controls are in general not accessible and have to be replaced by sub-optimal ones derived from an optimization procedure analogous to the first order reliability method known from time-invariant problems. The efficiency of the proposed Monte Carlo simulation technique is demonstrated by estimating first-passage probabilities of typical oscillators under external white-noise excitation. 相似文献
25.
26.
Adare A Afanasiev S Aidala C Ajitanand NN Akiba Y Al-Bataineh H Alexander J Al-Jamel A Aoki K Aphecetche L Armendariz R Aronson SH Asai J Atomssa ET Averbeck R Awes TC Azmoun B Babintsev V Baksay G Baksay L Baldisseri A Barish KN Barnes PD Bassalleck B Bathe S Batsouli S Baublis V Bauer F Bazilevsky A Belikov S Bennett R Berdnikov Y Bickley AA Bjorndal MT Boissevain JG Borel H Boyle K Brooks ML Brown DS Bucher D Buesching H Bumazhnov V Bunce G Burward-Hoy JM Butsyk S Campbell S Chai JS Chang BS 《Physical review letters》2007,98(16):162301
Differential measurements of elliptic flow (v2) for Au+Au and Cu+Cu collisions at sqrt[sNN]=200 GeV are used to test and validate predictions from perfect fluid hydrodynamics for scaling of v2 with eccentricity, system size, and transverse kinetic energy (KE T). For KE T identical with mT-m up to approximately 1 GeV the scaling is compatible with hydrodynamic expansion of a thermalized fluid. For large values of KE T mesons and baryons scale separately. Quark number scaling reveals a universal scaling of v2 for both mesons and baryons over the full KE T range for Au+Au. For Au+Au and Cu+Cu the scaling is more pronounced in terms of KE T, rather than transverse momentum. 相似文献
27.
Dr. Soukaina Bennaamane Barbara Rialland Lhoussain Khrouz Dr. Marie Fustier-Boutignon Dr. Christophe Bucher Dr. Eric Clot Dr. Nicolas Mézailles 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(3):e202209102
Ammonia, NH3, is an essential molecule, being part of fertilizers. It is currently synthesized via the Haber–Bosch process, from the very stable dinitrogen molecule, N2 and dihydrogen, H2. This process requires high temperatures and pressures, thereby generating ca 1.6 % of the global CO2 emissions. Alternative strategies are needed to realize the functionalization of N2 to NH3 under mild conditions. Here, we show that boron-centered radicals provide a means of activating N2 at room temperature and atmospheric pressure whilst allowing a radical process to occur, leading to the production of borylamines. Subsequent hydrolysis released NH4+, the acidic form of NH3. EPR spectroscopy supported the intermediacy of radicals in the process, corroborated by DFT calculations, which rationalized the mechanism of the N2 functionalization by R2B radicals. 相似文献
28.
Afanasiev S Aidala C Ajitanand NN Akiba Y Alexander J Al-Jamel A Aoki K Aphecetche L Armendariz R Aronson SH Averbeck R Awes TC Azmoun B Babintsev V Baldisseri A Barish KN Barnes PD Bassalleck B Bathe S Batsouli S Baublis V Bauer F Bazilevsky A Belikov S Bennett R Berdnikov Y Bjorndal MT Boissevain JG Borel H Boyle K Brooks ML Brown DS Bucher D Buesching H Bumazhnov V Bunce G Burward-Hoy JM Butsyk S Campbell S Chai JS Chernichenko S Chiba J Chi CY Chiu M Choi IJ Chujo T Chung P Cianciolo V 《Physical review letters》2008,100(23):232301
A three-dimensional correlation function obtained from midrapidity, low p(T), pion pairs in central Au+Au collisions at sqrt[s(NN)]=200 GeV is studied. The extracted model-independent source function indicates a long range tail in the directions of the pion pair transverse momentum (out) and the beam (long). A proper breakup time tau(0) ~ 9 fm/c and a mean proper emission duration Delta tau ~ 2 fm/c, leading to sizable emission time differences ({|Delta t(LCM)|} approximately 12 fm/c), are required to allow models to be successfully matched to these tails. The model comparisons also suggest an outside-in "burning" of the emission source reminiscent of many hydrodynamical models. 相似文献
29.
Adare A Afanasiev S Aidala C Ajitanand NN Akiba Y Al-Bataineh H Alexander J Al-Jamel A Aoki K Aphecetche L Armendariz R Aronson SH Asai J Atomssa ET Averbeck R Awes TC Azmoun B Babintsev V Baksay G Baksay L Baldisseri A Barish KN Barnes PD Bassalleck B Bathe S Batsouli S Baublis V Bauer F Bazilevsky A Belikov S Bennett R Berdnikov Y Bickley AA Bjorndal MT Boissevain JG Borel H Boyle K Brooks ML Brown DS Bucher D Buesching H Bumazhnov V Bunce G Burward-Hoy JM Butsyk S Campbell S Chai JS Chang BS 《Physical review letters》2007,98(23):232301
The PHENIX experiment at the BNL Relativistic Heavy Ion Collider (RHIC) has measured J/psi production for rapidities -2.2相似文献
30.