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111.
Increased structural complexity leads to higher activity: peptides as efficient and versatile catalysts for asymmetric aldol reactions 总被引:3,自引:0,他引:3
[reaction: see text] Peptides containing a secondary amine and a carboxylic acid in a specific orientation to each other are presented as highly efficient catalysts for asymmetric aldol reactions: (1) their activity is considerably higher compared to that of proline, and (2) the enantioselectivity of the peptidic catalysts can be changed from (R)- to (S)-selectivity by simple modifications of the secondary structure. 相似文献
112.
Cesare Oliva Anatoli V. Vishniakov Ivan E. Mukovozov Giorgio Termignone Lucio Forni 《Radiation Physics and Chemistry》1995,45(6):945-948
Evidence of quantum spin fluid and of quantum spin glass behaviour has been detected by extended EPR analysis in some La-cuprate catalysts of general formula La2−xEuxCuO4 + δ. Some features of the EPR spectrum, appearing in a few cases, are also discussed and attributed to a pseudo Jahn-Teller effect due to a particular coordination of up to five oxygen ions around surface copper ions at low temperature. 相似文献
113.
Theendomorphism spectrum of an ordered setP, spec(P)={|f(P)|:f End(P)} andspectrum number, sp(P)=max(spec(P)\{|P|}) are introduced. It is shown that |P|>(1/2)n(n – 1)
n – 1 implies spec(P) = {1, 2, ...,n} and that if a projective plane of ordern exists, then there is an ordered setP of size 2n
2+2n+2 with spec(P)={1, 2, ..., 2n+2, 2n+4}. Lettingh(n)=max{|P|: sp(P)n}, it follows thatc
1
n
2h(n)c
2
n
n+1 for somec
1 andc
2. The lower bound disproves the conjecture thath(n)2n. It is shown that if |P| – 1 spec(P) thenP has a retract of size |P| – 1 but that for all there is a bipartite ordered set with spec(P) = {|P| – 2, |P| – 4, ...} which has no proper retract of size|P| – . The case of reflexive graphs is also treated.Partially supported by a grant from the NSERC.Partially supported by a grant from the NSERC. 相似文献
114.
115.
Pavel Novotný 《Geometriae Dedicata》1994,50(1):53-55
This paper deals with the following kind of approximation of a convex bodyQ in Euclidean space E
n
by simplices: which is the smallest positive numberh
S(Q) such thatS
1 Q S
2 for a simplexS
1 and its homothetic copyS
2 of ratioh
S(Q). It is shown that ifS
0 is a simplex of maximal volume contained inQ, then a homothetic copy ofS
0 of ratio 13/3 containsQ. 相似文献
116.
117.
Rafael Abela Christopher Baines Xavier Donath Dierk Herlach David Maden Ivan D. Reid Dieter Renker György Solt Ulrich Zimmermann 《Hyperfine Interactions》1994,87(1):1105-1110
TheSR Facility Instruments presently available at PSI and the envisaged medium- and long-term developments are presented. The plans focus on further upgrades of the existing instruments and the development of new techniques using the very high fluxes becoming available at PSI, in particular the setup of a beamline with a fast kicker for muons on request (MORE) and the development of very low energy muon beams. 相似文献
118.
Martina Schwager Emil Roduner Ivan D. Reid Paul W. Percival Jean-Claude Brodovitch Stanislaw Wlodek Robert F. Marzke 《Hyperfine Interactions》1994,87(1):859-864
SR spectra of the ethyl radical adsorbed on porous silica were observed in transverse and in longitudinal magnetic fields in the temperature range 190–298 K. The line widths reflect the dynamic partial averaging of the hyperfine anisotropy due to reorientation and surface diffusion. 相似文献
119.
A beam of relativistic antihydrogen atoms — the bound state (
e+) — can be created by circulating the beam of an antiproton storage ring through an internal gas target. An antiproton which
passes through the Coulomb field of a nucleus will create e+e− pairs, and antihydrogen will form when a positron is created in a bound instead of continuum state about the antiproton.
The cross section for this process is roughly 3Z
2 pb for antiproton momenta about 6 GeV/c. A sample of 600 antihydrogen atoms in a low-emittance, neutral beam will be made in 1995 as an accidental byproduct of Fermilab
experiment E760. We describe a simple experiment, Fermilab Proposal P862, which can detect this beam, and outline how a sample
of a few-104 atoms can be used to measure the antihydrogen Lamb shift to 1 %.
Work supported in part by Department of Energy contract DE-AC03-76SF00515 (SLAC).
Work supported by Fondo Nacional de Investigación Científica y Tecnológica, Chile. 相似文献
120.