全文获取类型
收费全文 | 435388篇 |
免费 | 5503篇 |
国内免费 | 1230篇 |
专业分类
化学 | 233760篇 |
晶体学 | 6489篇 |
力学 | 18765篇 |
综合类 | 13篇 |
数学 | 49930篇 |
物理学 | 133164篇 |
出版年
2021年 | 3763篇 |
2020年 | 4185篇 |
2019年 | 4518篇 |
2018年 | 5853篇 |
2017年 | 5744篇 |
2016年 | 8831篇 |
2015年 | 5561篇 |
2014年 | 8542篇 |
2013年 | 20183篇 |
2012年 | 15647篇 |
2011年 | 19261篇 |
2010年 | 13497篇 |
2009年 | 13350篇 |
2008年 | 17647篇 |
2007年 | 17541篇 |
2006年 | 16252篇 |
2005年 | 14550篇 |
2004年 | 13524篇 |
2003年 | 11892篇 |
2002年 | 11728篇 |
2001年 | 13429篇 |
2000年 | 10085篇 |
1999年 | 7916篇 |
1998年 | 6569篇 |
1997年 | 6314篇 |
1996年 | 6081篇 |
1995年 | 5470篇 |
1994年 | 5392篇 |
1993年 | 5197篇 |
1992年 | 5828篇 |
1991年 | 5924篇 |
1990年 | 5664篇 |
1989年 | 5472篇 |
1988年 | 5493篇 |
1987年 | 5374篇 |
1986年 | 5091篇 |
1985年 | 6561篇 |
1984年 | 6694篇 |
1983年 | 5301篇 |
1982年 | 5387篇 |
1981年 | 5367篇 |
1980年 | 4955篇 |
1979年 | 5352篇 |
1978年 | 5491篇 |
1977年 | 5385篇 |
1976年 | 5328篇 |
1975年 | 4914篇 |
1974年 | 4885篇 |
1973年 | 4880篇 |
1972年 | 3455篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
111.
Tereshchenko E. D. Cherniakov S. M. Yurik R. Yu. Rietveld M. T. Häggström I. 《Radiophysics and Quantum Electronics》2020,62(10):667-676
Radiophysics and Quantum Electronics - We present the results of comparing the total electron content measurements based on GLONASS satellite signals and the EISCAT UHF incoherent scatter radar... 相似文献
112.
Umie F.M. Haziz Rosenani A. Haque Shun-Ze Zhan Hassan H. Abdallah Mohd R. Razali 《应用有机金属化学》2020,34(10):e5818
The synthesis and characterizations for a series of dinuclear gold (I)-di-NHC complexes, 1–8 through the trans-metalation method of their respective silver (I)-di-NHC complexes, i–viii are reported (where NHC = N-heterocyclic carbene). The successful complexation of a series of unusual non-symmetrical and symmetrical di-NHC ligands, 3,3'-(ethane-1,2-diyl)-1-alkylbenzimidazolium-1'-butylbenzimidazolium (with alkyl = methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, benzyl) with the gold (I) ions are suggested by elemental analysis, Fourier transform-infrared, 1H- and 13C-NMR data. The 13C-NMR spectra of 1–8 show a singlet sharp peak in the range of 190.00–192.00 ppm, indicating the presence of a carbene carbon that bonded to the gold (I) ion. From single crystal X-ray diffraction data, the structure of complex 6 with the formula of [di-NHC-Au (I)]2·2PF6 is obtained [where NHC = 3,3'-(ethane-1,2-diyl)-1-hexylbenzimidazolium-1'-butylbenzimidazolium]. The photophysical study in solid state of 6 displays an intense photoluminescence with a strong emission maxima, λem = 480 nm, upon excitation at 340 nm at room temperature. Interestingly, the emission maximum at 77 K shows a structural character with a strong peak at 410 nm, a medium at 433 nm and a weak at 387 nm, accompanied by a tail band to about 500 nm. 相似文献
113.
Beyond Stereoselectivity,Switchable Catalysis: Some of the Last Frontier Challenges in Ring‐Opening Polymerization of Cyclic Esters 下载免费PDF全文
Dr. Sophie M. Guillaume Dr. Evgueni Kirillov Dr. Yann Sarazin Prof. Dr. Jean‐François Carpentier 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):7988-8003
Metal‐based catalysts and initiators have played a pivotal role in the ring‐opening polymerization (ROP) of cyclic esters, thanks to their high activity and remarkable ability to control precisely the architectures of the resulting polyesters in terms of molar mass, dispersity, microstructure, or tacticity. Today, after two decades of extensive research, the field is slowly reaching maturity. However, several challenges remain, while original concepts have emerged around new types or new applications of catalysis. This Review is not intended to comprehensively cover all of these aspects. Rather, it provides a personal overview of the very recent progress achieved in some selected, important aspects of ROP catalysis—stereocontrol and switchable catalysis. Hence, the first part addresses the development of new metal‐based catalysts for the isoselective ROP of racemic lactide towards stereoblock copolymers, and the use of syndioselective ROP metal catalysts to control the monomer sequence in copolymers. A second part covers the development of ROP catalysts—primarily metal‐based catalysts, but also organocatalysts—that can be externally regulated by the use of chemical or photo stimuli to switch them between two states with different catalytic abilities. Current challenges and opportunities are highlighted. 相似文献
114.
115.
116.
117.
Doklady Mathematics - In this paper, for the first time, we provide a quasi-polynomial time approximation scheme for the well-known capacitated vehicle routing problem formulated in metric spaces... 相似文献
118.
119.
120.
Pan Huang Dawen Xu Robert M. Reich Felix Kaiser Boping Liu Fritz E. Kühn 《Tetrahedron letters》2019,60(24):1574-1577
A first example of an Et2Zn mediated silylation of 1-aklynes is reported. A series of functional groups are tolerated in this reaction. Mechanistic studies support Zn alkynilides as intermediates in the reaction. This reaction protocol provides a practical method for the preparation of alkynylsilanes and expands the application of organometallic zinc in organic synthesis. 相似文献