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91.
Christina Hauser 《Nachrichten aus der Chemie》2008,56(11):1111-1113
92.
Dr. David Scheerer Prof. Dr. Heng Chi Dr. Dan McElheny Prof. Dr. Timothy A. Keiderling Prof. Dr. Karin Hauser 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(16):3524-3534
Site-specific isotopic labeling of molecules is a widely used approach in IR spectroscopy to resolve local contributions to vibrational modes. The induced frequency shift of the corresponding IR band depends on the substituted masses, as well as on hydrogen bonding and vibrational coupling. The impact of these different factors was analyzed with a designed three-stranded β-sheet peptide and by use of selected 13C isotope substitutions at multiple positions in the peptide backbone. Single-strand labels give rise to isotopically shifted bands at different frequencies, depending on the specific sites; this demonstrates sensitivity to the local environment. Cross-strand double- and triple-labeled peptides exhibited two resolved bands that could be uniquely assigned to specific residues, the equilibrium IR spectra of which indicated only weak local-mode coupling. Temperature-jump IR laser spectroscopy was applied to monitor structural dynamics and revealed an impressive enhancement of the isotope sensitivity to both local positions and coupling between them, relative to that of equilibrium FTIR spectroscopy. Site-specific relaxation rates were altered upon the introduction of additional cross-strand isotopes. Likewise, the rates for the global β-sheet dynamics were affected in a manner dependent on the distinct relaxation behavior of the labeled oscillator. This study reveals that isotope labels provide not only local structural probes, but rather sense the dynamic complexity of the molecular environment. 相似文献
93.
A CE instrument that can be assembled from commercially available components with minimal construction effort is described. Except for the electronic control circuitry no specially made parts are required. It is based on a flexible design of microfluidic, electropneumatic, and electronic sections and different configurations can easily be implemented. Automated injection into the capillary is performed hydrodynamically by the application of a pressure for a controlled length of time. The performance of the device was tested with a contactless conductivity detector by separating different metal ions. In addition, nine metal cations related to the quality of honey were separated in 2.3 min and four honey samples were analysed quantitatively to demonstrate the applicability of the method. 相似文献
94.
I. W. Ellms S. I. Hauser L. W. Winkler H. Pecker V. Froboese A. T. Stuart F. Malméjac J. Tillmans O. Heublein H. Noll J. M. Kolthoff H. Klut Dietl L. Dede E. Hauser E. M. Chamot D. S. Pratt A. E. Johnson H. Silvester W. Vaubel G. Denigès E. H. Miller S. Rothenfusser M. Bornand L. Rosenthaler V. Jahn A. Dané L. v. Liebermann D. Acel E. B. Phelps H. L. Shoub Escaich H. Berger G. D. Elsdon N. Evers H. W. Brubaker F. W. Bruckmiller 《Analytical and bioanalytical chemistry》1922,61(4-5):196-205
95.
W. R. Schoeller A. R. Powell O. Hahn K. E. Pütter E. S. Simpson W. F. Hillebrand G. E. F. Lundell O. Ruff E. Schiller W. P. Headden H. Pied H. W. Webb R. J. Meyer O. Hauser W. B. Giles R. C. Wells E. F. Waterhouse G. T. Prior E. C. Deering L. Finckh J. H. Muller J. W. Mellor E. W. Todd V. Schwarz G. W. Sears W. D. Treadwell 《Analytical and bioanalytical chemistry》1934,99(5-6):205-227
96.
A flow-through optical absorption detector for HPLC was constructed using a novel deep-UV light-emitting diode as radiation source with a peak emission wavelength of 255 nm. For measuring the transmitted intensity (a property correlated to Transmittance) a special UV-sensitive photodiode was employed. Besides the power source, no optical or electronic components other than an inexpensive operational amplifier and a few passive components were necessary. The performance of the detector was tested with three substances, namely nitrobenzene, benzoic acid and methyl benzoate, which were separated by gradient elution using an acetonitrile/water mixture and tetrabutylammonium hydrogensulfate as pH-buffer. Calibration curves for concentrations between 1.6 microg.mL(-1) and 400 microg.mL(-1) (nitrobenzene) and 8 microg.mL(-1) and 2.5 mg.mL(-1) (benzoic acid and methyl benzoate) were determined and coefficients of determination, r(2), of 0.9945, 0.9972 and 0.9996 were obtained for quadratic curve fits for the 3 compounds respectively. Relative standard deviations (n = 7) for peak areas were determined as 0.35% (nitrobenzene, 80 microg.mL(-1)), 0.27% (benzoic acid, 400 microg.mL(-1)) and 0.83% (methyl benzoate, 200 microg.mL(-1)). The lower limits of detection were found to be 750 ng.mL(-1), 5.8 microg.mL(-1) and 12 microg.mL(-1) for nitrobenzene, benzoic acid and methyl benzoate respectively. 相似文献
97.
98.
We applied theoretical models and molecular dynamics simulations to explore extreme multielectron ionization in Xe(n) clusters (n=2-2171, initial cluster radius R(0)=2.16-31.0 A) driven by ultraintense infrared Gaussian laser fields (peak intensity I(M)=10(15)-10(20) W cm(-2), temporal pulse length tau=10-100 fs, and frequency nu=0.35 fs(-1)). Cluster compound ionization was described by three processes of inner ionization, nanoplasma formation, and outer ionization. Inner ionization gives rise to high ionization levels (with the formation of [Xe(q+)](n) with q=2-36), which are amenable to experimental observation. The cluster size and laser intensity dependence of the inner ionization levels are induced by a superposition of barrier suppression ionization (BSI) and electron impact ionization (EII). The BSI was induced by a composite field involving the laser field and an inner field of the ions and electrons, which manifests ignition enhancement and screening retardation effects. EII was treated using experimental cross sections, with a proper account of sequential impact ionization. At the highest intensities (I(M)=10(18)-10(20) W cm(-2)) inner ionization is dominated by BSI. At lower intensities (I(M)=10(15)-10(16) W cm(-2)), where the nanoplasma is persistent, the EII contribution to the inner ionization yield is substantial. It increases with increasing the cluster size, exerts a marked effect on the increase of the [Xe(q+)](n) ionization level, is most pronounced in the cluster center, and manifests a marked increase with increasing the pulse length (i.e., becoming the dominant ionization channel (56%) for Xe(2171) at tau=100 fs). The EII yield and the ionization level enhancement decrease with increasing the laser intensity. The pulse length dependence of the EII yield at I(M)=10(15)-10(16) W cm(-2) establishes an ultraintense laser pulse length control mechanism of extreme ionization products. 相似文献
99.
D. Taqqu F. Biraben C.A.N. Conde T.W. Hänsch F.J. Hartmann P. Hauser P. Indelicato P. Knowles F. Kottmann F. Mulhauser C. Petitjean R. Pohl P. Rabinowitz R. Rosenfelder J.M.F. Santos W. Schott L.M. Simons J.F.C.A. Veloso 《Hyperfine Interactions》1999,119(1-4):311-315
The muonic hydrogen atom in the 2s state provides the possibility of achieving high precision laser spectroscopy experiments
from which a high precision value of the proton radius can be deduced. This will ultimately allow an increased precision in
the test of QED in bound systems. Important progress has been made in recent years in the ability to stop muons in a low pressure
gas target and in the understanding of the 2s-metastability in muonic hydrogen. As a consequence the 2s–2p laser spectroscopy
experiment is now feasible and we present here the basic experimental concept considered by our collaboration.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
100.
M. Mühlbauer H. Daniel F.J. Hartmann P. Hauser F. Kottmann C. Petitjean W. Schott D. Taqqu P. Wojciechowski 《Hyperfine Interactions》1999,119(1-4):305-310
The classical methods used in beam cooling are hard to be adapted for a beam of short-lived elementary particles. A novel
method, the so-called frictional cooling – that is cooling a beam of low-energy charged particles by moderation in matter
and acceleration in an electrostatic field – has been shown to be feasible. In our experiments performed in 1994/1995 a beam
of short-lived particles was cooled for the first time ever. Utilizing frictional cooling on a beam of slow negative muons
we observed increase in phase space density by about one order of magnitude.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献