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921.
Christov Ivan; Christov C. I.; Jordan P. M. 《The Quarterly Journal of Mechanics and Applied Mathematics》2007,60(4):473-495
Three weakly nonlinear models of lossless, compressible fluidflow—a straightforward weakly nonlinear equation (WNE),the inviscid Kuznetsov equation (IKE) and the Lighthill–Westerveltequation (LWE)—are derived from first principles and theirrelationship to each other is established. Through a numericalstudy of the blow-up of acceleration waves, the weakly nonlinearequations are compared to the exact Euler equations,and the ranges of applicability of the approximate models areassessed. By reformulating these equations as hyperbolic systemsof conservation laws, we are able to employ a Godunov-type finite-differencescheme to obtain numerical solutions of the approximate modelsfor times beyond the instant of blow-up (that is, shock formation),for both density and velocity boundary conditions. Our studyreveals that the straightforward WNE gives the best results,followed by the IKE, with the LWE's performance being the poorestoverall. 相似文献
922.
Enantiomerically pure benzyl -α,β-epoxycarboxylates were prepared by a modified Darzens procedure utilizing aldol condensation reactions of chiral α-haloimidates with various aldehydes. A unique chirality reversal was observed using Zincenolates. 相似文献
923.
924.
F. Cornea L. Ivan E. Segal A. Haures 《Journal of Thermal Analysis and Calorimetry》1988,34(5-6):1485-1488
A derivatographic investigation was performed on the thermal behaviour of three thioamides and the nonisothermal kinetic parameters for the liquid-phase decomposition of N-acetylthiobenzamide were determined. 相似文献
925.
Jaroslav Mosnáček Ivan Lukáč Štefan Chromik Ivan Kostič Pavol Hrdlovič 《Journal of polymer science. Part A, Polymer chemistry》2004,42(3):765-771
The irradiation (λ > 400 nm) in air of a copolymer of phenyl vinyl ketone with 4-vinylbenzil (VBZ) containing 1.5 wt % VBZ structural units in film, followed by the thermal decomposition of the resulting pendant benzoyl peroxide groups, leads to crosslinking. The subsequent irradiation of the crosslinked polymer at 366 nm results in the cleavage of the poly(phenyl vinyl ketone) chain between the junction points of the polymer network through a Norrish type II reaction. Therefore, poly(phenyl vinyl ketone-co-4-vinylbenzil) represents a novel type of photoresist based on polymer network decrosslinking. The process involves three steps: photogeneration of peroxide, crosslinking by its thermal decomposition, and subsequent photodecrosslinking of the polymer network. This material provides positive-tone images after UV exposure (λ > 330 nm) and development in an organic medium such as isopropyl methyl ketone. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 765–771, 2004 相似文献
926.
927.
928.
In this contribution, a novel method is described for the determination of platinum metals. The procedure developed employs a carbon paste electrode modified in situ with cationic surfactants of the quaternary ammonium salt type. The pre-concentration step is based on a specific accumulation mechanism involving ion-pair formation; the detection being performed by cathodic scanning in the differential pulse voltammetric mode. Regarding the individual forms of platinum metals, the method has been found convenient for the determination of three heavy platinum metals in the form of Pt(IV), Ir(III) and Os(IV), whereas for the remaining elements (Ru, Rh, and Pd) was almost inapplicable. Platinum metals of the former group can be pre-concentrated in chloride-containing supporting media via PtCl62−, IrCl63− and OsCl62− complex anions, the central atom of each species being fairly reducible during the voltammetric scan. Stripping signals for both platinum and iridium were proportional to the concentration in a range of 1-10 × 10−6 M Pt(IV) and Ir(III); the response for osmium being linear within 0.1-6 × 10−7 M Os(IV) with a detection limit of about 5 × 10−9 mol l−1. During optimisation, special attention was paid to the accumulation mechanism, choice of key experimental conditions, and to interference effects from foreign ions with potentially ion-pairing capabilities (AuCl4−, TlCl4−, CrO42−, MnO4−, SCN−, and I−). The method elaborated has been tested on both model solutions and real samples of industrial waste water, showing in both cases satisfactory analytical performance. 相似文献
929.
Ihor Pavlov Andrey Rybak Andrii Dobrovolskiy Viktor Kadan Ivan Blonskiy Fatih Ö. Ilday 《Liquid crystals》2018,45(9):1265-1271
It is well known that the alignment of liquid crystals (LCs) can be realised by rubbing or photoalignment technologies. Recently, nonlinear laser lithography (NLL) was introduced as a fast, relatively low-cost method for large area nano-grating fabrication based on laser-induced periodic surface structuring. In this letter for the first time, the usage of the NLL as a perspective method of the alignment of nematics was presented. By NLL, nanogrooves with about 0.92 μm period were formed on Ti layer. The nanostructured Ti layer (NSTL) was coated with oxidianiline-polyimide film with annealing of the polymer followed without any further processing. Aligning properties of NSTLs were examined with combined twist LC cell. The dependencies of the twist angle of LC cells and azimuthal anchoring energy (AE) of layers on scanning speed and power of laser beam during processing of the Ti layer were the focus of our studies as well. The maximum azimuthal AE, obtained for pure NSTL, is comparable with photoalignment technology. It was found that the deposition of polyimide film on NSTL leads to the gain effect of the azimuthal AE. Also, atomic force microscopy (AFM) study of aligning surfaces was carried out. 相似文献
930.
Egorin Andrei Sokolnitskaya Tatiana Azarova Yuliya Portnyagin Arseniy Balanov Mikhail Misko Darya Shelestyuk Evgeny Kalashnikova Anastasia Tokar Eduard Tananaev Ivan Avramenko Valentin 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(1):243-251
Sorption of micro- and microamounts of Sr from seawater has been studied using granulated Na-birnessite. Distribution coefficients of 90Sr in the natural seawater are 0.8–1.2?×?103 ml g?1, in the model seawater they are 1.6–1.8?×?103 ml g?1. Application of Na-birnessite was shown to be prospective in sorption–desorption–regeneration regime. In dynamic sorption conditions, over 150 bed volumes of seawater can be purified till 5% breakthrough occurs at feed rate 10 BV h?1. Na-birnessite can be used for 90Sr radionuclide removal from liquid radioactive wastes containing seawater.
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