Efficient and selective synthesis of alkoxy substituted di(pyridin-2-yl)amines and N-arylpyridin-2-ylamines

The formation of alkoxy substituted di(pyridin-2-yl)amines and N-arylpyridin-2-ylamines by nitro group reduction is described. Unexpected substitution of ortho with the amino at C-6 was observed during the reduction using SnCl₂·2H₂O in different alcohols. The influence of the nature of the atom at the 3- and 5-positions of nitro-substituted di(pyridin-2-yl)amines and N-arylpyridin-2-ylamines was investigated.     

Effect of the manufacturing parameters on the structure of nitrogen-doped carbon nanotubes produced by catalytic laser-induced chemical vapor deposition

Series of self-assembled and mono-dispersed bovine serum albumin (BSA)-conjugated ZnS/CuS nano-composites with different Zn/Cu ratios had been successfully synthesized by a combination method of the biomimetic synthesis and ion-exchange strategy under the gentle conditions. High-resolution transmission electron microscopy observation, Fourier transform infrared spectra and zeta potential analysis demonstrated that BSA-conjugated ZnS/CuS nano-composites with well dispersity had the hierarchical structure and BSA was a key factor to control the morphology and surface electro-negativity of final products. The real-time monitoring by atomic absorption spectroscopy and powder X-ray diffraction revealed that the Zn/Cu ratio of nano-composites could be controlled by adjusting the ion-exchange time. In addition, the metabolic and morphological assays indicated that the metabolic proliferation and spread of rat pheochromocytoma (PC12) cells could be inhibited by nano-composites, with the high anti-cancer activity at a low concentration (4 ppm). What were more important, Zn and Cu in nano-composites exhibited a positive cooperativity at inhibiting cancer cell functions. The microscope observation and biochemical marker analysis clearly revealed that the nano-composites-included lipid peroxidation and disintegration of membrane led to the death of PC12 cells. Summarily, the present study substantiated the potential of BSA-conjugated ZnS/CuS nano-composites as anti-cancer drug.     

Enzymatic degradation of some nanocomposites of poly(vinyl alcohol) with starch

A study of the enzymatic degradation of some montmorillonite-containing nanocomposites of poly(vinyl alcohol) with starch was based on the determinations of mass loss and the reducing sugars. The degraded residues have been examined by FT-IR spectroscopy and optical microscopy. It has been established that the nanoparticles hinder degradation, while the susceptibility to enzymatic degradation varies in the order: PVA/starch/nanocore > PVA/starch/Bentonite > PVA/starch/Peruvian clay.     

Thermal analysis,microstructure and impurity phases evolution in Fe14Cr ferritic steel powders ball-milled in air and under an argon atmosphere

Journal of Thermal Analysis and Calorimetry - Azobenzenes undergo reversible trans–cis photo-isomerization and have been studied extensively as photo-responsive materials. Despite their...     

Sparse classification with paired covariates

Advances in Data Analysis and Classification - This paper introduces the paired lasso: a generalisation of the lasso for paired covariate settings. Our aim is to predict a single response from two...     

A numerical approximation of parabolic stochastic partial differential equations driven by a Poisson random measure

The paper deals with SPDEs driven by Poisson random measures in Banach spaces and its numerical approximation. We investigate the accuracy of space and time approximation. As the space approximation we consider spectral methods and as time approximation the implicit Euler scheme and the explicit Euler scheme. AMS subject classification (2000) 60H15, 35R30     

Existence theory of abstract approximate deconvolution models of turbulence

This report studies an abstract approach to modeling the motion of large eddies in a turbulent flow. If the Navier-Stokes equations (NSE) are averaged with a local, spatial convolution type filter, , the resulting system is not closed due to the filtered nonlinear term . An approximate deconvolution operator D is a bounded linear operator which is an approximate filter inverse

Synthesis and Characterization of Diatomaceous Earth Chemically Modified with γ-Aminopropyltrimethoxysilane

JPC – Journal of Planar Chromatography – Modern TLC - A stationary phase for thin-layer chromatography has been prepared by bonding purified diatomaceous earth (rich in silica) with...     

In Situ-Generated,Dispersed Cu Catalysts for the Catalytic Hydrogenolysis of Glycerol

The present study is dedicated to the experimental verification of a concept for the hydrogenolysis of glycerol over in situ-generated Cu dispersed particles (Cu-DP). The Cu-DP were generated by in situ reduction of a precursor salt (Cu(OAc)₂, CuSO₄, CuCl₂) in the presence of KOH and were active in glycerol conversion under hydrogen (T = 200–220 °C, p(H₂) = 1–4 MPa), where 1,2-propylene glycol (PG) and lactic acid (LA) were detected to be the main products. The influence of the reaction conditions (temperature, hydrogen pressure, reaction time, catalyst-to-feed ratio and the KOH/Cu ratio) on the yields of the products is described. It was shown that the selectivity between the PG and LA could be tuned by changing p(H₂) or by the KOH amount, i.e., higher yields of LA corresponded to lower p(H₂) and higher alkalinity of the reaction media. The activity of the in situ-generated Cu-DP was found to be comparable to that of an industrial Cu-Cr₂O₃ catalyst. The Cu-DP catalysts were characterized by XRD, XPS, HRTEM and SEM. During the reaction, the catalyst evolved by the sintering and recrystallization of the separate Cu-DP; the crystallite sizes after 1 and 15 h reaction times amounted to 35 and 49 nm, respectively.     

Optical and electrochemical-mediated detection of ascorbic acid using manganese porphyrin and its gold hybrids

The developments concerning new hybrids based on porphyrin derivatives and colloids destined for the detection of ascorbic acid (AA) in the relevant range for medical investigations are presented. Mn(III) tetratolylporphyrin chloride (MnTTPCl), spherical gold colloid (n-Au), and their hybrid (MnTTPCl/n-Au) were chosen to be comparatively investigated by ultraviolet–visible spectroscopy in the presence of AA. The hybrid material (MnTTPCl/n-Au) has the best capacity to detect concentrations of AA in the range of 2.6 × 10^?6–4.38 × 10^?5 M. Modified glassy carbon (GC) electrodes were obtained by thin film deposition of MnTTPCl, n-Au alone, and in successive mixed thin films, comparing their response during the electrochemical oxidation of AA. The electrocatalytic effect of the MnTTPCl on the AA oxidation is justified both by the increase in the peak current density and by the shift toward more negative potentials (0.024 V). The GC/MnTTPCl electrode has the best electrocatalytic effect for the AA oxidation and is promising for sensor applications.